UNS N08810 · W.Nr. 1.4958 · X5NiCrAlTi31-20 · 30.0-35.0% Ni – 19.0-23.0% Cr – 39.5% min Fe – C 0.05-0.10 – Al 0.15-0.60 – Ti 0.15-0.60 – Al+Ti 0.30-1.20. THE FAMILY HAS THREE SEPARATE GRADES AND THEY ARE NOT INTERCHANGEABLE: 800 = UNS N08800 · W.Nr. 1.4876 · C 0.10 max · NO grain size requirement; 800H = UNS N08810 · W.Nr. 1.4958 · C 0.05-0.10 · grain size ASTM 5 or coarser; 800HT = UNS N08811 · W.Nr. 1.4959 · C 0.06-0.10 · Al+Ti 0.85-1.20 · grain size ASTM 5 or coarser. The Ni-Cr-Fe band is the same for all three; the difference is CARBON, Al+Ti and GRAIN SIZE.
A Ni-Fe-Cr SOLID-SOLUTION alloy. It DOES NOT PRECIPITATION HARDEN; it cannot be hardened by heat treatment, and strength is raised only by cold work, which annealing removes again.
Forms
Round bar · Flat bar · Plate · Sheet · Tube and pipe · Forging. All forms are supplied to order.
Standards
AMS 5766 — bars and forgings (SAE title: Alloy, Corrosion and Heat-Resistant, Bars and Forgings 21Cr – 32.5Ni – 0.38Ti – 0.38Al – 45Fe, Solution Heat Treated; bars and forgings 4.0 in. (102 mm) and under, and forging stock of any size). · AMS 5871 — sheet, strip and plate (SAE title: Alloy, Corrosion and Heat-Resistant, Sheet, Strip and Plate, 21Cr – 32.5Ni – 0.38Ti – 0.38Al – 45Fe, Solution Heat Treated). · ASTM B409 / ASME SB-409 — plate, sheet and strip. · ASTM B408 / ASME SB-408 — rod and bar. · ASTM B407 / ASME SB-407 — seamless pipe and tube. · ASTM B564 / ASME SB-564 — forgings. · ASTM B163 / ASME SB-163 — seamless condenser and heat-exchanger tube. · ASTM B514 / ASME SB-514 — welded pipe (N08120, N08800, N08810; N08811 IS NOT COVERED). · ASTM B515 / ASME SB-515 — welded tube (N08120, N08800, N08810, N08811). · ASTM B366 / ASME SB-366 — welded fittings. · ASME Code acceptance: design stresses for Section I and Section VIII Division 1 are in Table 1B, for Section VIII Division 2 in Table 2B; Code Cases 1325 (all product forms), 1949 (forgings), 1983 (seamless pipe and tube), 2339 (800H plate); for nuclear work, Section III and Code Cases N-201, N-253 and N-254. · DIN 17460 · EN 10095 · EN 10028-7 · ISO 9723 (bar) / 9725 (forgings) / 6207 (seamless tube) · BS 3076NA15. THE TITLES OF AMS 5766 AND AMS 5871 CARRY NO UNS NUMBER; the chemistry in the title (21Cr-32.5Ni-0.38Ti-0.38Al-45Fe) is that of the 800 family, and distributors apply both numbers to 800, 800H and 800HT alike.
Advantage
Carbon held to the 0.05-0.10% band, and a grain size of ASTM 5 or coarser made a SPECIFICATION REQUIREMENT through a minimum anneal at 1121 °C (2050 °F).
Welding
Filler metal: for service BELOW 790 °C (1450 °F), INCONEL Filler Metal 82 / AWS A5.14 ERNiCr-3 (GTAW and GMAW) and INCO-WELD A covered electrode;
Limits
1) ROOM AND LOW TEMPERATURE — 800H IS NOT BOUGHT FOR THIS DUTY. The ASTM specification minimum for 800H/800HT is 450 MPa tensile / 170 MPa yield; for plain grade 800 it is 520 MPa / 205 MPa. Coarse grain LOWERS room-temperature strength. For pressure equipment below 593 °C the correct grade is 800.
Compiled from manufacturer data sheets · confirm against the current specification before ordering
On this page · click to jump
800, 800H and 800HTWhat Actually Fails with “800/800H Dual-Certified” MaterialStandards by Product FormMechanical Properties, Physical Properties and WeldingHeat Treatment, Fabrication and Service BehaviourFrequently Asked Questions
Incoloy 800H, generally known as Alloy 800, is a nickel alloy chosen where high temperatures are involved and mechanical strength is required. Incoloy 800 exists in three different versions that differ in carbon, titanium and aluminium content. The most widely used of these versions is grade 1.4876.
The first of the three Incoloy 800 materials is Incoloy 800 (Alloy 800), also designated 1.4876. When the price of nickel rose in the 1950s, heat resistant materials with a high nickel content became very expensive. Metallurgists therefore began to research and develop a material that contained less nickel while withstanding the same temperatures. Standing up as well as many materials with a higher nickel content, Incoloy 800 creates a price and cost advantage through its lower nickel content.
