Martensitic precipitation-hardening stainless steel. Hardening comes from nickel-aluminium precipitates rather than carbides, which is why carbon is held below 0.05%. Vacuum induction melting followed by consumable electrode remelting (VIM + VAR/ESR) is a specification requirement.
Forms
Round bar · Flat bar · Plate · Sheet · Tube · Forging
Standards
AMS 5629 (bars, wire, forgings, flash-welded rings, extrusions up to 305 mm nominal diameter — vacuum induction plus consumable electrode melted, premium aircraft-quality) · AMS 5864 (plate — vacuum induction plus consumable electrode melted) · AMS 5934 (bars, wire, forgings, rings, extrusions — “Extra High Toughness” grade, VIM plus consumable electrode melted) · AMS 5840 (welding wire, vacuum melted) · ASTM A564 / ASME SA-564 Grade XM-13 (bars, wire, shapes) · ASTM A693 / ASME SA-693 Grade XM-13 (plate, sheet, strip) · ASTM A705 / ASME SA-705 Grade XM-13 (forgings) · W.Nr. 1.4534 The SAE title of AMS 5629 carries the wording “Vacuum Induction Plus Consumable Electrode Melted, Premium Aircraft-Quality”: vacuum induction melting followed by consumable electrode remelting (VAR or ESR) is MANDATORY, not optional.
Advantage
Compared on the minima of one and the same standard (ASTM A564), the difference is numerical. The highest-strength condition of XM-13, H950: minimum 1515 MPa tensile / 1415 MPa yield.
Welding
Filler metal: the matching filler is AMS 5840 welding wire (13Cr – 8.0Ni – 2.3/2.4Mo – 1.1Al, vacuum melted). Where high weld strength is not needed, austenitic AWS ER308L may be used (High Temp Metals and ARMCO give it as the secondary option; that weld metal does not respond to ageing).
Limits
Service temperature: the sources conflict and no single ceiling figure can be given. The safe rule is this — service temperature must stay at least 28 °C (50 °F) BELOW the ageing temperature (Carpenter/ARMCO and High Temp Metals); an H1050 part is therefore not run above 538 °C, an H950 part not above 482 °C.
Compiled from manufacturer data sheets · confirm against the current specification before ordering
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Standards by Product FormConditionsHeat Treatment, Welding and MachiningWhen to Choose 13-8 MoFrequently Asked Questions
Corrosion resistance: Very good in terms of corrosion resistance, grade 1.4534 / 13-8 PH is used where high mechanical strength and high corrosion resistance are required together. One of the age-hardened (PH) materials, this grade has considerably better corrosion resistance than grade 630 (17-4 PH, 1.4542) and 15-5 PH (1.4545). PH 13-8 Mo is chosen where very high mechanical strength and very good corrosion resistance are required.
Weldability: As with all PH (age-hardened) materials, this grade has limited weldability.
Machinability: The purpose of this material is to deliver the highest level of mechanical strength together with very good corrosion resistance in extremely critical parts. Machinability is one of the last properties sought in this material, and the machinability of this grade is low.
Heat treatment: 13-8 PH / 1.4534 steel is put through special heat treatment techniques in order to gain hardness and durability. The treatment is generally carried out by solution treatment followed by air cooling.
Applications: The most common application area for PH 13-8 Mo stainless steel is aerospace. It is chosen for aircraft landing gear parts, aircraft landing gear gears, parts requiring high mechanical strength, valve and shaft components, shafts in contact with petrochemical fluids and working under load, and nuclear power plant shafts.
Because it is expensive, this grade is chosen in environments where the alternatives are not sufficient. As a highly specialised material, it is generally used in very specific components.
Chemical Composition
DEFENCE METAL
C
Max. 0.050
Mn
Max. 0.20
Si
Max. 0.10
P
Max. 0.010
S
Max. 0.008
Cr
Min. 12.25 · Max. 13.25
Ni
Min. 7.50 · Max. 8.50
Mo
Min. 2.00 · Max. 2.50
Al
Min. 0.90 · Max. 1.35
Mechanical Properties
DEFENCE METAL
Tensile Strength (MPa)
1480
Proof Stress (MPa)
1415
Elongation A50 mm
13
Hardness Brinell
– Max HB
Density
7.8 g/cm3
Melting Point
1405-1440 °C
Modulus of Elasticity
221 GB
Electrical Resistivity
0.0001 ohm-cm
Thermal Conductivity
14.0 W/m.K
Thermal Expansion
–
Standards and Equivalents · 13-8Ph
DEFENCE METAL
Trade name
13-8Ph
UNS
S13800
W.Nr (DIN/EN)
1.4534
AMS
5629 · 5864
ASTM
A564 · A693 · A705
Available forms
Round bar · Flat bar · Plate · Sheet · Tube · Forgings All forms are supplied to order.
