{"id":3575,"date":"2026-09-16T11:01:54","date_gmt":"2026-09-16T08:01:54","guid":{"rendered":"https:\/\/www.defencemetal.com\/index.php\/en\/invar-36\/"},"modified":"2026-09-25T16:27:54","modified_gmt":"2026-09-25T13:27:54","slug":"invar-36","status":"publish","type":"page","link":"https:\/\/www.defencemetal.com\/index.php\/en\/invar-36\/","title":{"rendered":"Invar 36"},"content":{"rendered":"<p><!-- dm-hap --><\/p>\n<h1 class=\"dm-ust-baslik\" style=\"font-family:-apple-system,BlinkMacSystemFont,'Segoe UI',Helvetica,Arial,sans-serif !important;text-transform:none !important;font-size:27px;line-height:1.3;font-weight:800;color:#12303f;margin:0 0 10px;letter-spacing:-.01em;\">Invar 36 \/ (1.3912) \/ UNS K93600<\/h1>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:0 0 22px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"background:#12303f;padding:14px 16px 12px;position:relative;z-index:2;\">\n<div style=\"font-size:22px;font-weight:700;color:#fff;line-height:1.25;\">Invar 36<\/div>\n<div style=\"font-family:ui-monospace,Menlo,Consolas,monospace;font-size:12.5px;color:#b9cfdb;line-height:1.5;margin-top:5px;word-wrap:break-word;\">UNS K93600 (the same alloy also appears as K93601 and K93603 in ASTM and producer records) \u00b7 W.Nr. 1.3912 \u00b7 FeNi36 \/ Ni36 (DIN 1715, SEW 385) \u00b7 ~36% Ni \u2013 balance Fe. Specification limits: Ni 35.0-37.0% \u00b7 C 0.10% max \u00b7 Mn 0.60% max \u00b7 Si 0.35% max \u00b7 Cr 0.50% max \u00b7 Mo 0.50% max \u00b7 Cu 0.50% max \u00b7 P 0.025% max \u00b7 S 0.025% max. It is an austenitic iron-nickel alloy; it is not stainless and is not protected by chromium.<\/div>\n<div data-dmkars-blok=\"1\" style=\"border-top:1px solid rgba(255,255,255,.16);margin-top:13px;padding-top:11px;\">\n<div style=\"font-size:10px;letter-spacing:.09em;text-transform:uppercase;color:#7f9fb0;font-weight:700;margin-bottom:8px;\">Not to be confused with<\/div>\n<p><a href=\"https:\/\/www.defencemetal.com\/index.php\/2026\/09\/15\/invar-36-kovar-difference\/\" data-dmkars=\"1\" style=\"display:inline-block;padding:4px 11px;border:1px solid rgba(36,190,229,.45);background:rgba(36,190,229,.12);border-radius:99px;margin:0 6px 6px 0;font-size:12.5px;font-weight:600;color:#9fe2f7;text-decoration:none;\">Kovar<\/a><\/div>\n<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">For what<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">The iron-nickel alloy with the lowest thermal expansion. It is NOT PRECIPITATION HARDENABLE and cannot be hardened by heat treatment; its distinguishing property is not mechanical strength but its COEFFICIENT OF THERMAL EXPANSION.<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Forms<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">Round bar \u00b7 flat bar \u00b7 plate \u00b7 sheet \u00b7 strip \u00b7 tube \u00b7 wire \u00b7 forging. All forms are supplied to order.<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Standards<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">AMS \u2014 NO independent AMS product specification belonging to Invar 36 could be found. AMS-I-23011 (&#8216;Iron-Nickel Alloys for Sealing to Glasses and Ceramic&#8217;) uses a class system and Invar 36 is listed as Class 7 of that specification; this class assignment could be verified in only two independent sources. \u00b7 ASTM F1684 \u2014 iron-nickel and iron-nickel-cobalt alloys for low thermal expansion applications; it was the principal product specification for Invar 36 and was WITHDRAWN IN 2024 WITH NO REPLACEMENT. The last valid edition is F1684-06(2021). \u00b7 ASTM B753 Alloy T36 (thermostat metal) \u00b7 AFNOR NF A54-301 \u00b7 DIN 1715 \u00b7 SEW 385 \u00b7 GB\/T 4J36 \u00b7 Boeing D-33028 (producer\/customer specification).<br \/><span style=\"font-size:12.5px;color:#7b8f9b;line-height:1.6;display:inline-block;margin-top:6px;\">UNS TRAP: this alloy is not identified by a single UNS number. Special Metals gives &#8216;K93600 and K93601&#8217; for NILO alloy 36, Carpenter gives &#8216;K93601 \/ K93603&#8217; for its own Invar 36, while ASTM F1684 lists only K93603 (plus the free-machining K93050 and the\u2026<\/span><\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Advantage<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">Over 20-100 \u00b0C the mean linear coefficient of thermal expansion is about 1.2-1.5 ppm\/K (Special Metals NILO 36: 1.5 for 20-100 \u00b0C; Carpenter: 1.30 for 25-93 \u00b0C; Rolled Alloys: 1.44 for 21-100 \u00b0C; Nickel Institute and ESPI: 0.70 x 10-6\/\u00b0F over -18 to 93 \u00b0C = 1.26 ppm\/K;<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Welding<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">GTAW (TIG) and short-circuiting GMAW (MIG) are recommended (Nickel Institute). The filler metal must match the composition; matching filler wires sold as Invarod and CF36 are used. Heat input must be limited and the molten pool must not be overheated (Carpenter \/ High Temp Metals).<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#fdeceb;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#c0392b;font-weight:600;line-height:1.5;\">Limits<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;background:#fdeceb;\">ABOVE THE CURIE TEMPERATURE (about 277-279 \u00b0C) IT LOSES ITS LOW-EXPANSION PROPERTY. The expansion coefficient begins to rise well before that point: the 20-200 \u00b0C mean is 2.6 ppm\/K, the 20-300 \u00b0C mean 5.5 ppm\/K and the 20-500 \u00b0C mean 10.1 ppm\/K (Special Metals). Special Metals puts the inflection point at 220 \u00b0C, ESPI at 190 \u00b0C (375 \u00b0F).<\/div>\n<\/div>\n<div style=\"padding:14px;border-top:1px solid #eceff1;\"><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/contact\/\" style=\"display:inline-block;padding:11px 20px;font-size:14px;font-weight:700;text-decoration:none;margin:0 8px 6px 0;background:#dd3333;color:#ffffff;\">REQUEST A QUOTE<\/a><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nickel-alloys\/\" style=\"display:inline-block;padding:11px 20px;font-size:14px;font-weight:700;text-decoration:none;margin:0 8px 6px 0;font-weight:600;border:1px solid #12303f;color:#12303f;\">All nickel alloys &rarr;<\/a><span data-dm=\"dm-teknik\" style=\"cursor:pointer;display:inline-block;padding:11px 20px;font-size:14px;font-weight:700;text-decoration:none;margin:0 8px 6px 0;border:1px solid #dd3333;color:#dd3333;\">TECHNICAL DETAILS &darr;<\/span><\/div>\n<div style=\"padding:9px 14px;border-top:1px solid #eceff1;font-size:11.5px;color:#8a9aa4;line-height:1.5;\">Compiled from manufacturer data sheets \u00b7 confirm against the current specification before ordering<\/div>\n<\/div>\n<\/div>\n<p><!-- \/dm-hap --><!-- dm-nav --><\/p>\n<style>h4[id^=\"dm-b\"]{scroll-margin-top:120px}#dm-teknik{scroll-margin-top:120px}<\/style>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:0 0 22px;padding:12px 14px;\">\n<div style=\"font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;margin-bottom:9px;\">On this page &middot; click to jump<\/div>\n<div><span data-dm=\"dm-b0\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">What Invar 36 Is<\/span><span data-dm=\"dm-b1\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Standards by Product Form<\/span><span data-dm=\"dm-b2\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Code Acceptance and Temperature Limits<\/span><span data-dm=\"dm-b3\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Product Forms With NO Standard<\/span><span data-dm=\"dm-b4\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Chemical Composition<\/span><span data-dm=\"dm-b5\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Mechanical Properties<\/span><span data-dm=\"dm-b6\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Physical Properties<\/span><span data-dm=\"dm-b7\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Heat Treatment and Dimensional Stability<\/span><span data-dm=\"dm-b8\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Welding<\/span><span data-dm=\"dm-b9\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Machining<\/span><span data-dm=\"dm-b10\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Corrosion<\/span><span data-dm=\"dm-b11\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Frequently Asked Questions<\/span><span data-dm=\"dm-b12\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Common Datasheet Errors<\/span><\/div>\n<\/div>\n<p><script>(function(){function go(id){var e=document.getElementById(id);if(e){var s=document.scrollingElement||document.documentElement;var y=e.getBoundingClientRect().top+s.scrollTop-118;if(y-0-0-0-0!==y){y=0;}window.scrollTo(0,y);}}function bind(el){el.addEventListener(\"click\",function(ev){ev.preventDefault();go(el.getAttribute(\"data-dm\"));});}function init(){var l=document.querySelectorAll(\"[data-dm]\");Array.prototype.forEach.call(l,bind);if(location.hash){if(location.hash.indexOf(\"#dm-\")===0){try{history.replaceState(null,\"\",location.pathname+location.search);}catch(e){}window.scrollTo(0,0);setTimeout(function(){window.scrollTo(0,0);},80);}}}if(document.readyState===\"loading\"){document.addEventListener(\"DOMContentLoaded\",init);}else{init();}})();<\/script><!-- \/dm-nav --><br \/>\n<span id=\"dm-teknik\" style=\"display:block;height:0;overflow:hidden;\"><\/span><br \/>\nInvar 36, also widely known as Nilo Alloy 36, is a nickel-iron alloy. The material consists essentially of 36% nickel and 64% iron. The fundamental property of this alloy is its very low thermal expansion, which is why it is used in many measuring and control instruments. Because it expands so little it is frequently used in fields such as aerospace. It is also very often used in various composite materials, in reference lengths, in measuring and metrology instruments, in parts requiring high precision and in thermostat shafts. The material is also designated UNS K93600 and UNS K93601.<\/p>\n<p><strong>Machinability:<\/strong> Moderate difficulty can be expected in terms of machinability. Machining, welding and cold forming are generally possible, but they require particular care.<\/p>\n<p><strong>Machining:<\/strong> It can be machined by conventional techniques such as milling, turning and drilling. It is important, however, to use suitable cutting fluids in order to minimise the effects of temperature change and to obtain a good surface finish.<\/p>\n<p><strong>Welding:<\/strong> Welding can be carried out, although Invar 36 can present some difficulties. Heat treatment may be required after welding in order to preserve the original properties of the alloy.<\/p>\n<p><strong>Cold forming:<\/strong> Cold forming can be applied, but care should be taken in operations requiring high precision.<\/p>\n<p><strong>Hot forming:<\/strong> Hot working and forming can be carried out, but care and proper temperature control are important during the operation.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Chemical Composition (INVAR 36, Alloy 36) \u00b7 Alloy 36 (1.3912, NILO 36)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Ni<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">36.0%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Fe<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">64.0%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Mechanical Properties at Room Temperature<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Density (specific gravity)<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">8110 kg\/m\u00b3<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Melting Temperature<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">1430\u00b0C<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Yield Strength (20 \u00b0C)<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">240 MPa<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Tensile Strength (20 \u00b0C)<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">490 MPa<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div class=\"dm-std\" style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Standards and Equivalents \u00b7 Invar 36<\/div>\n<div data-dmtw=\"1\" style=\"position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;overflow-x:auto;\">\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Trade name<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Invar 36<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">UNS<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">K93600 \u00b7 K93601<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">W.Nr (DIN\/EN)<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">1.3912<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Available forms<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Round bar \u00b7 Flat bar \u00b7 Plate \u00b7 Sheet \u00b7 Tube \u00b7 Forgings<br \/><span style=\"font-size:13px;color:#6b7a84;\">All forms are supplied to order.