Another widely used version is Incoloy 800H, also known as Alloy 800H. Alloy 800H is the version of Alloy 800 with a slightly higher carbon content, and that small amount of extra carbon gives the material somewhat more strength. Apart from the carbon content there is little difference between Incoloy 800H and Incoloy 800. Alloy 800H is also designated UNS N08810, and in the DIN system it is designated 1.4958.
The third and most distinct version of Incoloy 800 is Incoloy 800HT. The carbon content of this material is similar to that of Alloy 800H, but in addition its aluminium and titanium contents are higher than in the other two versions. This makes Incoloy 800HT somewhat more durable in more demanding and severe environments. Designated UNS N08811, it is also known as 1.4959. Both Incoloy 800H and Incoloy 800HT are designated X10NiCrAlTi32-20 under the EN standards.
The essential differences between these three Alloy 800 materials are their temperature capability, grain size and mechanical strength. Incoloy 800 is a nickel alloy recommended for use up to 816 °C; at higher temperatures the 800H and 800HT alloys should be used. The grain size of Alloy 800H and 800HT is specified and is required to exceed defined values, whereas Alloy 800 has no specified grain size. Finally, in terms of temperature capability and mechanical strength, the comparison from strongest to weakest is: Incoloy 800HT > Incoloy 800H > Incoloy 800.
Round bar · Flat bar · Plate · Sheet · Tube · Forgings All forms are supplied to order.
800, 800H and 800HT — the Centrepiece of This Page
The three grades have identical nickel, chromium and iron. Everything that separates them is carbon, aluminium plus titanium, grain size and annealing temperature — which is precisely why buyers get it wrong: the top three lines of the mill certificate look the same for all three.
800 / 800H / 800HT · the Real Difference
DEFENCE METAL
Ni · Cr · Fe
Identical in all three: Ni 30.0–35.0 % · Cr 19.0–23.0 % · Fe 39.5 % min
Carbon
800: 0.10 % max (no minimum) · 800H: 0.05–0.10 % · 800HT: 0.06–0.10 %
800: — (could not be verified; print no figure) · 800H: 0.30–1.20 % · 800HT: 0.85–1.20 %
ASTM grain size
800: not specified · 800H and 800HT: 5 or coarser (ASTM E112)
Anneal
800: Grade 1 ≈980 °C, Grade 2 ≈1150 °C · 800H/800HT: 1150–1200 °C; 1149 °C minimum is mandatory for 800HT
The service-temperature dividing line — and a real divergence. ASTM’s own scope text (which appears verbatim in B407, B408, B409, B514 and B564) says: “Alloy UNS N08800 is normally employed in service temperatures up to and including 1100 °F (593 °C)”, while the other alloys are for “service temperatures above 1100 °F where resistance to creep and rupture is required, and they are annealed to develop controlled grain size for optimum properties in this temperature range”. Against that, the originator’s own bulletin says the H grades are used “especially at temperatures above 1500 °F (816 °C)“. Both figures are real and must not be averaged. The safe procurement rule is ASTM’s: above 1100 °F / 593 °C, order 800H or 800HT, not 800.
ASME Status — and a Second Divergence
DEFENCE METAL
800 (N08800)
Section I: to 816 °C · Section VIII Div. 1: to 816 °C · Div. 2: to 427 °C (single-sourced)
800H (N08810)
Section I: to 816 °C · Section VIII Div. 1: to 982 °C via Code Case 1983 · Div. 2: to 427 °C
800HT (N08811)
Section VIII Div. 1: to 982 °C via Code Case 1983
The divergence
The originator says 982 °C (1800 °F); a major distributor says 899 °C (1650 °F). Report both. The figure to quote a procurement engineer is the conservative one, 1650 °F, with 1800 °F footnoted
The commercial case for 800HT
800HT carries higher design stresses than 800H specifically over 593–899 °C (1100–1650 °F). That band is the entire reason to pay for 800HT
Code Case caution
Code Cases 1325-7 and 1983 circulate through the whole trade literature. Their current status could not be verified (the ASME Code Case index is licensed). Code Cases can be annulled or absorbed into the Code body — never invoke a code case on a purchase order without confirming it is live in the current BPVC Code Case book
Section III / nuclear · B31.3
— (could not be verified). Publish no figure
Section IX P-Number
P45 (single-sourced)
What Actually Fails with “800/800H Dual-Certified” Material
800H/800HT dual certification is legitimate and is the normal commercial product. Every 800HT limit sits inside 800H (carbon 0.06–0.10 within 0.05–0.10; Al+Ti 0.85–1.20 within 0.30–1.20), so one heat genuinely satisfies both — the trade calls it “800H/AT”. Accept it.
The dual certification that deserves scrutiny is 800/800H. Chemically it can be honest: carbon of 0.05–0.10 % also satisfies 800’s “0.10 % max”. But alloy 800 imposes no grain-size requirement and may be annealed as low as 980 °C. The “800” line on the certificate provides cover for material that was processed as N08800 — Grade 1 anneal, fine grain, no grain-size report. That material is a perfectly valid N08800 and a non-conforming N08810.