Standards by Product Form
STANDARDS BY PRODUCT FORM
DEFENCE METAL
Product form
Standards
Round bar, flat bar, shapes
AMS 5629 (VIM plus consumable electrode melted, premium aircraft-quality; up to 305 mm diameter) · AMS 5934 (extra high toughness grade) · ASTM A564 / ASME SA-564 Grade XM-13 · W.Nr. 1.4534
The product forms were read from the defencemetal.com 13-8 PH page; the standard mapping was verified from independent sources.
PH 13-8 Mo (UNS S13800 / XM-13 / 1.4534) sits at the toughness end of the precipitation-hardening stainless family. Two features set it apart: it hardens not through copper but through a NiAl (nickel-aluminide) intermetallic, and it must be double melted (VIM + VAR or ESR) — which is where its transverse and through-thickness toughness comes from.
Standards by Product Form · PH 13-8 Mo (S13800 / XM-13)
DEFENCE METAL
Bar · Wire · Forgings · Rings · Extrusions
AMS 5629 (Condition A; VIM + VAR or ESR)
Bar (ASTM route)
ASTM A564 / ASME SA-564, Type XM-13
Forgings · Rings · Flanges
ASTM A705 / ASME SA-705, Gr. XM-13
Sheet · Plate · Strip
AMS 5864 · ASTM A693 (Type XM-13)
Extra high toughness (“Super Tough”)
AMS 5934 — VIM plus consumable-electrode vacuum melting, with tighter Si/Mn/P/S limits. This is the number to cite when guaranteed toughness is required
Welding wire
AMS 5840 (13Cr-8.0Ni-2.3Mo-1.1Al, vacuum-melted bare wire)
Welding electrode (covered)
— (no verifiable AWS covered-electrode class exists for S13800; the grade is welded GTAW/GMAW with bare wire)
Seamless / welded pipe · tube · fittings
— (no verifiable pipe, tube or fittings standard was found for S13800; fittings are machined from A564 bar or A705 forgings)
WARNING — catalogue traps. (1) AMS 5659 is not a 13-8 Mo specification — it is the 15-5 PH bar/wire/forging spec, and it is sometimes miscopied onto 13-8 Mo listings. (2) Some secondary datasheets publish “typical” mill test results as though they were specification values; the table below gives the AMS 5629 minimums (guaranteed) — typical values sit above these but cannot be held to contractually. (3) Published Charpy figures for 13-8 Mo are largely single-sourced; where a guaranteed impact or fracture toughness is required, the specification to cite is AMS 5934, not AMS 5629.
Composition (ASTM A564 / AMS 5629): C ≤0.05% · Cr 12.25–13.25% · Ni 7.50–8.50% · Mo 2.00–2.50% · Al 0.90–1.35% · Mn ≤0.10% · Si ≤0.10% · P ≤0.010% · S ≤0.008% · N ≤0.010%. Why the cleanliness matters: the very low carbon keeps chromium out of carbides, so it stays in solid solution for corrosion resistance and the alloy strengthens almost entirely through NiAl precipitation. The P and S limits — far tighter than typical 300-series levels — minimise grain-boundary segregation and sulphide inclusions, which is the real source of the grade’s high, uniform toughness in heavy sections, and is only achievable with VIM+VAR/ESR melting.
Conditions — AMS 5629 Minimums
STRENGTH BY AGEING CONDITION
DEFENCE METAL
Condition
Hardness
Yield MPa
Tensile MPa
Elongation
H950
≥ 45
1415
1515
10%
H1000
≥ 43
1310
1415
10%
H1025
≥ 41
1210
1280
11%
H1050
≥ 40
1140
1210
12%
H1100
≥ 34
930
1035
14%
H1150
≥ 30
620
930
14%
Condition A (solution treated)
≤ 38 (≤ 363 HB)
—
≤ 1205
—
All rows are ASTM A564/A564M Grade XM-13 (ASME SA-564) STANDARD MINIMUM values for the LONGITUDINAL direction. These are NOT manufacturer typical values. A separate column gives the TRANSVERSE reduction-of-area minimum from AMS 5629. This table is STANDARD MINIMA. Manufacturer typical values run above these minima (for example ARMCO, High Temp Metals and California Metal give a typical 47 HRC and 1551 MPa tensile at H950); typical values were not taken into the table because they could not be confirmed consistently across 4 independent sources. The H1150-M condition is NOT in this table. Its ASTM A564 minima could be confirmed by only 3 sources and did not meet the 4-source threshold, so the row was removed and moved to the “atlananlar” (omitted) list. The H1150-M heat treatment cycle is confirmed by 8 sources and therefore remains in the heat treatment diagram. The values apply to product up to 305 mm (12 in.) nominal diameter. The Brinell equivalents (430 · 400 · 380 · 372 · 313 · 283 HBW) were not taken into the table because they could be confirmed by only 2 sources.