<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<p><!-- dm-zengin --><\/p>\n<h4 id=\"dm-b0\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">What Invar 36 Is \u2014 and Why \u201cZero Expansion\u201d Is the Wrong Phrase<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\">Invar 36 (UNS <b>K93600 \/ K93601 \/ K93603<\/b> \u00b7 W.Nr. <b>1.3912<\/b> \u00b7 EN designation <b>Ni36<\/b> \u00b7 <b>FeNi36<\/b> \u00b7 Chinese <b>4J36<\/b>) is a binary iron-nickel alloy, nominally <b>36 % nickel, balance iron<\/b>. It contains no meaningful chromium, no meaningful molybdenum, does not precipitation harden, and is never bought for strength. <b>It exists for one property: an extraordinarily low coefficient of thermal expansion near room temperature.<\/b> Charles \u00c9douard Guillaume discovered it in 1895 and received the 1920 Nobel Prize in Physics for it.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>The physics of the effect also explains every one of the alloy&#8217;s limits.<\/b> The Invar effect arises from <b>spontaneous volume magnetostriction<\/b>: magnetic ordering swells the lattice in the direction opposite to normal thermal expansion, and the two effects roughly cancel. <b>This is a magnetic phenomenon.<\/b> As magnetic order weakens the cancellation degrades, and above the Curie temperature it disappears entirely \u2014 <b>the alloy then expands like any ordinary iron-nickel<\/b>. Low expansion is therefore not a material constant but <b>a behaviour valid inside a narrow temperature window<\/b>.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>This is the warning that must be published.<\/b> The <b>1.2\u20131.5 \u00d7 10\u207b\u2076\/K<\/b> figure datasheets put on the cover belongs to the <b>20\u2013100 \u00b0C<\/b> range. The same alloy gives <b>5.5 \u00d7 10\u207b\u2076\/K<\/b> over <b>20\u2013300 \u00b0C<\/b> and <b>10.1 \u00d7 10\u207b\u2076\/K<\/b> over <b>20\u2013500 \u00b0C<\/b> \u2014 at 500 \u00b0C Invar 36 is practically indistinguishable from ordinary steel. <b>Publishing a single expansion number for this alloy is a fatal error.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">The Controlled-Expansion Family \u00b7 Honest Positioning<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Invar 36<\/b><br \/>K93600\/K93603 \u00b7 1.3912<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Fe\u201336 Ni.<\/b> <b>1.5 \u00d7 10\u207b\u2076\/K<\/b> over 20\u2013100 \u00b0C \u2014 the lowest in the family. Inflection point <b>220 \u00b0C<\/b>, Curie temperature <b>279 \u00b0C<\/b>. <b>Does not match glass or ceramic<\/b> \u2014 it expands far too little. It is a dimensional stability alloy, not a sealing alloy<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Alloy 42 \/ NILO 42<\/b><br \/>K94100 \u00b7 1.3917<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Fe\u201342 Ni.<\/b> Inflection point <b>370 \u00b0C<\/b>, Curie <b>330 \u00b0C<\/b>. <b>4.0\u20134.7 \u00d7 10\u207b\u2076\/K<\/b> over 30\u2013300 \u00b0C \u2014 <b>matches silicon and alumina<\/b>. IC lead frames, semiconductor packages, glass-to-metal seals. <b>Sold as \u201cInvar 42\u201d but it is NOT Invar 36<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Alloy 48 \/ NILO 48<\/b><br \/>K94800<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Fe\u201348 Ni.<\/b> Inflection point <b>460 \u00b0C<\/b>. Matches soft (soda-lime) glasses<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Kovar \/ NILO K<\/b><br \/>K94610 \u00b7 1.3981<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Fe\u201329 Ni\u201317 Co.<\/b> Inflection point <b>450 \u00b0C<\/b>, Curie <b>435 \u00b0C<\/b>. <b>The SHAPE of its expansion curve is tailored to borosilicate glass<\/b> \u2014 the only true hermetic glass-to-metal sealing alloy in this family. <b>Not interchangeable with Invar 36<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Super Invar \/ Inovco<\/b><br \/>Fe\u201333 Ni\u20134.5 Co<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Cobalt shifts the expansion minimum to room temperature: <b>0.55 \u00d7 10\u207b\u2076\/K<\/b> (single source). The window is far narrower and the alloy <b>much more expensive<\/b>; it only makes sense for room-temperature metrology<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Trade names \u2014 not all of them are the same material<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Invar\u00ae<\/b> is a registered trademark of ArcelorMittal\/Aperam; <b>Nilo\u00ae 36<\/b> is Special Metals, <b>Pernifer\u00ae 36 \/ VDM\u00ae Alloy 36<\/b> is VDM Metals, <b>Invar\u00ae M93<\/b> is Aperam&#8217;s cryogenic grade. The Chinese equivalent is <b>4J36<\/b>. All belong to the Fe\u201336 Ni family, but <b>carbon and impurity ceilings differ from mill to mill<\/b> \u2014 and that is exactly what governs dimensional stability. LNG membrane grades such as <b>Aperam Invar M93<\/b> are produced and qualified as 0.7 mm strip through a separate route; they are not the same product as general-purpose Invar 36 plate.<\/p>\n<h4 id=\"dm-b1\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Standards by Product Form \u2014 and What Happened in 2024<\/h4>\n<p><!-- dm-diy-std --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">STANDARDS BY PRODUCT FORM<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:12px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"overflow-x:auto;position:relative;z-index:2;\">\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;min-width:430px;background:transparent;\">\n<tr>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Product form<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Standards<\/th>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Plate, sheet, strip<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">NO AMS product specification (the AMS-I-23011 Class 7 assignment could be verified in only two sources) \u00b7 ASTM F1684 \u2014 WITHDRAWN in 2024 with no replacement; last edition F1684-06(2021) \u00b7 AFNOR NF A54-301 \u00b7 DIN 1715 \u00b7 SEW 385 \u00b7 The acceptance criteria must be written into the purchase order<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Round bar, flat bar<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">NO AMS product specification \u00b7 ASTM F1684 (withdrawn) \u00b7 AFNOR NF A54-301 \u00b7 DIN 1715 \u00b7 SEW 385 \u00b7 GB\/T 4J36<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Wire, wire rod<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">NO AMS product specification \u00b7 ASTM F1684 (withdrawn) also covered wire \u00b7 DIN 1715 \u00b7 SEW 385<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Tube<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">NO AMS product specification \u00b7 ASTM F1684 (withdrawn) also covered tubing \u00b7 There is no product specification in force; it is sold to mill specification<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Forging<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">NO AMS product specification \u00b7 No ASTM product specification covering forgings was found \u00b7 The acceptance criteria are set by the purchase order text<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Thermostat metal (bimetal strip)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">ASTM B753 Alloy T36 \u2014 as the low-expansion component (Carpenter alloy page)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Aerospace \u2014 customer specification<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Boeing D-33028 (High Temp Metals) \u00b7 AMS-I-23011 Class 7 \/ MIL-I-23011 Class 7 (Ed Fagan; the class assignment rests on two sources)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Chemical composition and numbering<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">UNS K93600 (also K93601 and K93603) \u00b7 W.Nr. 1.3912 \u00b7 FeNi36 \/ Ni36<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\">Because there is no AMS number the AMS row on this map is empty; the AMS-I-23011 Class 7 assignment rests on two sources and is therefore not stated as established. The most important warning is that ASTM F1684 has been withdrawn: there is no product specification in force and the acceptance criteria must be written into the purchase order. On an order the expansion coefficient must always be given TOGETHER WITH ITS TEMPERATURE RANGE.<\/div>\n<\/div>\n<p><!-- \/dm-diy-std --><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Do not quote Invar 36 without reading this section.<\/b> The alloy&#8217;s position in the ASTM system changed fundamentally in 2024, and the large majority of distributor pages still publish the old picture.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Standards by Product Form \u00b7 Invar 36 (K93600 \/ K93603 \/ 1.3912)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Principal specification (all wrought forms)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>ASTM F1684 \u2014 \u201cIron-Nickel and Iron-Nickel-Cobalt Alloys for Low Thermal Expansion Applications\u201d. WITHDRAWN 2024, NO REPLACEMENT.<\/b> The last valid edition is F1684-06(2021). Grades covered: <b>K93603<\/b> (conventional Fe\u201336 Ni), <b>K93050<\/b> (free-machining Fe\u201336 Ni) and <b>K93500<\/b> (Fe\u201332 Ni\u20135 Co). Forms: <b>wire, rod, bar, strip, sheet, plate and tubing<\/b>; <b>K93050 bar only<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Plate \u00b7 sheet \u00b7 strip<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Beyond the withdrawn <b>F1684<\/b>, no independent ASTM product specification could be <b>verified<\/b>. In practice sold to <b>mill specification<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Rod \u00b7 bar<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Same situation. For the free-machining grade, the <b>K93050<\/b> line of the withdrawn F1684 was the only published reference<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Seamless pipe<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>There is NO ASTM specification.<\/b> F1684 covered <i>tubing<\/i> only; an NPS\/DN <b>pipe<\/b> specification never existed<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Welded pipe<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No specification.<\/b> Mill specification<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Tube \u00b7 capillary tube<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Was covered by the withdrawn <b>F1684<\/b>. Today: mill specification<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Wrought fittings \u00b7 flanges<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No specification.<\/b> There is no Invar equivalent of B366\/B462\/B564<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Forgings<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>No separate forging specification.<\/b> Chemistry to F1684, mechanicals by agreement<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Bolts \u00b7 nuts \u00b7 castings<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No specification.<\/b> Invar 36 has no cast equivalent; no standard for a cast Fe-Ni controlled-expansion grade could be found<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Welding wire<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>There is NO AWS classification.<\/b> Commercial products are proprietary: Special Metals <b>NILO Filler Metal CF36<\/b>, Aperam <b>Invar M93T<\/b>, Washington Alloy <b>Ni-Fe 36<\/b>. <b>No ERNiFe-36 class exists in AWS A5.14<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Covered electrode<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No specification<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Thermostat component \u00b7 bimetal<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>ASTM B753<\/b> (Thermostat Component Alloys) and <b>ASTM B388<\/b> (Thermostat Metal Sheet and Strip) are <b>active<\/b>, and Special Metals cites them for NILO 36. <b>But these are bimetal strip standards<\/b>, not structural Invar plate specifications<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Europe<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Material number <b>1.3912<\/b> exists; Special Metals cites <b>DIN 1715<\/b> and <b>SEW 385<\/b>, Rolled Alloys cites <b>AFNOR NF A54-301<\/b> (chemistry only). <b>No current, in-force EN product specification could be verified<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Aerospace \u00b7 composite tooling<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Boeing D-33028 \/ D-33028-2<\/b> is cited by two independent publishers and is the de facto specification for composite tooling plate<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>ASME IX P \/ F number<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>\u2014 could not be verified. Do NOT publish a P or F number.