The failure is invisible at goods-in. Room-temperature tensile passes — the originator notes that alloy 800 actually has higher room-temperature and short-time elevated-temperature properties than 800H. Chemistry passes. The failure appears in service above 1100 °F, thousands of hours in, as bulging, cavitation and early rupture of a component designed to 800H allowable stresses — because those allowables were derived from coarse-grained material.
Practical acceptance rule: a certificate is only 800H if it shows (1) C ≥ 0.05 %, (2) a reported ASTM grain size of 5 or coarser on the certificate, and (3) the actual annealing temperature, ≥1150 °C. If the grain-size line is blank, it is not 800H, whatever the heading says. For 800HT additionally require Al+Ti 0.85–1.20 % with Al and Ti each ≥0.25 %. One more warning: alloy 800 itself has a Grade 2 anneal at about 1150 °C, so “annealed at 2100 °F” alone proves nothing.
Standards by Product Form
STANDARDS BY PRODUCT FORM
DEFENCE METAL
Product form
Standards
Round bar, flat bar
AMS 5766 (bars and forgings; bars 4.0 in. (102 mm) and under, forging stock of any size) · ASTM B408 / ASME SB-408 (rod and bar) · ASTM B906 and B775 (general requirements) · DIN 17460 · EN 10095 · ISO 9723 · BS 3076NA15. Anneal >= 1121 °C for N08810 and >= 1149 °C for N08811; grain size ASTM No. 5 or coarser. ASME Code: design stresses for Section I and Section VIII Division 1 are in Table 1B; Code Case 1325 covers all product forms.
Forging
AMS 5766 (bars and forgings) · ASTM B564 / ASME SB-564 (nickel alloy forgings) · ASTM B408 for forging stock · ASME Code Case 1949 (forgings) · DIN 17460 · ISO 9725. ASTM B564 section 5.2: annealed N08810 and N08811 shall have a grain size of ASTM No. 5 or coarser. Hot working 900-1200 °C; the 760-540 °C range is passed through quickly and a solution anneal follows.
Plate
AMS 5871 (sheet, strip and plate) · ASTM B409 / ASME SB-409 (plate, sheet, strip) · ASTM B906 (general requirements) · DIN 17460 · EN 10028-7 · EN 10095 · BS 3072NA15. ASME Code Case 2339 covers 800H PLATE specifically. Special Metals gives the grain size for plate as ASTM 1-5.
Sheet, strip
AMS 5871 (sheet, strip and plate) · ASTM B409 / ASME SB-409 · DIN 17460 · EN 10095 · BS 3073NA15 (strip). Special Metals gives the grain size for sheet as ASTM 2-5, which differs from plate and tube.
Tube and pipe — seamless
NO AMS. · ASTM B407 / ASME SB-407 (seamless pipe and tube) · ASTM B163 / ASME SB-163 (seamless condenser and heat-exchanger tube) · ASTM B829 and B775 (general requirements) · DIN 17459 · ISO 6207 · BS 3074NA15. ASME Code Case 1983 covers seamless pipe and tube and permits service to 1800 °F (982 °C) under Section VIII Division 1 (Special Metals). In B407, N08800 has two separate sets of minimums while N08810/N08811 have one.
Tube and pipe — welded
NO AMS. · ASTM B514 / ASME SB-514 (welded pipe) — ONLY N08120, N08800 and N08810; N08811 IS NOT COVERED. · ASTM B515 / ASME SB-515 (welded tube) — N08120, N08800, N08810 and N08811. · ASTM B751 and B775 (general requirements). B514 requires an anneal of >= 1121 °C for N08810 and a grain size of ASTM No. 5 or coarser.
Welded fitting
NO AMS. · ASTM B366 / ASME SB-366 (factory-made wrought fittings). Special Metals lists this standard for grade 800; for an 800H/800HT order the grade and the grain size requirement must be stated separately.
Welding consumable
NO AMS. · For service below 790 °C (1450 °F): AWS A5.14 ERNiCr-3 (INCONEL Filler Metal 82; VDM FM 82, W.Nr. 2.4806) and INCO-WELD A covered electrode. · For service above 790 °C: AWS A5.14 ERNiCrCoMo-1 (Filler Metal 617) and AWS A5.11 ENiCrCoMo-1 (Electrode 117). · ASME Section IX: base metal P-No. 45. No preheat is required.
ASME Code acceptance and maximum code temperature
Section I: 1500 °F (816 °C) — Special Metals; Code Case 1325. · Section VIII Division 1: design stresses in Table 1B; Special Metals gives 1800 °F (982 °C) through Code Case 1983, Rolled Alloys gives 1650 °F (899 °C) and Jacquet gives 1500 °F (816 °C) for Table UNF-23.2 — NO SINGLE FIGURE HAS BEEN WRITTEN, the sources disagree. · Section VIII Division 2: 800 °F (427 °C) — Special Metals. · The allowable stresses for 800HT between 1100 and 1650 °F (593-899 °C) are higher than those for 800H. · Plain grade 800 is capped at 1500 °F (816 °C) in Section I and Section VIII Division 1. · Nuclear: Section III and Code Cases N-201, N-253 and N-254. The project value must be verified from the Section II Part D tables.