HEAT TREATMENT — SCHEMATIC
1 · SOLUTION TREATMENT
927 °C (1700 °F); sources give a band of 910-940 °C (1675-1725 °F) 15-30 min; up to about 1 hour for heavy sections
2 · COOL
Cool to below 16 °C (60 °F) — air, oil, water or polymer. Required for complete transformation to martensite.
3 · AGEING
see the table below
DEFENCE METAL
Solution treatment
Step
Condition A (solution treated)
Temperature
927 °C (1700 °F); sources give a band of 910-940 °C (1675-1725 °F)
Time
15-30 min; up to about 1 hour for heavy sections
Cooling
Cool to below 16 °C (60 °F) — air, oil, water or polymer. Required for complete transformation to martensite.
DEFENCE METAL
Cryogenic step for RH950 (this condition only)
Step
Cryogenic step for RH950 (this condition only)
Requirement
Within 24 HOURS of solution treatment, cold treat to −73 °C (−100 °F), hold a minimum of 2 hours, air warm to room temperature; then age at 510 °C (950 °F) / 4 hours / air cool.
Note
No cryogenic treatment is required for the standard H conditions. RH950 does not appear in the standard condition list of ASTM A564 or AMS 5629.
DEFENCE METAL
H950
Step
H950
Temperature
510 °C (950 °F) ± 6 °C
Time
4 hours
Cooling
air
DEFENCE METAL
H1000
Step
H1000
Temperature
538 °C (1000 °F) ± 6 °C
Time
4 hours
Cooling
air
DEFENCE METAL
H1025
Step
H1025
Temperature
552 °C (1025 °F) ± 6 °C
Time
4 hours
Cooling
air
DEFENCE METAL
H1050
Step
H1050
Temperature
566 °C (1050 °F) ± 6 °C
Time
4 hours
Cooling
air
DEFENCE METAL
H1100
Step
H1100
Temperature
593 °C (1100 °F) ± 6 °C
Time
4 hours
Cooling
air
DEFENCE METAL
H1150
Step
H1150
Temperature
621 °C (1150 °F) ± 6 °C
Time
4 hours
Cooling
air
DEFENCE METAL
H1150-M
Step
H1150-M
Temperature
760 °C (1400 °F) → 621 °C (1150 °F)
Time
2 hours + 4 hours
Cooling
air after each cycle
Schematic; the time axis is not to scale. No published TTT/CCT curve was used for this alloy. Sources differ on solution treatment time: Carpenter, ATI, Rolled Alloys and NeoNickel give 15-30 min; High Temp Metals, ARMCO and California Metal give about 1 hour. It depends on section thickness. The ATI datasheet does not list the H1150-M condition; Carpenter, ARMCO, ASTM A564 and California Metal do.
PH 13-8 Mo · AMS 5629 Minimum Mechanical Properties
Overaged; hardness ≤ 302 HB. Best toughness and machinability
The reduction of area is specified separately in three directions: longitudinal (L), transverse (T) and short-transverse / through-thickness (ST). The signature of this grade is that the three values stay close together — in many wrought steels the short-transverse figure falls away sharply, and in 13-8 Mo it does not. That isotropy is the direct payoff of the clean melt and the very low P and S limits.
Heat Treatment, Welding and Machining
Heat treatment
The mechanism is precipitation of a finely dispersed, coherent NiAl intermetallic in a low-carbon martensitic matrix. This is a different mechanism from the copper-rich precipitates of 17-4 PH and 15-5 PH, and it is why 13-8 Mo has higher, more isotropic toughness. Solution treatment (Condition A): about 927 °C (1700 °F ±15–25 °F), held according to section thickness, then air or oil cooled to below 16 °C — no separate deep-freeze step is required. Ageing:4 hours ±15 min at the nominal temperature, air cool: H950 = 510 °C, H1000 = 540 °C, H1025 = 550 °C, H1050 = 565 °C, H1100 = 595 °C, H1150 = 620 °C. H1150M: 760 °C for 2 hours, then 620 °C for 4 hours, air cool. Standard delivery is Condition A.