<\/b> No assigned ASME Section IX group number for Invar 36 could be confirmed<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Inspection document<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>EN 10204 3.1<\/b> as standard; <b>3.2<\/b> for independent inspection<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">What the withdrawal of F1684 means in practice<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Withdrawal does not ban the alloy; it removes the specification basis.<\/b> The consequences are concrete: (1) <b>\u201cconforms to ASTM F1684\u201d is no longer a reference to an in-force standard<\/b> \u2014 the purchase order must cite it <b>with its edition year<\/b> (\u201cF1684-06(2021), withdrawn edition\u201d); (2) mills are moving to their own internal specifications and <b>carbon, sulphur and silicon ceilings are diverging between mills<\/b>; (3) <b>third-party inspection<\/b> is now performed against <b>your order text<\/b>, not against an ASTM table. <b>Practical advice: write the chemical ranges, the heat treatment route and the expansion acceptance band EXPLICITLY into the order confirmation.<\/b> The same reasoning applies to <b>ASTM F15 (Kovar)<\/b> and <b>ASTM F30 (Fe-Ni sealing alloys)<\/b> \u2014 all three were withdrawn together in 2024.<\/p>\n<h4 id=\"dm-b2\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Code Acceptance and Temperature Limits \u2014 Here the Limit Is Physics, Not Code<\/h4>\n<p><!-- dm-diy-isil --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">HEAT TREATMENT \u2014 SCHEMATIC<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">1 \u00b7 FULL ANNEAL<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">1 \u00b7 FULL ANNEAL<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Applied after extensive forming or welding. It recrystallises the material and relieves internal stress. It gives no strength increase.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">790 \u00b1 28 \u00b0C (1450 \u00b1 50 \u00b0F) \u2014 Nickel Institute. 815 \u00b0C (1500 \u00b0F) \u2014 Carpenter Technology. 843 \u00b0C (1550 \u00b0F) \u2014 Carpenter \/ High Temp Metals. 830 \u00b0C (1525 \u00b0F) \u2014 first stage of the Special Metals NILO 36 stabilization cycle. The band given by four independent sources is 790-845 \u00b0C; it has not been averaged.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">30 minutes per 25 mm of section, not less than 15 minutes (Nickel Institute and Carpenter). 1 hour (High Temp Metals). One additional hour for each inch above one inch (High Temp Metals).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Cool in still air (Nickel Institute) or furnace cool (High Temp Metals). Where dimensional stability is required the part is quenched \u2014 see stage 2.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Typical annealed hardness about 70 HRB (Carpenter, ESPI, Ed Fagan).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Warning<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Invar 36 forms surface scale during heat treatment and the scale grows with both time and temperature. A controlled-atmosphere furnace should be used or the part cleaned afterwards. The part must be free of surface contaminants before heat treatment.<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">2 \u00b7 DIMENSIONAL STABILIZATION CYCLE \u2014 quench<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">2 \u00b7 DIMENSIONAL STABILIZATION CYCLE \u2014 quench<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">The first step of the multi-stage cycle used on parts that must hold precise dimensions. Rapid cooling from high temperature locks out the internal stress that shifts dimensions over time.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">815 \u00b0C (1500 \u00b0F) \u2014 Carpenter Technology and ESPI. 830 \u00b0C (1525 \u00b0F) \u2014 Special Metals NILO 36.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">30 minutes per 25 mm of section (Carpenter, Special Metals).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">WATER QUENCH \u2014 Carpenter, Special Metals, ESPI.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">3 \u00b7 DIMENSIONAL STABILIZATION CYCLE \u2014 intermediate hold<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">3 \u00b7 DIMENSIONAL STABILIZATION CYCLE \u2014 intermediate hold<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">The second step, which relieves the stress introduced by the quench.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">315 \u00b0C (600 \u00b0F) \u2014 Carpenter Technology and ESPI. 300 \u00b0C (570 \u00b0F) \u2014 Special Metals NILO 36.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">1 hour (Carpenter, Special Metals, ESPI).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Air cool.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">4 \u00b7 DIMENSIONAL STABILIZATION CYCLE \u2014 long hold<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">4 \u00b7 DIMENSIONAL STABILIZATION CYCLE \u2014 long hold<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">The last step of the three-stage cycle that Special Metals gives for NILO 36. It is NOT an ageing treatment; no precipitation occurs. Its purpose is to exhaust the remaining dimensional creep.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">100 \u00b0C (212 \u00b0F) \u2014 Special Metals NILO 36 (one independent source).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">48 hours (Special Metals).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Air cool.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">5 \u00b7 STRESS-RELIEF ANNEAL (optional)<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">5 \u00b7 STRESS-RELIEF ANNEAL (optional)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Applied between rough and finish machining and after minor weld repairs. It does not replace the full anneal.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">315 \u00b0C (600 \u00b0F) \u2014 High Temp Metals. 315-370 \u00b0C (600-700 \u00b0F) \u2014 ESPI.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">2 hours (High Temp Metals); about 1 hour (ESPI).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Air or furnace cool.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">6 \u00b7 REGION TO AVOID \u2014 precision service above 200 \u00b0C<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">6 \u00b7 REGION TO AVOID \u2014 precision service above 200 \u00b0C<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Not a heat treatment stage but a usage limit. The expansion coefficient rises markedly from 200 \u00b0C onward and above the Curie temperature (277-279 \u00b0C) the low-expansion property is lost entirely.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Inflection point 220 \u00b0C \u2014 Special Metals; 190 \u00b0C (375 \u00b0F) \u2014 ESPI. Curie temperature 277-279 \u00b0C \u2014 Carpenter, Nickel Institute, ESPI, Ed Fagan.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\">The diagram is schematic; the time axis is NOT to scale. No published TTT\/CCT curve was used, so no curve is drawn. Invar 36 is NOT PRECIPITATION HARDENABLE and cannot be hardened by heat treatment. The purpose of these cycles is not hardness but the RELIEF OF INTERNAL STRESS and DIMENSIONAL STABILITY. The word &#8216;ageing&#8217; is not used for this alloy; the long 100 \u00b0C hold in the fourth stage is not a precipitation step but a dimensional stability hold. Schematic; the time axis is not to scale. NOT PRECIPITATION HARDENABLE \u2014 there is no solution treatment plus ageing cycle. The purpose of the stages is dimensional stability. The last step of the three-stage stabilization cycle (100 \u00b0C \/ 48 hours) comes from a single independent source; the other two steps were found in three sources. The lower and upper ends of the annealing band belong to different producers; they have not been averaged.<\/div>\n<\/div>\n<p><!-- \/dm-diy-isil --><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>No published ASME pressure-vessel allowable stress table for Invar 36 could be verified.<\/b> Unlike the Ni-Cr-Mo corrosion alloys, this material is not marketed as an ASME Section VIII material; <b>do not look for a maximum code temperature \u2014 there isn&#8217;t one.<\/b> Invar 36&#8217;s real limits are <b>metallurgical<\/b>, and they are collected below.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">The Real Limits (physics, not code)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Fully stable dimensional window<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">After the three-step stabilisation route a manufacturer states <b>full stability up to 100 \u00b0C<\/b>. <b>That temperature, not the melting point, is the dimensional criterion<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Low-expansion window<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Roughly <b>\u2212250 \u00b0C to +200 \u00b0C<\/b> (mill statement). Above 200 \u00b0C expansion begins to climb noticeably<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Inflection point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>220 \u00b0C (430 \u00b0F)<\/b> \u2014 where the expansion curve bends. <b>This is NOT the same as the Curie temperature<\/b> and it is lower<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Curie temperature<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>279 \u00b0C (535 \u00b0F)<\/b> \u2014 three independent publishers. <b>[Conflict]<\/b> Two publishers put <b>230 \u00b0C<\/b> on this line, most likely the inflection point mislabelled. <b>Know both: 220\u2013230 \u00b0C is where the curve bends, 279 \u00b0C is where magnetic order is lost<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Behaviour above the Curie point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>The Invar effect ends.<\/b> Mean 20\u2013400 \u00b0C is <b>8.4<\/b>, mean 20\u2013500 \u00b0C is <b>10.1 \u00d7 10\u207b\u2076\/K<\/b>. Carbon steel is ~12; so <b>at 500 \u00b0C Invar has no expansion advantage left at all<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>The cryogenic side<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Essentially unlimited: <b>KCV &gt;200 J\/cm\u00b2 at \u2212196 \u00b0C<\/b>, <b>Rp0.2 870 MPa with 40 % elongation at \u2212269 \u00b0C<\/b> (mill data, longitudinal). <b>Ductile down to liquid helium temperature<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>The LNG membrane route<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">An LNG membrane is <b>not within ASME scope<\/b>. Approval runs through the <b>IMO IGC Code + classification society + the containment designer&#8217;s (GTT) type approval<\/b>. Material acceptance follows that chain, not an ASTM table<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Oxidation \u00b7 high temperature<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Invar 36 is not a high-temperature alloy.<\/b> With no chromium it forms no protective oxide above 500 \u00b0C and is not designed for sustained high-temperature service<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b3\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Product Forms With NO Standard \u2014 the Commercially Valuable Section<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>After the withdrawal of F1684 this section covers nearly the whole alloy.<\/b> These are the sentences a sales engineer should have memorised.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Specification Gaps for Invar 36<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>All wrought forms (post-2024)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">There is <b>no in-force ASTM product specification<\/b> for plate, sheet, strip, bar, wire or tube. The honest answer: <b>\u201cchemistry and expansion per the withdrawn F1684-06(2021) tables; mechanicals and heat treatment by order agreement.\u201d<\/b> If a customer demands \u201cInvar 36 to ASTM\u201d, state in writing that this is <b>a reference to a standard that no longer exists<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Pipe<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Never existed.