The titles of AMS 5766 and AMS 5871 carry no UNS number. An order placed on the AMS number alone does not guarantee the carbon band and the grain size requirement of 800H; the order must state UNS N08810 and the relevant ASTM standard explicitly. The ASTM B514 welded-pipe standard does not cover N08811. It cannot be used when 800HT is required in welded pipe. No single figure has been written for the maximum ASME code temperature: Special Metals gives 1800 °F (982 °C, Code Case 1983), Rolled Alloys gives 1650 °F (899 °C) and Jacquet gives 1500 °F (816 °C). No average has been taken; the project value must be verified from the Section II Part D tables. On the EN / DIN side the number for 800H is 1.4958, while VDM Metals lists its own 800 H product as 1.4876. Both the UNS and the W.Nr. should be stated in the order text.
W.Nr./EN 1.4958 (800H) and 1.4959 (800HT); DIN X 5 NiCrAlTi 31 20 and X 10 NiCrAlTi 32 20. AMS 5871 is cited but its scope could not be verified
Three mis-citations, with the correction.(1) ASTM A240 is cited for 800/800H plate; A240’s scope is “chromium, chromium-nickel, and chromium-manganese-nickel stainless steel plate, sheet and strip”, and N08800/N08810/N08811’s presence in its grade table could not be confirmed — do not put A240 on a purchase order for 800H plate; cite B409. (2) ASTM B516 is not an 800H specification: its scope covers N06600, N06601, N06603, N06025, N06045, N06690, N06693 and N06699 — no 800-family alloy at all. The correct welded-tube specification is B515. (3) B514 does not cover N08811: an order saying “800HT welded pipe per B514” is unsatisfiable.
Mechanical Properties, Physical Properties and Welding
The first fourteen rows are SPECIFICATION MINIMUMS for room temperature; the last row is a producer TYPICAL value, not a specification requirement, and the two must not be mixed. Because N08810 / N08811 DO NOT PRECIPITATION HARDEN, the rows are split by PRODUCT FORM, GRADE and DELIVERY CONDITION, not by ageing condition. THE POINT TO NOTE: the room-temperature minimums of 800H and 800HT are LOWER than those of plain grade 800 (450/170 MPa against 520/205 MPa); coarse grain lowers room-temperature strength, and the gain lies in the creep regime above 593 °C. There is NO hardness row: no hardness value confirmed by four independent sources could be found for the 800 family. There is no AMS row either: the texts of AMS 5766 and AMS 5871 could not be read in this study and their minimums could not be verified. The room-temperature SPECIFICATION MINIMUM of 800H and 800HT is LOWER than that of plain grade 800. This is not a defect but the direct consequence of the coarse-grain requirement; the gain lies in the creep regime. The MPa equivalents shift by a few units from standard to standard (450/448, 170/172, 520/517, 205/207). That is SI rounding in different ASTM editions, not a difference in material. The order should be placed on the ksi value. No elevated-temperature strength or creep-rupture table has been placed in this diagram: a complete creep-rupture set confirmed by four independent sources for the same temperature and the same duration could not be assembled. No hardness value has been written; it could not be confirmed by four independent sources. ASTM B407 and B408 carry TWO separate sets of minimums for N08800; N08810 and N08811 have a single set. If the delivery condition is not stated in the order text, the wrong row is applied.
Specification minimums are not printed on this page. None of the sources reviewed gives the ASTM/ASME minimum tensile, yield and elongation for N08810 or N08811; those live in B409/B407/B408 Table 3. One distributor’s “Yield 200 MPa minimum / Tensile 531 MPa minimum / Elongation 52 % minimum” is not a set of minimums: another distributor publishes the identical three numbers as typical room-temperature values, and a 52 % elongation minimum is not credible for any wrought alloy. Note too that the minimums differ between N08800 and N08810 — the originator states alloy 800 has higher room-temperature properties — so a single shared minimums table for all three grades would be wrong.
The tensile/yield ratio is typically greater than 2, and the work-hardening rate is lower than the common austenitic stainless grades — a fabricator planning intermediate anneals on a 304 schedule is over-processing
Physical properties: density 7.94 g/cm³ · melting range 1357–1385 °C · specific heat (0–100 °C) 460 J/kg·°C · modulus of elasticity 196 GPa at 70 °F. Magnetic behaviour: austenitic and essentially non-magnetic at and above room temperature (µ = 1.014 at 200 Oe); because the Curie temperature is −115 °C, it becomes ferromagnetic only at cryogenic temperatures. A buyer testing with a magnet at ambient will correctly find it non-magnetic; a strongly magnetic response is evidence of the wrong material or of heavy cold work.