Welding
Weldability is good: no preheat is required and no special interpass cooling is needed. GTAW is standard; resistance welding is also suitable. The matching filler is AMS 5840 bare wire — which must itself be vacuum melted with controlled interstitials, or the toughness match is lost. Post-weld ageing is required (roughly 480–620 °C for 1–4 hours, i.e. one of the standard H cycles). Where possible, weld in Condition A and then solution-treat and age the whole assembly; welding already-aged material locally over-ages the HAZ.
Machining
Machinability tracks hardness directly. In Condition A, cutting speeds run roughly 20–30% lower than for 17-4 PH or 302/304 austenitic stainless. The best machinability of the standard conditions is the overaged H1150M. Where complex features must be machined before final strengthening, the practical route is to machine in H1150M or Condition A and then re-solution and re-age; H950 and H1000 are the hardest conditions to machine.
When to Choose 13-8 Mo
Comparison · PH 13-8 Mo and the Other PH Grades
DEFENCE METAL
PH 13-8 Mo (S13800)
Precipitate: NiAl intermetallic. Melt: VIM + VAR or ESR. Contains 2.0–2.5% Mo — the best transverse and through-thickness toughness of the group, and the best pitting and crevice resistance
Precipitate: copper-rich. No molybdenum; better transverse toughness than 17-4 PH, below 13-8 Mo
Corrosion
General corrosion resistance approaches 304 in oxidising environments. For stress-corrosion cracking resistance, ageing at ≥538 °C is recommended; conversely the best general and salt-fog resistance is at H950 — corrosion resistance falls as ageing temperature rises
Service temperature
Sources report good oxidation resistance to about 595 °C; sustained service in roughly the 315–480 °C band may reduce toughness — this figure is single-sourced and should be confirmed for critical applications
Typical applications
Valve parts, fittings, cold-headed and machined fasteners, aircraft components, nuclear reactor and petrochemical components
Magnetic
Ferromagnetic, like all martensitic precipitation-hardening grades
Frequently Asked Questions
When does 13-8 Mo justify its premium over 17-4 PH or 15-5 PH?
Choose 13-8 Mo when the part is thick-section and load-bearing and needs guaranteed properties in the short-transverse (through-thickness) direction: large valve bodies, shafts, structural forgings — anywhere a crack could propagate along the weak axis of the material. Two things buy that isotropy: VIM + VAR (or ESR) double melting and the P ≤0.010% / S ≤0.008% limits, far tighter than standard-melt 17-4 or 15-5 PH. 17-4 PH and 15-5 PH are cheaper and machine faster, and are the right call for smaller parts or where through-thickness toughness is not the governing design case. The 2.0–2.5% molybdenum in 13-8 Mo also buys measurably better pitting and crevice resistance than either alternative, which can be decisive in oil-and-gas and marine-adjacent service.
Which H condition, and what is the strength–toughness trade-off?
H950 gives the highest strength (yield ≥1413 MPa, tensile ≥1517 MPa) and the best general corrosion resistance of the standard conditions, but the lowest ductility and toughness. Moving up the ageing ladder trades strength for ductility and impact toughness: H1000 and H1025 are the common “balanced” choices; H1100 and H1150 give up substantial strength for maximum ductility and machinability; and H1150M (double age) is the most ductile and machinable but lowest-strength condition, typically chosen for parts needing extensive machining or where fracture toughness governs. One important detail: if the application requires a guaranteed impact or fracture-toughness minimum, specify AMS 5934 rather than AMS 5629.
Does VIM-VAR need to be called out separately on the order?
Yes — and by specification number. AMS 5629 permits VAR or ESR as the second melt, so writing “13-8 Mo” alone does not guarantee VIM-VAR. For the tightest cleanliness and toughness guarantee, specify AMS 5934 (“extra high toughness”), which calls out VIM plus consumable-electrode vacuum melting and tighter residual limits. Relying on a distributor’s generic “13-8 Mo” listing without citing AMS 5629 or 5934 risks receiving single-melt or non-aerospace-grade material. Always verify the melting route and the specification number on the certificate.