<\/b> F1684 covered <i>tubing<\/i>, not pressure pipe. Invar pipework (cryogenic transfer lines, for example) is built to <b>project specification<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Flanges \u00b7 fittings \u00b7 valve bodies<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No standard.<\/b> An Invar flange can be machined from bar to ASME B16.5 dimensions, but <b>Invar is not in the B16.5 material list<\/b> \u2014 so a B16.5 pressure-temperature class <b>cannot be applied<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Castings<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>There is no standardised cast Invar grade.<\/b> In a casting, grain coarseness and segregation change expansion locally; a dimensionally critical part should be <b>machined from wrought product<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Welding consumables<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No AWS class.<\/b> This matters: if the filler&#8217;s expansion does not match the base metal, <b>the weld bead itself becomes an expansion defect<\/b>. Use only a <b>matched Fe\u201336 Ni filler with declared expansion<\/b> and <b>demand the filler&#8217;s expansion data on the certificate<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Spring wire \u00b7 cold-drawn wire<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">F1684 covered wire; after withdrawal it is <b>mill specification<\/b>. Also, cold work <b>changes<\/b> both expansion and dimensional stability \u2014 expansion data in the hard temper <b>differ from annealed data<\/b> and must be requested separately<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Additive manufacturing powder and parts<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No AM product specification for Invar 36 could be verified.<\/b> The literature indicates that expansion and corrosion behaviour of AM Invar may <b>differ<\/b> from wrought material; <b>do not sell AM Invar against a wrought datasheet<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>What the certificate actually rests on<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">An <b>EN 10204 3.1<\/b> certificate is issued against <i>something<\/i>. That something is no longer a standard \u2014 it is <b>your order text<\/b>. If chemical ranges, heat treatment route, expansion measurement band and acceptance criterion are not written into the order, <b>the certificate guarantees nothing<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b4\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Chemical Composition<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Invar 36 is a binary alloy: nickel and iron. Everything else is an impurity under a ceiling \u2014 and those impurities are exactly what governs dimensional stability.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Chemical Composition \u00b7 weight %<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Nickel<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>35.0\u201337.0<\/b> (withdrawn F1684 route and two mills). A third publisher gives a tighter <b>35.5\u201336.5<\/b>. <b>Expansion is extremely sensitive to nickel content<\/b>: the minimum sits near 36 %, and departure from it raises expansion <b>rapidly<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Iron<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Balance<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Carbon<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>\u22640.10<\/b> (F1684 route and Nickel Institute). One publisher gives <b>\u22640.15<\/b>, one mill runs a typical <b>0.02<\/b>. <b>[Conflict]<\/b> One European mill sheet shows <b>\u22640.4<\/b> \u2014 almost certainly a decimal error; <b>do not use that figure<\/b>. <b>Carbon is the primary driver of temporal dimensional instability<\/b> (see below)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Manganese<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>\u22640.60<\/b> \u00b7 one mill typical 0.35<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Silicon<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>\u22640.35<\/b> \u00b7 two publishers \u22640.40 \u00b7 one mill gives \u22640.50<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Phosphorus \u00b7 Sulphur<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>P \u22640.025 \u00b7 S \u22640.025<\/b> (F1684 route). One European mill publishes <b>P \u22640.015 \u00b7 S \u22640.015<\/b>, one publisher <b>P \u22640.006 \u00b7 S \u22640.004<\/b>. <b>For material that will be welded, specify low S and P<\/b> \u2014 they govern hot cracking<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Chromium<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>\u22640.50<\/b> \u00b7 two publishers \u22640.25. <b>This is an impurity ceiling; it confers no corrosion resistance<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Copper \u00b7 Molybdenum<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Cu \u22640.50 \u00b7 Mo \u22640.50<\/b> (F1684 route)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Cobalt<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>\u22640.50<\/b> (single source). <b>If cobalt is added deliberately the alloy is no longer Invar 36<\/b> \u2014 Fe\u201333 Ni\u20134.5 Co is Super Invar<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Ultra-pure grade (reference)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">The patent literature specifies <b>C &lt;0.01<\/b> and <b>Mn, Si, P, S and Al each \u22640.01<\/b> for dimensionally stable Invar. Commercial Invar 36 is not that material; that is a metrology-grade product<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">The one sentence of chemistry that reaches purchasing<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>In Invar 36 the purpose of chemistry is not corrosion but dimension.<\/b> Carbon and interstitial impurities redistribute over time, and this produces a <b>measurable dimensional drift<\/b>. The published range is striking: commercial Invar materials have been reported to change dimension by <b>1.5 to 27 ppm per year<\/b>, and worst cases as high as <b>+11.0 ppm per day at 20 to 70 \u00b0C<\/b> have been reported. The same literature shows that with ultra-low carbon and impurities plus the correct stabilisation route, <b>1 ppm per year<\/b> is achievable. <b>If you are buying a metrology frame or a lithography stage, demand the CARBON value and the stabilisation records, not just the chemical range.<\/b><\/p>\n<h4 id=\"dm-b5\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Mechanical Properties<\/h4>\n<p><!-- dm-diy-sert --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">STRENGTH VALUES<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:12px 10px 0;\"><svg viewBox=\"0 0 740 400\" style=\"width:100%;height:auto;display:block;\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\" role=\"img\"><rect x=\"16\" y=\"6\" width=\"12\" height=\"12\" fill=\"#12303f\"\/><text x=\"34\" y=\"16\" font-size=\"11.5\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Yield (MPa)<\/text><rect x=\"146\" y=\"6\" width=\"12\" height=\"12\" fill=\"#7fa8bd\"\/><text x=\"164\" y=\"16\" font-size=\"11.5\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Tensile (MPa)<\/text><text x=\"16\" y=\"44\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed, 20 \u00b0C<\/text><rect x=\"16\" y=\"50\" width=\"545.2\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"568.2\" y=\"62\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">490<\/text><rect x=\"16\" y=\"68\" width=\"267.0\" height=\"15\" fill=\"#12303f\"\/><text x=\"290.0\" y=\"80\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">240<\/text><text x=\"16\" y=\"108\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed, 20 \u00b0C \u2014 Carpenter typical<\/text><rect x=\"16\" y=\"114\" width=\"498.5\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"521.5\" y=\"126\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">448<\/text><rect x=\"16\" y=\"132\" width=\"307.1\" height=\"15\" fill=\"#12303f\"\/><text x=\"330.1\" y=\"144\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">276<\/text><text x=\"16\" y=\"172\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed, 100 \u00b0C<\/text><rect x=\"16\" y=\"178\" width=\"478.4\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"501.4\" y=\"190\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">430<\/text><rect x=\"16\" y=\"196\" width=\"267.0\" height=\"15\" fill=\"#12303f\"\/><text x=\"290.0\" y=\"208\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">240<\/text><text x=\"16\" y=\"236\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed, 300 \u00b0C<\/text><rect x=\"16\" y=\"242\" width=\"456.2\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"479.2\" y=\"254\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">410<\/text><rect x=\"16\" y=\"260\" width=\"122.4\" height=\"15\" fill=\"#12303f\"\/><text x=\"145.4\" y=\"272\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">110<\/text><text x=\"16\" y=\"300\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed, 500 \u00b0C<\/text><rect x=\"16\" y=\"306\" width=\"230.3\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"253.3\" y=\"318\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">207<\/text><rect x=\"16\" y=\"324\" width=\"84.6\" height=\"15\" fill=\"#12303f\"\/><text x=\"107.6\" y=\"336\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">76<\/text><text x=\"16\" y=\"364\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed \u2014 upper bound (acceptance ceiling)<\/text><rect x=\"16\" y=\"370\" width=\"652.0\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"675.0\" y=\"382\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">586<\/text><\/svg><\/div>\n<div style=\"padding:12px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"overflow-x:auto;position:relative;z-index:2;\">\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;min-width:430px;background:transparent;\">\n<tr>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Condition<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Hardness<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Yield MPa<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Tensile MPa<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Elongation<\/th>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Annealed, 20 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">240-290<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">490<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">42%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Annealed, 20 \u00b0C \u2014 Carpenter typical<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">70 HRB<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">276<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">448<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">35%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Annealed, 100 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">240<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">430<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">42%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Annealed, 300 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">110<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">410<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">45%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Annealed, 500 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">76-93<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">207-290<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">53-68%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Annealed \u2014 upper bound (acceptance ceiling)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">70 HRB max<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">586 max<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\"><b style=\"color:#12303f;\">Because ASTM F1684 was withdrawn in 2024, this alloy has NO specification minimum in force. Every row below is a PRODUCER TYPICAL VALUE and cannot be used as a specification minimum. Because Invar 36 is not precipitation hardenable, the rows are split by TEMPERATURE and TEMPER, not by ageing condition. This alloy is bought for its expansion coefficient and not for its strength; this table is supplementary, not decisive.<\/b> In the chart, a value given as a range is drawn at its lower bound; the full range is in the table. There is NO SPECIFICATION MINIMUM in force; ASTM F1684 was withdrawn in 2024. All rows are producer typical values. There is no precipitation hardening; the rows are not split by ageing condition. The 100 \u00b0C, 300 \u00b0C and 500 \u00b0C rows come from one or two sources, and the source count is stated beside them. This alloy is bought for its expansion coefficient and not for its strength.