Welding
Processes: SMAW, GTAW and GMAW. ASME Section IX P-Number: P45.Consumable selection changes with service temperature, and the crossover is the key fact:up to 788 °C (1450 °F) use INCO-WELD A for SMAW and INCONEL Filler Metal 82 (AWS ERNiCr-3) for GTAW/GMAW; above 788 °C use INCONEL Welding Electrode 117 for SMAW and INCONEL Filler Metal 617 (AWS ERNiCrCoMo-1) for GTAW/GMAW. RA330-04 (UNS N08334) is an alternative. Matching-composition filler is not used — both mills point to nickel-base fillers (82 / 617), not an 800H-composition wire, and this is worth saying explicitly because buyers ask for “800H filler”. The AWS classification of INCO-WELD A (commonly quoted as ENiCrFe-2) could not be verified; do not print an AWS class for the covered electrode until it is confirmed.
Post-weld heat treatment carries a genuine, safety-relevant disagreement. One distributor says “no post-weld heat treatment is required”. Another requires, for N08811 entering service above 538 °C, 899 °C for approximately 1 hour per inch of thickness (30 minutes minimum), then air cool, in order to “avoid possible stress relaxation grain boundary cracking“. These directly contradict. Stress-relaxation (reheat) cracking is a well-known problem in coarse-grained creep-resistant austenitics; for high-temperature service follow the specific, mechanistically-argued position.
No numeric preheat, interpass temperature or heat-input limits are printed on this page — none could be verified. The welding pitfalls the page should list: (1) stress-relaxation cracking in the coarse-grained HAZ of heavy sections; (2) welding or any hot work in the 1200–1600 °F (650–870 °C) range is prohibited; (3) HAZ sensitisation in the 540–760 °C range; (4) choosing Filler 82 / ERNiCr-3 for service above 788 °C — it is the wrong filler above that line.
Heat Treatment, Fabrication and Service Behaviour
HEAT TREATMENT — SCHEMATIC
DEFENCE METAL
ANNEAL / SOLUTION ANNEAL — 800H (N08810), the standard delivery condition
Step
ANNEAL / SOLUTION ANNEAL — 800H (N08810), the standard delivery condition
Summary
This is the treatment that separates 800H from 800. Its purpose is not to harden but to develop an average grain size of ASTM 5 OR COARSER; the creep and rupture strength comes from that coarse grain. The ASTM minimums are measured in this condition.
Temperature
SPECIFICATION FLOOR: 2050 °F (1121 °C) MINIMUM — the same figure appears in the texts of ASTM B409, B408, B407 and B514. PRODUCER PRACTICE BANDS: 2100-2200 °F (1150-1200 °C) — Special Metals and Corrosion Materials · 2050-2150 °F (1121-1177 °C) — Jacquet · 2100 °F (1149 °C) minimum — Rolled Alloys · 1150 °C — VDM Metals. No single figure has been written; the sources give different bands.
Time
The ASTM texts give no time, they require the result (grain size). VDM Metals gives a soaking time based on thickness (d): for d <= 10 mm, 3 min/mm · for d = 10-20 mm, 30 min + (d-10) x 2 min/mm · for d > 20 mm, 50 min + (d-20) x 1 min/mm.
Cooling
Water quench or rapid air cool. VDM Metals gives water quenching; the 760-540 °C range is passed through quickly.
Purpose
Creep service above 593 °C. The ASTM B409 / B408 / B407 / B564 / B514 / B515 minimums apply in this condition.
The specification floor for 800HT is 50 °F higher than for 800H. The chemistry additionally limits Al+Ti to 0.85-1.20%. Together these two requirements give higher allowable stresses between 593 and 899 °C.
Temperature
SPECIFICATION FLOOR: 2100 °F (1149 °C) MINIMUM — the same figure in the texts of ASTM B409, B408 and B407.
Time
The ASTM texts give no time; the requirement is the grain size.
Cooling
Water quench or rapid air cool; the same practice as 800H.
Purpose
Creep service above 700 °C. In the ASME Code the allowable stresses between 1100 and 1650 °F are higher than those for 800H.
Specifications
ASTM B409 · B408 · B407 · B564 · B515. ASTM B514 DOES NOT COVER N08811.
DEFENCE METAL
GRAIN SIZE REQUIREMENT — the requirement that defines 800H and 800HT
Step
GRAIN SIZE REQUIREMENT — the requirement that defines 800H and 800HT
Summary
Plain grade 800 has NO grain size requirement. In 800H and 800HT the grain size is an acceptance criterion and is reported on the certificate.
Temperature
The associated annealing temperature: >= 1121 °C for N08810, >= 1149 °C for N08811.
Time
–
Cooling
–
Purpose
ASTM REQUIREMENT: annealed N08810 and N08811 shall conform to an average grain size of ASTM No. 5 OR COARSER (the same sentence appears in B407, B408, B409, B514, B515 and B564). ADDITIONAL PRODUCER REQUIREMENTS: Special Metals gives grain size by product form as plate ASTM 1-5, tube and pipe ASTM 1-5, sheet ASTM 2-5; VDM Metals requires >= 90 µm (ASTM No. 4), that is a coarser grain than the ASTM floor.