<\/div>\n<\/div>\n<p><!-- \/dm-diy-sert --><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Invar 36 is a soft alloy and is never bought for strength.<\/b> Do not mix the two tables below: the first is typical annealed data versus temperature, the second is cold-worked tempers.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Annealed \u00b7 Typical Values vs Temperature (mill data, not guaranteed)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">20 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm <b>490 MPa<\/b> \u00b7 Rp0.2 <b>240 MPa<\/b> \u00b7 A <b>42 %<\/b> \u00b7 Reduction of area 70 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">100 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Rm 430 \u00b7 Rp0.2 180 \u00b7 A 43 % \u00b7 70 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">200 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm 430 \u00b7 Rp0.2 110 \u00b7 A 45 % \u00b7 70 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">300 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Rm 410 \u00b7 Rp0.2 93 \u00b7 A 48 % \u00b7 70 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">400 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm 350 \u00b7 Rp0.2 93 \u00b7 A 53 % \u00b7 70 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">500 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Rm 290 \u00b7 Rp0.2 93 \u00b7 A 59 % \u00b7 69 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">600 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm 210 \u00b7 Rp0.2 77 \u00b7 A 68 % \u00b7 67 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Note<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Yield strength has already halved by 200 \u00b0C.<\/b> If Invar is used as a load-bearing member, design with the yield <b>at service temperature<\/b>, not at room temperature<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">By Temper (second mill source)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Annealed<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rp0.2 <b>276 MPa<\/b> \u00b7 Rm <b>448 MPa<\/b> \u00b7 A <b>35 %<\/b> \u00b7 Reduction of area 65 % \u00b7 <b>70 HRB<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Cold drawn<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Rp0.2 <b>483 MPa<\/b> \u00b7 Rm <b>621 MPa<\/b> \u00b7 A <b>20 %<\/b> \u00b7 60 % \u00b7 <b>90 HRB<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Cold rolled strip<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rp0.2 <b>679 MPa<\/b> \u00b7 Rm <b>717 MPa<\/b> \u00b7 A <b>5.5 %<\/b> \u00b7 <b>98 HRB<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Hardness bands<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Annealed <b>\u2264150 HV (\u226480 HRB)<\/b> \u00b7 full hard <b>\u2265220 HV (\u226596 HRB)<\/b>. <b>Always state the scale<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Strip product band<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">One distributor gives Rm as a band of <b>400\u2013500 MPa<\/b> (58\u201372.5 ksi), A <b>34 %<\/b> and <b>60\u201385 HRB<\/b> \u2014 <b>that is a BAND<\/b>, not a single value<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Critical warning<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Cold work changes both expansion and dimensional stability.<\/b> Expansion data for hard temper Invar differ from annealed data and are almost never published on distributor pages. <b>Machine dimensionally critical parts from annealed material<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Cryogenic Data \u2014 the Alloy&#8217;s Second Selling Argument<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>\u2212196 \u00b0C (liquid nitrogen)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>KCV &gt;200 J\/cm\u00b2<\/b> (mill data). <b>Fatigue limit 700 MPa at \u2212196 \u00b0C<\/b> \u2014 very close to the yield strength, which is decisive for a cyclically loaded LNG membrane<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>\u2212253 \u00b0C (liquid hydrogen)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Annealed tensile <b>~869 MPa (126,000 psi)<\/b> \u00b7 yield <b>~759 MPa (110,100 psi)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>\u2212269 \u00b0C (liquid helium)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rp0.2 <b>870 MPa<\/b> \u00b7 elongation <b>40 %<\/b> (longitudinal, mill data). <b>Good toughness down to liquid helium temperature<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Long-term cryogenic exposure<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Exposure for up to several thousand hours at \u2212196 \u00b0C, with and without applied stress, has not altered the mechanical properties<\/b> \u2014 the one sentence worth telling a cryogenic buyer<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Ductile\u2013brittle transition<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Effectively none.<\/b> Being an FCC (\u03b3) iron-nickel solid solution it does not show the transition-temperature behaviour of ferritic steels<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b6\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Physical Properties<\/h4>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Physical Properties \u00b7 Invar 36<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Density<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>8.05\u20138.13 g\/cm\u00b3 \u00b7 [Conflict]<\/b> Two publishers give 8.05 (0.291 lb\/in\u00b3), two give 8.11 (0.293 lb\/in\u00b3), one gives 8.13. <b>Use 8.1 g\/cm\u00b3 for calculation and allow tolerance<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Melting point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>1427\u20131430 \u00b0C<\/b> (2600\u20132605 \u00b0F) \u2014 three publishers. <b>[Conflict]<\/b> One publisher gives <b>1450 \u00b0C<\/b>; that is the Kovar and alloy 48 value, probably a row shift<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Thermal conductivity (20 \u00b0C)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>10.0\u201310.5 W\/m\u00b7K.<\/b> <b>Roughly one fifth that of carbon steel.<\/b> This is why heat piles up at the tool tip during machining and why composite tools take so long to heat through<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Electrical resistivity<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>80\u201382.3 \u00b5\u03a9\u00b7cm<\/b> at 20 \u00b0C, rising with temperature: <b>~121 \u00b5\u03a9\u00b7cm at 600 \u00b0C<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Specific heat<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>0.515 kJ\/kg\u00b7K<\/b> (0.123 Btu\/lb\u00b7\u00b0F)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Modulus of elasticity<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Annealed <b>~141 GPa<\/b> (20.5 \u00d7 10\u00b3 ksi) \u00b7 cold rolled <b>~148 GPa<\/b> (21.5 \u00d7 10\u00b3 ksi) \u00b7 another publisher 140 GPa. <b>Well below steel&#8217;s ~200 GPa<\/b> \u2014 the difference matters in stiffness calculations<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Curie temperature<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>279 \u00b0C (535 \u00b0F)<\/b> \u2014 three publishers. <b>[Conflict]<\/b> two publishers write 230 \u00b0C<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Inflection point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>220 \u00b0C (430 \u00b0F)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Magnetic behaviour<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Ferromagnetic.<\/b> That is the cause of the Invar effect, not a side effect. <b>Saturation magnetostriction ~+4 ppm at 1 T<\/b> \u2014 meaning <b>Invar 36 changes dimension in a magnetic field<\/b>. In precision metrology environments with magnetic fields (near MRI, accelerators, magnetic measuring benches) this is a real error source, and it is almost never mentioned on datasheets<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>The commercially meaningful point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Invar 36 is <b>magnetic, rust-prone, soft, a poor heat conductor and difficult to machine<\/b>. All of that is accepted for <b>one advantage<\/b>: <b>1.5 \u00d7 10\u207b\u2076\/K<\/b> over 20\u2013100 \u00b0C. <b>If that advantage does not hold across your temperature range, the alloy has no advantage at all<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">MEAN COEFFICIENT OF THERMAL EXPANSION \u00b7 10\u207b\u2076\/K \u00b7 THE MOST IMPORTANT TABLE ON THIS PAGE<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">\u2212200 \u2192 20 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>1.5<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">\u2212100 \u2192 20 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>1.3<\/b> \u2014 <b>the family minimum<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">20 \u2192 100 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>1.5<\/b> \u2014 <b>this is the number catalogues publish<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">20 \u2192 150 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>2.0<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">20 \u2192 200 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>2.6<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">20 \u2192 250 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>3.5<\/b> \u2014 <b>entering the inflection region<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">20 \u2192 300 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>5.5<\/b> \u2014 <b>3.7 times<\/b> the 20\u2013100 \u00b0C value<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">20 \u2192 350 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>7.2<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">20 \u2192 400 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>8.4<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">20 \u2192 450 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>9.3<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">20 \u2192 500 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>10.1<\/b> \u2014 <b>the Invar effect is over<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Verification<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">This table was <b>independently confirmed<\/b> by unit-converting a second manufacturer&#8217;s \u00b0F table (values 0.8 \/ 0.7 \/ 0.8 \/ 1.1 \/ 1.4 \/ 1.9 \/ 3.1 \/ 4.0 \/ 4.7 \/ 5.2 \/ 5.6 \u00d7 10\u207b\u2076 in\/in\u00b7\u00b0F). <b>Two publishers give the same curve<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>For comparison<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Carbon steel ~12 \u00b7 316L ~16 \u00b7 aluminium ~23 \u00b7 <b>Invar 36 (20\u2013100 \u00b0C) 1.5<\/b>. The advantage is <b>8\u201310 fold over 20\u2013100 \u00b0C<\/b> and <b>nil over 20\u2013500 \u00b0C<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b7\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Heat Treatment and Dimensional Stability<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>In Invar 36 heat treatment is done for DIMENSION, not for strength. In this alloy this section replaces the solution-annealing section of a corrosion alloy as the critical one.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Three Distinct Routes \u2014 They Do NOT Substitute for Each Other<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>1 \u00b7 Full anneal (softening)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>790 \u00b0C<\/b>, <b>30 minutes per inch of thickness<\/b>, <b>air cool<\/b> (one mill). An alternative published route: <b>843 \u00b0C (1550 \u00b0F) for 1 hour<\/b>, air or furnace cool. Its purpose is to <b>restore ductility<\/b> after heavy forming or welding. <b>It does not deliver dimensional stability<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>2 \u00b7 MAXIMUM DIMENSIONAL STABILITY (three-step route)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>(a)<\/b> heat to <b>815 \u00b0C<\/b>, hold 30 minutes per inch, <b>WATER QUENCH<\/b>; <b>(b)<\/b> reheat to <b>315 \u00b0C<\/b> for <b>1 hour<\/b>, air cool; <b>(c)<\/b> age at <b>93 \u00b0C for 24\u201348 hours<\/b>. <b>A second manufacturer publishes the same route as 830 \u00b0C \/ water quench + 300 \u00b0C \/ 1 h + 100 \u00b0C \/ 48 h<\/b> and states the outcome plainly: <b>full stability up to 100 \u00b0C<\/b>. <b>The quench step is not optional<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>3 \u00b7 Stress relief (intermediate)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>315\u2013425 \u00b0C<\/b>; a published typical practice is <b>2 hours at 315 \u00b0C<\/b>, air or furnace cool. Applied <b>between roughing and finishing, and after every heavy cut<\/b>. Skip it and the part leaves the machine on size, then <b>drifts over months<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Heating and cooling RATE<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Published rule: heat at <b>~28 \u00b0C (50 \u00b0F) per hour<\/b> and cool at <b>~28 \u00b0C per hour<\/b> until below 315 \u00b0C. The patent literature limits furnace cooling to <b>\u226455 \u00b0C\/h (100 \u00b0F\/h)<\/b> down to 150 \u00b0C. <b>Fast cooling introduces fresh stress and wastes the entire treatment<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Heavy section rule<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Add one hour for each additional inch above 25 mm (1 inch)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Natural ageing<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">For metrology-grade parts, classic practice is to <b>let the part sit for months and re-measure<\/b>. The literature describes this as \u201c<b>many years of natural and artificial ageing<\/b>\u201d \u2014 the modern three-step route was developed to shorten it<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Temporal instability \u2014 with numbers<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Invar 36 changes dimension on its own over time, and that is not a defect but the nature of the alloy.<\/b> The published range: commercial Invar 36 materials have shown <b>1.5 to 27 ppm per year<\/b> of dimensional change, and in the worst reported cases values as high as <b>11.0 ppm per day at 20 to 70 \u00b0C<\/b>. The change is <b>a carbon-dependent phenomenon<\/b>. When carbon and the Mn\/Si\/P\/S\/Al impurities are each held <b>below 0.01 %<\/b> and the three-step route above is applied, the literature reports <b>1 ppm per year stability together with &lt;1 \u00d7 10\u207b\u2076\/\u00b0C expansion<\/b>. <b>Commercial Invar 36 is not that material.<\/b> On a one-metre optical bench, 27 ppm per year means <b>27 micrometres per year<\/b> \u2014 unacceptable for most precision optics. <b>For dimensionally critical work, demand the stabilisation records and the carbon value on the certificate.<\/b><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>A second and less known effect: magnetic history.<\/b> Invar is ferromagnetic and has a <b>positive saturation magnetostriction of about 4 ppm<\/b>. An Invar part that has passed through a strong magnetic field, or been machined on a magnetic chuck, can show a <b>measurable permanent dimensional change<\/b> after the field is removed. <b>Magnetic chucks, magnetic lifters and magnetic particle inspection should not be used on dimensionally critical Invar parts<\/b>; if they have been, the part should be <b>demagnetised and re-stabilised<\/b>.<\/p>\n<h4 id=\"dm-b8\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Welding<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Invar 36 is weldable \u2014 but \u201cweldable\u201d carries an unusual meaning here. The problem is not strength; it is the EXPANSION of the weld bead.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Welding Parameters and Rules<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Recommended processes<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>GTAW (TIG)<\/b> and the <b>short-circuiting mode of MIG<\/b>. LNG membrane production uses <b>PAW (plasma) and automatic GTAW<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>NOT recommended<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>MIG spray transfer and submerged arc welding are not recommended<\/b> (mill statement). Both deliver high heat input and Invar does not tolerate it<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Matched filler (first choice)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Proprietary <b>Fe\u201336 Ni fillers with titanium and manganese additions<\/b>: Special Metals <b>NILO Filler Metal CF36<\/b>, Aperam <b>Invar M93T<\/b>, Washington Alloy <b>Ni-Fe 36<\/b> (typical: Ni 35.0\u201338.0 \u00b7 C \u22640.10 \u00b7 Mn \u22640.60 \u00b7 Si \u22640.35 \u00b7 Cu \u22640.50 \u00b7 Cr \u22640.50 \u00b7 Co \u22641.00 \u00b7 Mo \u22640.50). <b>The Ti and Mn additions are there to suppress porosity and hot cracking<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Nickel-base fillers (second choice)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Published alternatives: <b>INCONEL Filler Metal 92<\/b>, <b>Nickel Filler Metal 61<\/b>, <b>INCONEL Filler Metal 82<\/b>, <b>HASTELLOY alloy W<\/b>; for covered electrodes <b>Nickel Welding Electrode 141<\/b>, <b>INCO-WELD A \/ B<\/b>. <b>WARNING: none of these matches Invar&#8217;s expansion.<\/b> Use them only where expansion matching does not matter<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>The expansion-matching rule<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>If the filler&#8217;s expansion does not match the base metal, the bead becomes an expansion defect.<\/b> In an LNG membrane or an optical bench this produces <b>local, repeatable distortion<\/b> along the weld line. <b>Demand expansion data on the filler certificate<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Heat input<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Keep it low.<\/b> The mill&#8217;s sentence is explicit: <b>\u201ccaution must be taken so as not to overheat the molten metal.\u201d<\/b> High heat input produces a coarse-grained bead and a wide HAZ; both locally corrupt expansion behaviour<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Cleanliness and porosity<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Invar is porosity-prone.<\/b> Oil, moisture, paint, marker ink and fingerprints must be removed completely before welding. Shielding gas must be <b>dry argon<\/b>; wet gas leads directly to porosity<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Hot cracking<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Governed by sulphur and phosphorus.<\/b> Specify <b>low S and P<\/b> for material to be welded (one European mill runs \u22640.015\/\u22640.015, one publisher \u22640.004\/\u22640.006). Watch for <b>crater cracks<\/b> as in stainless practice<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Preheat \u00b7 interpass<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No preheat required.<\/b> Keep interpass temperature <b>low<\/b> \u2014 high interpass does the same damage as high heat input. <b>A numerical interpass ceiling could not be independently verified<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Post-weld treatment<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>For dimensionally critical parts, post-weld heat treatment is NOT optional.<\/b> Welding erases the entire stabilisation history. After heavy welding: <b>full anneal + three-step stabilisation<\/b>; after light welding at minimum <b>2 hours stress relief at 315 \u00b0C<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b9\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Machining \u2014 Invar Is Difficult to Machine; Say So Up Front<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Invar 36 is NOT an easy material to machine, and saying so at the quotation stage beats saying so at the delivery stage.<\/b> The alloy work-hardens aggressively like austenitic stainless steel, produces <b>stringy, gummy chips<\/b> that birdnest around the tool and block coolant from the cutting zone. With one fifth the thermal conductivity of steel, <b>heat accumulates at the tool tip<\/b>.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>The single most common mistake<\/b> is letting the tool dwell or ride on the surface. That creates a <b>glazed, work-hardened surface<\/b>, and restarting a cut in it is very difficult. <b>Interrupted cuts, dwelling and successive thin cuts are the three things to avoid absolutely.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Machining Parameters \u00b7 HSS tooling (carbide: 2\u20133\u00d7 speed, 50\u2013100 % more feed)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Turning (roughing)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>12\u201318 m\/min (40\u201360 SFM)<\/b> (one source). Another publisher gives <b>18\u201320 m\/min (60\u201365 SFM)<\/b> at <b>0.074\u20130.109 mm\/rev (0.0029\u20130.0043 in\/rev)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Turning (finishing)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>15\u201324 m\/min (50\u201380 SFM)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Drilling (\u00d89.5 mm \u00b7 3\/8 in)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>13 m\/min (43 SFM)<\/b> \u00b7 feed <b>0.076 mm\/rev (0.0030 in\/rev)<\/b>. <b>Peck 3\u20134 drill diameters at a time and clear the chips<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Reaming<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>17 m\/min (57 SFM)<\/b> \u00b7 feed <b>0.076\u20130.114 mm\/rev<\/b>. Another source gives <b>8\u201312 m\/min (25\u201340 SFM)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Tapping<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>2\u20135 m\/min (6\u201316 SFM)<\/b> depending on pitch. Another source gives <b>6\u20139 m\/min (20\u201330 SFM)<\/b>. <b>Taps break easily in Invar<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Milling<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>11\u201321 m\/min (35\u201370 SFM)<\/b> \u00b7 feed per tooth <b>0.05\u20130.13 mm (0.002\u20130.005 in)<\/b>. <b>Coarse-tooth cutters preferred<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Tool geometry<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Positive top rake 5\u201310\u00b0<\/b> \u00b7 <b>front clearance 7\u201310\u00b0<\/b> \u00b7 tools <b>large, sharp and rigidly supported<\/b>. Carbide allows higher speeds but <b>demands far more rigidity and will not tolerate shock or interrupted cuts<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Coolant<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Sulphochlorinated oil<\/b> preferred \u2014 it breaks chips and prevents seizing. Emulsions cool better but control chips poorly. <b>Keep the fluid clean when reaming<\/b>; fine chip contamination ruins the bore<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Grinding \u00b7 forging \u00b7 forming<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Grinding: <b>silicon carbide wheel<\/b>, <b>80 grit<\/b> for finishing. Forging: <b>1100\u20131180 \u00b0C (2000\u20132150 \u00b0F)<\/b>, <b>heat quickly, do not soak<\/b>. Forming: <b>~90 HRB<\/b> for blanking, <b>~75 HRB<\/b> after annealing for deep drawing<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Heat treatment between operations<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Treat 315\u2013425 \u00b0C stress relief between roughing and finishing as MANDATORY.<\/b> Skip it and the part leaves the machine on size, then drifts<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b10\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Corrosion \u2014 Invar 36 Is NOT Stainless<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>This is the most frequently skipped and most expensive section on this page. Invar 36 is not a corrosion alloy. It rusts. Having nickel in the name does not change that.<\/b><\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Why it rusts \u2014 the metallurgy in one sentence<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\">Invar 36 contains <b>no meaningful chromium<\/b> (ceiling <b>\u22640.50 %<\/b>, at most mills <b>\u22640.25 %<\/b>, and it is an <i>impurity ceiling<\/i>, not a deliberate addition). <b>It forms no passive oxide film.<\/b> The nickel content is 36 %, enough to give an austenitic lattice but <b>nowhere near enough to passivate<\/b>. For corrosion purposes, think of Invar 36 as <b>a low-alloy steel<\/b> \u2014 not mechanically, but as regards rust.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Where it is GOOD<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>It is good in dry atmosphere at room temperature<\/b> (mill statement). In controlled environments \u2014 a climate-controlled metrology lab, an optical bench under dry nitrogen, a spacecraft structure in vacuum \u2014 Invar 36 poses no corrosion problem. <b>It is good in cryogenic service, in dry LNG and in dry nitrogen<\/b>: the liquid hydrocarbon is not corrosive and there is no moisture. One mill rates humidity resistance as \u201c<b>good<\/b>\u201d on a four-level comparative scale \u2014 <b>but that is a relative rating, not an absolute claim of resistance<\/b>.