The forging and hot rolling range. This is not a hardening treatment but a forming range.
Temperature
900-1200 °C — VDM Metals. Hot bending 1000-1150 °C — VDM Metals. Sandmeyer gives 1205 °C for hot working.
Time
The specifications give no time; it depends on the section and the press capacity.
Cooling
The 760-540 °C range is passed through QUICKLY; the material is not held in that range, to avoid sensitization (Sandmeyer, Special Metals, VDM Metals).
Purpose
Forgings and hot-rolled product. A SOLUTION ANNEAL follows hot working.
Specifications
ASTM B564 (forgings) · ASTM B408 (bar).
DEFENCE METAL
COLD WORKING
Step
COLD WORKING
Summary
Cold work is the only route to higher strength; there is no precipitation hardening, and annealing removes the effect.
Temperature
Room temperature. More than 10% deformation calls for a solution anneal afterwards (VDM Metals).
Time
–
Cooling
–
Purpose
Forming. An anneal after cold work is mandatory to re-establish the grain size requirement.
Specifications
In ASTM B407 and B408 ‘cold-worked and annealed’ is a separate delivery condition.
DEFENCE METAL
After welding
Step
AFTER WELDING
Summary
Post-weld heat treatment is NOT REQUIRED in normal use (Sandmeyer, Haynes International). Preheat is not required either; for solid-solution nickel alloys ambient temperature counts as sufficient preheat (Haynes).
Temperature
For WELDED 800HT fabrication that will operate above 540 °C (1000 °F), heating at 899 °C (1650 °F) for about one hour per inch of thickness is recommended to avoid stress-relaxation grain-boundary cracking (Rolled Alloys). NO intermediate-temperature heat treatment is applied between 538 and 816 °C (1000-1500 °F) (Haynes International).
Note
Filler metal: ERNiCr-3 (Filler Metal 82) for service below 790 °C, ERNiCrCoMo-1 / ENiCrCoMo-1 (alloy 617 and Electrode 117) for service above 790 °C. ASME Section IX base metal P-No. 45.
DEFENCE METAL
Range to avoid
Step
HAZARD BANDS — the material is not held in these ranges
Temperature
STRESS RELAXATION CRACKING: 550-750 °C (1022-1380 °F) — VDM Metals. SENSITIZATION / CHROMIUM CARBIDE PRECIPITATION: 538-760 °C (1000-1400 °F) — Jacquet and Special Metals.
Time
No published time-temperature curve was found, so NO numerical time limit has been written for the band. VDM Metals reports that stress relaxation cracks may appear during continuous operation between 500 and 800 °C.
Result
NO stress-relief or post-weld heat treatment cycle that falls in this band is applied. The only accepted post-weld treatment is a full solution anneal (Haynes International).
Mechanism
Stress relaxation cracking: as residual stress relaxes at temperature, the strain concentrates at the grain boundaries and a crack runs along them; coarse grain increases the risk. Sensitization: chromium carbide precipitates at the grain boundaries and the adjacent region is depleted in chromium.
The diagram is schematic; the time axis is not to scale. No published TTT or CCT curve for N08810 / N08811 could be found, so NO CURVE IS DRAWN — only the cycle schematic is given. Incoloy 800H DOES NOT PRECIPITATION HARDEN — there is NO ageing condition such as H900 or H1025 and none should be sought. Incoloy 800H DOES NOT PRECIPITATION HARDEN. It is a solid-solution alloy and cannot be hardened by heat treatment. Strength is raised only by cold work, and annealing removes it again. No published TTT / CCT curve was found, so no curve is drawn. The diagram is schematic and the time axis is not to scale. What separates 800H from 800 is not the temperature but the RESULT: a grain size of ASTM 5 or coarser is an acceptance criterion and is reported on the certificate. Plain grade 800 carries no such requirement. The specification floor for 800HT is 50 °F (about 28 °C) higher than for 800H: 2100 °F against 2050 °F. This difference is not invented; it is written in the texts of ASTM B407, B408 and B409. Producer annealing temperatures differ and have NOT been averaged here; each band is given with its source. The VDM Metals grain size requirement (>= 90 µm, ASTM No. 4) is coarser than the ASTM floor. The two requirements are not the same, and the order must state which one applies. No separate STRESS-RELIEF recipe is given: typical stress-relief temperatures fall inside both the sensitization band (538-760 °C) and the stress relaxation cracking band (550-750 °C), so no invented figure has been written. The only accepted post-weld treatment is a full solution anneal. The 899 °C / one hour per inch post-weld treatment is given ONLY for welded 800HT fabrication that will operate above 540 °C (Rolled Alloys); it is not a general requirement.