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">WHERE IT FAILS \u2014 the list that must be published<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>1. Humid or wet atmosphere.<\/b> The mill statement is explicit: \u201c<b>in humid or moist atmospheres, corrosion can occur in the form of rust<\/b>.\u201d Condensation in storage, rain in transit, sweating in the shop \u2014 all produce surface rust.<br \/><b>2. Seawater and chlorides.<\/b> <b>No resistance whatsoever.<\/b> Do not expose Invar 36 to seawater, salt spray or chloride-bearing process fluid.<br \/><b>3. Acids.<\/b> With no chromium and no molybdenum it is <b>unprotected in both reducing and oxidising acids<\/b>. This is not an acid alloy.<br \/><b>4. Fingerprint corrosion.<\/b> On precision Invar surfaces <b>bare-hand contact creates measurable pitting<\/b>. Hand perspiration contains chloride and organic acids. <b>Invar must not be handled without gloves.<\/b><br \/><b>5. Composite tooling \u2014 the most common commercial failure.<\/b> Autoclave steam, release agents and volatiles from prepreg resin produce <b>rust and staining<\/b> on the Invar surface. A rusted tool face is <b>copied directly onto the part surface<\/b>. Invar composite tools do not last <b>without coating or continuous maintenance<\/b>.<br \/><b>6. Long outdoor storage.<\/b> Left in the open, Invar plate rusts within weeks. <b>VCI packaging, dry storage and a protective oil film are mandatory.<\/b><br \/><b>7. Galvanic couples.<\/b> In a wet environment, Invar 36 in contact with stainless steel, titanium or carbon-fibre composite <b>becomes the anode<\/b>. The Invar\u2013carbon-fibre couple is a known problem in composite tooling; <b>use an insulating interlayer<\/b>.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Protection methods<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\">Published and field-proven methods: <b>electrolytic or electroless nickel plating<\/b> (the most common; it also eases welding and soldering), <b>chromium plating<\/b> (for tool faces), <b>paint and resin coatings<\/b>, <b>dry nitrogen blanketing<\/b> and <b>VCI packaging<\/b>. <b>A caution when choosing a coating: the coating thickness and the coating&#8217;s own expansion are a measurable error source on thin, precision sections<\/b>, and hydrogen from the plating bath can cause trouble in a part that has not been stress relieved. <b>No numerical pitting or crevice corrosion data (PREN, critical pitting temperature, etc.) could be found for Invar 36 \u2014 do not publish such a number for this alloy; it would not be meaningful anyway.<\/b><\/p>\n<h4 id=\"dm-b11\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Frequently Asked Questions<\/h4>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Your datasheet says 1.5 \u00d7 10\u207b\u2076\/K. Our part reaches 250 \u00b0C. Is that a problem?<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Yes, a serious one \u2014 and it is the single most common design error made with Invar 36.<\/b><br \/>That <b>1.5 \u00d7 10\u207b\u2076\/K<\/b> figure is a <b>mean<\/b> value for the <b>20\u2013100 \u00b0C<\/b> range. Invar&#8217;s low expansion arises from a magnetic phenomenon and <b>disappears as magnetic order weakens<\/b>. The point where the expansion curve bends \u2014 the inflection point \u2014 is at <b>220 \u00b0C<\/b>; the Curie temperature is <b>279 \u00b0C<\/b> (some publishers put 230 \u00b0C on that line, most likely the inflection point mislabelled).<br \/>In your range the real numbers are: <b>2.6 over 20\u2013200 \u00b0C<\/b>, <b>3.5 over 20\u2013250 \u00b0C<\/b>, <b>5.5 \u00d7 10\u207b\u2076\/K over 20\u2013300 \u00b0C<\/b>. So for a part reaching 250 \u00b0C, Invar&#8217;s effective expansion is <b>two to three times<\/b> the catalogue figure. At 300 \u00b0C it is <b>3.7 times<\/b>. At 500 \u00b0C it is <b>10.1<\/b>, practically indistinguishable from carbon steel (~12).<br \/><b>What to do:<\/b> if your range exceeds 200 \u00b0C, <b>Invar 36 is the wrong alloy<\/b>. If you need a match to glass or ceramic, <b>alloy 42<\/b> (inflection 370 \u00b0C) or <b>Kovar<\/b> (inflection 450 \u00b0C) is the right choice. If you simply need low expansion above 200 \u00b0C, <b>no Fe-Ni controlled-expansion alloy will give you what you want<\/b>, and the design must solve it with expansion compensation. <b>Treating one catalogue number as a design constant is the most expensive mistake in this family.<\/b><\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">We bought an Invar 36 composite tool and it rusted in six months. Is the material defective?<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Almost certainly not. Invar 36 rusts; that is not a material defect but the definition of the alloy.<\/b><br \/>Invar 36 contains <b>no meaningful chromium<\/b>: the ceiling is 0.50 %, at most mills 0.25 %, and it is an <i>impurity ceiling<\/i>, not a deliberate addition. <b>No passive oxide film forms.<\/b> The mills&#8217; own wording is that it resists dry atmosphere at room temperature and that <b>in humid or wet atmosphere corrosion can occur in the form of rust<\/b>.<br \/>Composite tooling is the most demanding application in this respect: autoclave steam, release chemistry, prepreg volatiles and shop humidity all appear together. On top of that comes the <b>galvanic couple between Invar and carbon fibre<\/b> \u2014 in a wet environment <b>Invar is the anode and Invar is what dissolves<\/b>.<br \/><b>The right question is not \u201cis the material defective\u201d but \u201cwhat was the protection plan\u201d.<\/b> Approaches that work: <b>electroless nickel or chromium plating<\/b> of the tool face; <b>cleaning and a protective film after every cycle<\/b>; <b>dry storage and a VCI cover<\/b> when idle; breaking direct contact with carbon fibre using <b>an insulating interlayer<\/b>; and <b>never touching the tool face with bare hands<\/b> (hand perspiration contains chloride and pits Invar).<br \/><b>One more caution:<\/b> coating thickness and the coating&#8217;s own thermal expansion are a measurable error source on thin precision surfaces. <b>Account for the coating when the tool tolerance is calculated<\/b>, not as an afterthought.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Our specification says \u201cInvar 36 to ASTM F1684\u201d. We hear the standard has been withdrawn. Now what?<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>You heard correctly. ASTM F1684 was withdrawn in 2024 with no replacement published.<\/b> In the same round <b>ASTM F15 (Kovar)<\/b> and <b>ASTM F30 (Fe-Ni sealing alloys)<\/b> were also withdrawn \u2014 so the entire controlled-expansion family lost its ASTM basis at once.<br \/><b>This does not mean the alloy is banned.<\/b> The material is the same material and the mills are the same mills. What changed is <b>what the certificate is issued against<\/b>.<br \/><b>Do three things in practice.<\/b> First, cite the standard <b>with its edition year<\/b> in the purchase text: \u201c<b>chemical requirements per ASTM F1684-06(2021) (withdrawn edition), Table 1<\/b>\u201d. That is a clear and defensible reference for an inspector. Second, <b>move the work the standard used to do into the order text<\/b>: chemical ranges (especially <b>carbon<\/b>), the heat treatment route (<b>annealed, or three-step stabilised<\/b>), the expansion measurement range and <b>acceptance criterion<\/b>, temper, grain size and hardness. Third, require an <b>EN 10204 3.1<\/b> certificate and, for critical work, add <b>3.2<\/b> independent inspection.<br \/><b>What not to do<\/b> is accept without question an old supplier certificate that still says \u201cconforms to F1684\u201d and overlook that <b>chemical ranges now differ from mill to mill<\/b>. After a withdrawal those differences tend to <b>widen<\/b>, because no document imposes a common ceiling any more.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Invar 36 or Kovar? We are sealing a metal lid to a ceramic package.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Kovar. Invar 36 is the wrong alloy here, and the reason is precisely what makes Invar valuable: it expands TOO LITTLE.<\/b><br \/>In a hermetic glass-to-metal or ceramic-to-metal joint the goal is <b>not low expansion but MATCHED expansion<\/b>. Alumina expands at ~6\u20138 \u00d7 10\u207b\u2076\/K, borosilicate glass at ~4.6\u20135.3 \u00d7 10\u207b\u2076\/K. Kovar gives <b>5.1 \u00d7 10\u207b\u2076\/K<\/b> over 20\u2013300 \u00b0C and \u2014 more importantly \u2014 <b>the SHAPE of its curve is tailored to the glass curve<\/b>. Invar 36 may look like <b>5.5<\/b> over the same range, but it is only <b>1.5<\/b> over 20\u2013100 \u00b0C; so during cooldown the glass and the metal <b>follow very different paths<\/b> and stress accumulates in the joint. The result is a cracked seal or a leak.<br \/>The second difference is <b>surface chemistry<\/b>. For glass sealing, Kovar is given a <b>wet hydrogen decarburising anneal<\/b> followed by a controlled <b>nickel\u2013cobalt oxide film<\/b>; that film is what the glass wets and dissolves. The <b>cobalt in Kovar makes that oxide easier to melt and dissolve in the glass<\/b> \u2014 Invar contains no cobalt and the mechanism does not work.<br \/><b>In short:<\/b> for dimensional stability (optical benches, metrology frames, composite tools, LNG membranes) use <b>Invar 36<\/b>. For a hermetic seal to glass or ceramic use <b>Kovar<\/b> (borosilicate) or <b>alloy 42<\/b> (silicon and alumina). <b>The two are not interchangeable, and calling them both \u201clow-expansion Fe-Ni alloys\u201d hides the entire difference.<\/b><\/p>\n<h4 id=\"dm-b12\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Common Datasheet Errors \u2014 Check Before You Order<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>1. Publishing a single expansion number \u2014 the most common and most expensive error.<\/b> \u201cInvar 36 = 1.2 \u00d7 10\u207b\u2076\/K\u201d is true for <b>20\u2013100 \u00b0C<\/b> and hides that it is <b>5.5 over 20\u2013300 \u00b0C<\/b> and <b>10.1 over 20\u2013500 \u00b0C<\/b>. <b>In this alloy expansion is a table, not a number.<\/b><br \/><b>2. Confusing the Curie temperature with the inflection point.<\/b> The <b>inflection point is 220 \u00b0C<\/b> (where the curve bends); the <b>Curie temperature is 279 \u00b0C<\/b> (where magnetic order is lost). Some publishers put <b>230 \u00b0C<\/b> on the Curie line; that is most likely the inflection point mislabelled. <b>For design, 220 \u00b0C is the number that matters<\/b> \u2014 expansion starts climbing from there.<br \/><b>3. Confusing \u201cInvar 42\u201d with Invar 36.<\/b> <b>Alloy 42<\/b> (<b>UNS K94100 \u00b7 W.Nr. 1.3917 \u00b7 NILO 42<\/b>) is sometimes sold as \u201cInvar 42\u201d. <b>It is not the same alloy:<\/b> 42 % nickel, <b>4.0\u20134.7 \u00d7 10\u207b\u2076\/K<\/b> over 30\u2013300 \u00b0C, inflection point <b>370 \u00b0C<\/b>. Its use is different too \u2014 it is a <b>glass\/ceramic matching and lead-frame<\/b> alloy, not a dimensional stability alloy. <b>Read the UNS number on the order and the certificate, not the trade name.<\/b><br \/><b>4. Missing the ASTM withdrawals.<\/b> <b>F1684, F15 and F30 were all withdrawn in 2024 with no replacement.<\/b> Most pages that still say \u201cconforms to ASTM F1684\u201d do not know this. <b>Cite the edition year.<\/b><br \/><b>5. UNS number confusion.<\/b> <b>K93600<\/b> and <b>K93601<\/b> are general Invar 36; <b>K93603<\/b> is the grade the withdrawn ASTM F1684 covered; <b>K93050<\/b> is the <b>free-machining<\/b> grade, covered in F1684 for <b>bar only<\/b>; <b>K93500<\/b> is Fe\u201332 Ni\u20135 Co \u2014 <b>not Invar 36<\/b>. One mill states \u201c<b>K93600 to K93603 depending on application<\/b>\u201d; read the number on the certificate.<br \/><b>6. Material number confusion.<\/b> <b>1.3912 = Invar 36 (Ni36)<\/b>, <b>1.3917 = alloy 42<\/b>, <b>1.3981 = Kovar<\/b>. All three are called \u201clow-expansion Fe-Ni\u201d and all three do entirely different jobs.<br \/><b>7. Density conflict.<\/b> Published values range over <b>8.05 \u00b7 8.11 \u00b7 8.13 g\/cm\u00b3<\/b> \u2014 an <b>80 kg difference per cubic metre<\/b>. If you price by weight, <b>state which density you used in the quotation<\/b>.<br \/><b>8. Melting point row shift.<\/b> <b>1427\u20131430 \u00b0C<\/b> is correct for Invar 36. The <b>1450 \u00b0C<\/b> that appears on some pages is the Kovar and alloy 48 value.