Solution anneal at 1150–1200 °C, with time at temperature adjusted to achieve an ASTM grain size of 5 or coarser; 800HT specifically requires a minimum 1149 °C treatment. Stress relief begins at about 540 °C and is virtually complete after 870 °C; the guideline is 1 hour per inch (25 mm) of thickness, or 1½ hours at 870 °C, whichever is greater. Not hardenable by heat treatment: it is strengthened by solid solution, by carbon and carbides and by cold work, and at temperature by controlled coarse grain. Sensitisation window 540–760 °C (the underlying chromium-carbide precipitation runs 540–1095 °C); exposure there opens the alloy to intergranular attack in aggressive media. No claim is made about sigma phase — none of the sources reviewed discusses sigma for 800H, so neither freedom from it nor susceptibility to it should be asserted.
Machining: with coated carbide, 33.5–57.9 m/min (110–190 sfpm) at 0.20–0.89 mm/rev with good tool life; with high-speed steel, 10.7–29.0 m/min. “Readily machined by standard methods.” Hot forming 870–1200 °C; heavy forging down to 1010 °C, light working down to 870 °C. “No working should be done between 1200 and 1600 °F (650–870 °C).” That is a hard prohibition and the single most-ignored fabrication rule for this alloy. Cold forming: very ductile, and because the tensile/yield ratio exceeds 2, large amounts of cold work are possible before an intermediate anneal is needed. The corollary: cold-worked material re-annealed below 1150 °C will not meet the 800H grain-size requirement.
800H / 800HT · Service Behaviour
DEFENCE METAL
What sets the limit
Mechanical strength, not corrosion. Stress-rupture strength is negligible beyond 1095 °C while the oxide is still protective at 982 °C. The practical ceiling is wherever the design stress intersects the rupture curve: for pressure parts, the ASME ceiling (899 or 982 °C — disputed); for unpressurised furnace internals, considerably higher
Oxidation
Excellent, from the high Cr and Ni. Cyclic scaling tests at 980 and 1095 °C beat Type 309 and alloy 600. In refinery furnace atmospheres at 870–1150 °C, 6.0 mpy for 800H/800HT against 84.5 mpy for Type 309 — about a 14× advantage
Carburisation
100-hour test at 1095 °C in 2 % methane + 5 % argon in hydrogen, weight gain: 800H/800HT 21.58 mg/cm², Type 330 24.00, alloy 60012.30. An honest note: alloy 600 outperformed 800H in this specific test — do not overclaim carburisation resistance
Sulfidation
In hydrogen + 1.5 % H₂S, weight loss is 29.5 mg/cm² at 600 °C and 147.0 mg/cm² at 700 °C. The engineering message is that ~5× jump: sulfidation resistance degrades steeply with temperature, and the ~32 % nickel is a liability in high-sulfur service. This is not a sulfidation-first alloy
Nitriding
Nitrided depth 0.137 mm after one year in ammonia-converter conditions, against 1.08 mm for Type 304 — roughly 8× better. But the originator states that alloy 600 is usually preferred for nitriding service
Chloride stress-corrosion cracking
At ~30–35 % Ni the 800 family sits well above the ~8–12 % of 304/316, in the composition region where susceptibility falls away sharply. In practice it is used as an upgrade from austenitic stainless that has cracked. It is highly resistant but not immune — severe laboratory conditions can crack it; avoid claiming outright “immunity”
Aqueous corrosion
The commercial boundary: one mill states plainly that it is “not generally used under wet corrosive conditions”. This is a high-temperature alloy, not an aqueous-corrosion alloy
Frequently Asked Questions
800, 800H or 800HT — which do I order, and what fails if I get the wrong one?
All three share identical nickel (30–35 %), chromium (19–23 %) and iron (39.5 % min), so mill certificates look nearly the same. The differences are four lines: carbon, aluminium-plus-titanium, grain size and annealing temperature. Alloy 800 permits 0.10 % carbon maximum with no minimum, sets no grain-size requirement, and may be annealed as low as about 980 °C. Alloy 800H requires carbon 0.05–0.10 %, Al+Ti 0.30–1.20 %, an anneal at 1150–1200 °C and a grain size of ASTM 5 or coarser. Alloy 800HT tightens carbon to 0.06–0.10 % and Al+Ti to 0.85–1.20 %, with aluminium and titanium each at least 0.25 %, and mandates a minimum 1149 °C heat treatment. The rule ASTM prints in B407, B408, B409, B514 and B564 is unambiguous: N08800 is for service up to and including 1100 °F (593 °C); above that you need N08810 or N08811, because creep and stress-rupture resistance becomes the design basis and those grades are annealed to develop controlled coarse grain. The originator quotes a higher crossover, 1500 °F; take the conservative ASTM figure. What fails if you get plain 800 in an 800H application is not detectable at goods-in. Chemistry passes, room-temperature tensile passes — alloy 800 is actually stronger at room temperature. The failure is creep: fine-grained, low-carbon material has far lower rupture strength, and a component designed to 800H allowable stresses will bulge and rupture thousands of hours early. Always require the reported ASTM grain size on the certificate.