<br \/><b>9. Decimal error in the carbon ceiling.<\/b> One European mill sheet shows carbon at <b>\u22640.4 %<\/b>; every other source gives <b>\u22640.10 %<\/b> or lower. <b>This is almost certainly a decimal error, and carbon is the element that governs dimensional stability in this alloy \u2014 question the number.<\/b><br \/><b>10. Unit error in a heat-treatment temperature.<\/b> A widely mirrored Invar page gives the full anneal as \u201c<b>1550 \u00b0F or 2 hours at 1350 \u00b0C<\/b>\u201d. <b>1350 \u00b0C is just below the melting point and is plainly a value that should read \u00b0F.<\/b> Do not anneal Invar at 1350 \u00b0C.<br \/><b>11. Confusing annealing with stabilisation.<\/b> <b>790 \u00b0C \/ air cool<\/b> is a <i>softening<\/i> anneal and <b>gives no dimensional stability<\/b>. Dimensional stability comes from the three-step route: <b>815\u2013830 \u00b0C + WATER QUENCH + 315 \u00b0C for 1 h + 93\u2013100 \u00b0C for 24\u201348 h<\/b>. <b>Any datasheet that puts both routes on the same line is misleading.<\/b><br \/><b>12. Assuming Invar is \u201cstainless\u201d.<\/b> Because nickel is in the name it is assumed not to rust. <b>It has no chromium (a \u22640.50 % impurity ceiling), forms no passive film and rusts in a humid environment.<\/b><br \/><b>13. Omitting the magnetic behaviour.<\/b> Invar 36 is <b>ferromagnetic<\/b> with <b>~4 ppm saturation magnetostriction<\/b>. A part machined on a magnetic chuck or exposed to a strong field can show a <b>permanent dimensional change<\/b>. Do not use magnetic workholding on dimensionally critical Invar.<br \/><b>14. Omitting the filler&#8217;s expansion.<\/b> \u201cInvar is weldable\u201d is true but incomplete. <b>There is no AWS class<\/b>; nickel-base fillers (FM 61, FM 82, FM 92) will make a sound weld but <b>do not match expansion<\/b>. On a dimensionally critical joint use a <b>matched Fe\u201336 Ni filler<\/b> and <b>demand its expansion data<\/b>.<br \/><b>15. The phrase \u201czero expansion\u201d.<\/b> It is zero at no temperature. The lowest published mean is <b>1.3 \u00d7 10\u207b\u2076\/K over \u2212100 to 20 \u00b0C<\/b>. <b>Do not sell a zero-expansion material.<\/b><\/p>\n<p><!-- dm-diy-kars --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">COMPARISON<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:10px 14px 0;font-size:12.5px;color:#5b7180;line-height:1.7;\">MEAN LINEAR COEFFICIENT OF THERMAL EXPANSION (10-6\/\u00b0C) over the same temperature ranges referenced to 20 \u00b0C. The values for the two alloys come from the SAME measurement basis in the SAME source (the Special Metals NILO alloys bulletin), and each row has additionally been cross-checked against independent sources. These alloys are distinguished by their expansion behaviour rather than by their mechanical strength, so the comparison is built on that criterion.<\/div>\n<div style=\"padding:12px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"overflow-x:auto;position:relative;z-index:2;\">\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;min-width:430px;background:transparent;\">\n<tr>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Grade<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">UNS<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">W.-Nr.<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 100<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 200<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 250<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 300<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 400<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 500<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Donum noktasi<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Curie<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Davranis<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Ne icin secilir<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Capraz kontrol<\/th>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Invar 36<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">K93600 (also K93601, K93603)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">1.3912<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">1.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">2.6<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">3.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">5.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">8.4<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">10.1<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">220 \u00b0C (Special Metals); ESPI gives 190 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">277-279 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">The expansion coefficient is at its lowest around room temperature and RISES RAPIDLY as temperature increases. The 20-500 \u00b0C mean is about seven times the 20-100 \u00b0C mean. Above the Curie temperature the Invar effect disappears entirely.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Work below 200 \u00b0C in which the dimension must not change with temperature: composite moulds, optical and laser benches, length standards, cryogenic structures.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Carpenter 1.30 at 93 \u00b0C \u00b7 Rolled Alloys 1.44 for 21-100 \u00b0C \u00b7 Nickel Institute 1.26 for -18\/93 \u00b0C \u00b7 NeoNickel 1.2-1.5 for -100\/+100 \u00b0C<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Kovar<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">K94610<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">1.3981<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">6.0<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">5.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">5.3<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">5.1<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">4.9<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">6.2<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">450 \u00b0C (Special Metals)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">435 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Unlike Invar, the coefficient FALLS from room temperature to the inflection point and stays flat between 20 and 450 \u00b0C. The value is higher than Invar&#8217;s, but THE CURVE IS FLAT; it overlaps the curve of borosilicate glass up to 450 \u00b0C.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Hermetic glass-to-metal seals. What is wanted is not a low coefficient but a curve that MATCHES the glass.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Carpenter\/EFINEA 5.86 for 25-100 \u00b0C \u00b7 NiWire 6.4 for 20-100 \u00b0C \u00b7 Wikipedia 5.5 for 25-200 \u00b0C \u00b7 ASTM F15 acceptance range 4.60-5.20 for 30-400 \u00b0C and 5.10-5.50 for 30-450 \u00b0C<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">Additional information<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Kritik fark<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Invar 36 gives a LOW coefficient but only over a narrow band; Kovar gives a HIGHER but MUCH FLATTER coefficient. The choice depends on which of the two the job needs: Invar 36 where the dimension must not change at all near room temperature, Kovar where the expansion curve must follow a glass curve up to 450 \u00b0C. The two alloys are not interchangeable. NEITHER alloy is precipitation hardenable.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Siparis notu<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">An expansion coefficient is NEVER ordered without stating its temperature range. The statement &#8216;Invar 36, 1.3 ppm\/K&#8217; is incomplete and cannot serve as an acceptance criterion; it must be written as &#8216;mean linear coefficient of expansion over 20-100 \u00b0C &#8230; ppm\/K&#8217;. Because ASTM F1684 (Invar) and ASTM F15 (Kovar) were both withdrawn in 2024, the acceptance range must be written into the purchase order.<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\">Same criterion, same reference temperature (20 \u00b0C), same measurement basis: Tables 7 and 10 of the Special Metals NILO bulletin. The coefficients are given TOGETHER WITH THEIR TEMPERATURE RANGES; a coefficient given without a range cannot be used. The values in the cross-check rows use different reference temperatures (20, 21, 25, 30 \u00b0C), so they are not identical to one another and have not been averaged. NEITHER alloy is precipitation hardenable; the comparison is on thermal expansion, not on mechanical criteria.<\/div>\n<\/div>\n<p><!-- \/dm-diy-kars --><\/p>\n<p><!-- \/dm-zengin --><\/p>\n<div class=\"dm-benzer\" style=\"margin:22px 0 0;padding:14px 16px;border:1px solid #e0e0e0;background:#FBFCFD;\">\n<p style=\"font-size:11px;font-weight:700;letter-spacing:.08em;text-transform:uppercase;color:#9aa3a8;margin:0 0 8px;line-height:1.4;\">Related grades<\/p>\n<p style=\"margin:0;font-size:15px;line-height:2;color:#333;\"><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/kovar\/\" style=\"color:#24BEE5;font-weight:600;text-decoration:none;\">Kovar<\/a> &nbsp;\u00b7&nbsp; Tungsten &nbsp;\u00b7&nbsp; <a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nikel-200\/\" style=\"color:#24BEE5;font-weight:600;text-decoration:none;\">Nickel 200<\/a> &nbsp;\u00b7&nbsp; <a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nikel-201\/\" style=\"color:#24BEE5;font-weight:600;text-decoration:none;\">Nickel 201<\/a> &nbsp;\u00b7&nbsp; <a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nickel-alloys\/\" style=\"color:#666;font-weight:600;text-decoration:none;\">All nickel alloys \u2192<\/a><\/p>\n<\/div>\n<p><!-- dm-ld --><script type=\"application\/ld+json\">{\"@context\":\"https:\/\/schema.org\",\"@type\":\"WebPage\",\"name\":\"Invar 36\",\"url\":\"https:\/\/www.defencemetal.com\/index.php\/en\/invar-36\/\",\"inLanguage\":\"en\",\"description\":\"Invar 36 (UNS K93600 \/ K93601 \/ K93603 \u00b7 W.Nr. 1.3912 \u00b7 EN designation Ni36 \u00b7 FeNi36 \u00b7 Chinese 4J36) is a binary iron-nickel alloy, nominally 36 % nickel, balance iron. It contains no meaningful chromium, no meaningful molybdenum, does not precipitation harden, and is never bought for strength.\",\"isPartOf\":{\"@type\":\"WebSite\",\"name\":\"Defence Metal\",\"url\":\"https:\/\/www.defencemetal.com\/\"},\"publisher\":{\"@type\":\"Organization\",\"name\":\"Defence Metal\",\"url\":\"https:\/\/www.defencemetal.com\/\"},\"mainEntity\":{\"@type\":\"DefinedTerm\",\"name\":\"Invar 36\",\"description\":\"Invar 36 (UNS K93600 \/ K93601 \/ K93603 \u00b7 W.Nr. 1.3912 \u00b7 EN designation Ni36 \u00b7 FeNi36 \u00b7 Chinese 4J36) is a binary iron-nickel alloy, nominally 36 % nickel, balance iron. It contains no meaningful chromium, no meaningful molybdenum, does not precipitation harden, and is never bought for strength.\",\"inDefinedTermSet\":{\"@type\":\"DefinedTermSet\",\"name\":\"Defence Metal - metals and alloys\",\"url\":\"https:\/\/www.defencemetal.com\/\"},\"alternateName\":[\"UNS K93600\",\"W.Nr. 1.3912\",\"Ni36\"],\"identifier\":[{\"@type\":\"PropertyValue\",\"propertyID\":\"UNS\",\"value\":\"K93600\"},{\"@type\":\"PropertyValue\",\"propertyID\":\"Werkstoffnummer\",\"value\":\"1.3912\"}],\"additionalProperty\":[{\"@type\":\"PropertyValue\",\"name\":\"DIN \/ EN designation\",\"value\":\"Ni36\"}]}}<\/script><!-- \/dm-ld --><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Invar 36 \/ (1.3912) \/ UNS K93600 DEFENCE METAL Invar 36 UNS K93600 (the same alloy also appears as K93601 and K93603 in ASTM and producer records) \u00b7 W.Nr. 1.3912 \u00b7 FeNi36 \/ Ni36 (DIN 1715, SEW 385) \u00b7 ~36% Ni \u2013 balance Fe. Specification limits: Ni 35.0-37.0% \u00b7 C 0.10% max \u00b7 Mn 0.60% &hellip; <\/p>\n<p class=\"link-more\"><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/invar-36\/\" class=\"more-link\"><span class=\"screen-reader-text\"> &#8220;Invar 36&#8221;<\/span>devam\u0131n\u0131 oku<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":3526,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_yoast_wpseo_title":"INVAR 36 \/ (1.3912) \/ UNS K93600 | Defence Metal","_yoast_wpseo_metadesc":"Invar 36 (UNS K93600, 1.3912) \u2014 36% nickel iron alloy with minimal thermal expansion, for measuring instruments and precision components.","inspiro_hide_title":false,"inspiro_hide_featured_image":false,"footnotes":""},"dm_sektor":[13,18,14,11],"class_list":["post-3575","page","type-page","status-publish","hentry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.5 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ 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