800H versus 330, 601 and 625 for high-temperature service
Alloy 800H (N08810) is the pressure-boundary workhorse. It has ASME Boiler and Pressure Vessel Code approval for Section VIII Division 1 construction — the originator cites allowable stresses to 982 °C via Code Case 1983 while a major distributor quotes 899 °C, so treat 899 °C as the conservative design ceiling — with useful oxidation resistance through 982 °C. Choose it whenever the part is a code-stamped pressure component. Alloy 330 (N08330, 34–37 % Ni, 17–20 % Cr, with a deliberate 0.75–1.50 % silicon addition) resists scaling to roughly 1095 °C and oxidation to about 1150 °C. The silicon gives it genuinely better carburisation resistance than 800H. It is the choice for furnace internals, retorts and radiant tubes — but it is not an 800H substitute for coded pressure parts. Alloy 601 (N06601, 58–63 % Ni, 21–25 % Cr and, critically, 1.0–1.7 % aluminium) is the oxidation champion, resisting oxidation to about 1200 °C with a tightly adherent scale that survives thermal cycling. Its ASME allowables are restrictive, though: Section I to only 482 °C and Section VIII Division 1 to 899 °C. Alloy 625 is a strength-and-aqueous-corrosion alloy serving from cryogenic to 982 °C, above which scaling becomes restrictive. Watch the grade: the originator gives Section VIII Division 1 approval as Grade 1 to just 649 °C and Grade 2 to 871 °C. Short version: 800H for coded pressure parts, 330 for carburising furnace hardware, 601 for extreme cyclic oxidation, 625 for strength plus wet corrosion.
What does “800H/800HT dual certified” actually mean, and when should I refuse it?
Dual certification to 800H and 800HT together is normal and entirely legitimate. Every 800HT limit sits inside the 800H limits — carbon 0.06–0.10 within 0.05–0.10, Al+Ti 0.85–1.20 within 0.30–1.20 — so a single heat can genuinely satisfy N08810 and N08811 at once, provided the grain size is ASTM 5 or coarser and it was annealed at 1150 °C or above. Major distributors stock exactly this material as one product, “800H/AT”. Accept it. The dual certification that deserves scrutiny is 800/800H. Chemically it can be honest: carbon of 0.05–0.10 % also satisfies alloy 800’s “0.10 % maximum”. But alloy 800 imposes no grain-size requirement and may be annealed as low as 980 °C, so the plain-800 line on the certificate provides cover for material that was processed as N08800 and never developed the coarse grain that 800H’s creep strength and ASME allowable stresses depend on. That material is a perfectly valid N08800 and a non-conforming N08810. Refuse it whenever the certificate does not state, explicitly, a reported ASTM grain size of 5 or coarser and an actual annealing temperature of 1150 °C or higher. A blank grain-size field is disqualifying, regardless of the heading on the document. Two related traps: alloy 800 itself has a second annealed grade at about 1150 °C, so anneal temperature alone proves nothing; and there is no ASTM welded-pipe specification covering 800HT at all — B514 lists only N08120, N08800 and N08810.
800 · 800H · 800HT — THE GRADE DIFFERENCE, READ FROM THE SAME STANDARDS
DEFENCE METAL
Grade
Carbon
Al + Ti
Grain-size requirement
Minimum annealing temperature
ASTM room-temperature minimum
Design regime
ASME ceiling
800 (N08800 · W.Nr. 1.4876)
0.10% max
Al 0.15-0.60% · Ti 0.15-0.60% · Al+Ti 0.30-1.20%
NONE — grain size is not an acceptance criterion in the standard
450 MPa tensile / 170 MPa yield / 30% elongation (the same row as 800H)
Creep strength above 700 °C (Special Metals)
HIGHER allowable stresses than 800H between 1100 and 1650 °F (593-899 °C); service to 1800 °F (982 °C) · NOT covered by ASTM B514
One basis only: the requirement sentences and mechanical minimum tables of the ASTM B409 / B408 / B407 / B564 / B514 / B515 texts. No producer typical values are used. The Ni (30.0-35.0%), Cr (19.0-23.0%) and Fe (39.5% min) bands are THE SAME for all three; only the DIFFERENCES are in the table. The difference is not in room-temperature strength: the ASTM minimum for 800H and 800HT is LOWER than for 800 (450/170 MPa against 520/205 MPa). The difference is that carbon is tied to a lower limit and that a grain size of ASTM 5 or coarser is made a REQUIREMENT; what this buys is creep and rupture strength above 593 °C. 800HT adds Al+Ti of 0.85-1.20% and a minimum annealing temperature 50 °F higher, and is rewarded in the ASME Code with higher allowable stresses between 593 and 899 °C. BELOW 593 °C the correct grade is 800. The Ni, Cr and Fe bands are the same for all three. The difference lies only in carbon, Al+Ti and the grain size requirement, so the grade cannot be told apart from the Ni-Cr-Fe figures on a mill certificate. The ASTM room-temperature minimums of 800H and 800HT are IDENTICAL. The difference shows not at room temperature but in the ASME Code allowable stresses between 593 and 899 °C. Material that meets both the N08810 and the N08811 requirements is supplied dual certified as 800H/800HT; that is a commercial practice, not a separate grade. No creep-rupture curve has been placed in this table: a set confirmed by four independent sources for the same temperature and the same duration could not be assembled.