{"id":3537,"date":"2026-09-16T10:57:39","date_gmt":"2026-09-16T07:57:39","guid":{"rendered":"https:\/\/www.defencemetal.com\/index.php\/en\/kovar\/"},"modified":"2026-09-25T16:28:05","modified_gmt":"2026-09-25T13:28:05","slug":"kovar","status":"publish","type":"page","link":"https:\/\/www.defencemetal.com\/index.php\/en\/kovar\/","title":{"rendered":"Kovar \/ (1.3981) \/ ASTM F15"},"content":{"rendered":"<p><!-- dm-hap --><\/p>\n<h1 class=\"dm-ust-baslik\" style=\"font-family:-apple-system,BlinkMacSystemFont,'Segoe UI',Helvetica,Arial,sans-serif !important;text-transform:none !important;font-size:27px;line-height:1.3;font-weight:800;color:#12303f;margin:0 0 10px;letter-spacing:-.01em;\">Kovar \/ (1.3981) \/ UNS K94610 \/ ASTM F15<\/h1>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:0 0 22px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"background:#12303f;padding:14px 16px 12px;position:relative;z-index:2;\">\n<div style=\"font-size:22px;font-weight:700;color:#fff;line-height:1.25;\">Kovar<\/div>\n<div style=\"font-family:ui-monospace,Menlo,Consolas,monospace;font-size:12.5px;color:#b9cfdb;line-height:1.5;margin-top:5px;word-wrap:break-word;\">UNS K94610 \u00b7 W.Nr. 1.3981 \u00b7 DIN 17745 \u00b7 FeNi29Co17 \u00b7 ~53% Fe \u2013 29% Ni \u2013 17% Co. Minor elements: C 0.02-0.04% max \u00b7 Mn 0.30-0.50% max \u00b7 Si 0.20% max \u00b7 Cr 0.20% max \u00b7 Cu 0.20% max \u00b7 Mo 0.20% max \u00b7 Al, Mg, Zr, Ti 0.10% max each \u00b7 P and S 0.02% max. It is an iron-nickel-cobalt controlled-expansion alloy. ASTM F15 requires the iron, nickel and cobalt contents to be ADJUSTED by the manufacturer so that the alloy meets the expansion coefficient requirement; the figures given for those three elements are nominal. Other producer names: NILO alloy K, Alloy K, Rodar, Pernifer 2918.<\/div>\n<div data-dmkars-blok=\"1\" style=\"border-top:1px solid rgba(255,255,255,.16);margin-top:13px;padding-top:11px;\">\n<div style=\"font-size:10px;letter-spacing:.09em;text-transform:uppercase;color:#7f9fb0;font-weight:700;margin-bottom:8px;\">Not to be confused with<\/div>\n<p><a href=\"https:\/\/www.defencemetal.com\/index.php\/2026\/09\/15\/invar-36-kovar-difference\/\" data-dmkars=\"1\" style=\"display:inline-block;padding:4px 11px;border:1px solid rgba(36,190,229,.45);background:rgba(36,190,229,.12);border-radius:99px;margin:0 6px 6px 0;font-size:12.5px;font-weight:600;color:#9fe2f7;text-decoration:none;\">Invar 36<\/a><\/div>\n<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">For what<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">Its real job is the HERMETIC GLASS-TO-METAL SEAL. It is NOT PRECIPITATION HARDENABLE and cannot be hardened by heat treatment; its distinguishing property is not mechanical strength but THE SHAPE OF ITS THERMAL EXPANSION CURVE.<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Forms<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">Round bar \u00b7 flat bar \u00b7 plate \u00b7 sheet \u00b7 strip \u00b7 tube \u00b7 wire \u00b7 forging. All forms are supplied to order.<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Standards<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\"><b style=\"font-size:16.5px;font-weight:800;color:#12303f;\">AMS 7726<\/b> \u2014 wire; SAE title &#8216;Iron-Nickel-Cobalt Alloy, Wire 53Fe &#8211; 29Ni &#8211; 17Co Low Expansion, Glass Sealing, Annealed&#8217;. \u00b7 <b style=\"font-size:16.5px;font-weight:800;color:#12303f;\">AMS 7727<\/b> \u2014 bars and forgings; SAE title &#8216;Iron-Nickel-Cobalt Alloy, Bars and Forgings 53Fe &#8211; 29Ni &#8211; 17Co Low Expansion, Glass Sealing&#8217;. \u00b7 <b style=\"font-size:16.5px;font-weight:800;color:#12303f;\">AMS 7728<\/b> \u2014 sheet, strip and plate; SAE title &#8216;Iron-Nickel-Cobalt Alloy, Sheet, Strip, and Plate, 53Fe &#8211; 29Ni &#8211; 17Co, Low Expansion Glass Sealing, Annealed&#8217;. \u00b7 AMS-I-23011 \/ MIL-I-23011 Class 1 (&#8216;Iron-Nickel Alloys for Sealing to Glasses and Ceramic&#8217;). \u00b7 ASTM F15 \u2014 iron-nickel-cobalt sealing alloy; it covered wire, rod, bar, strip, sheet and tubing and was WITHDRAWN IN 2024 WITH NO REPLACEMENT. The last valid edition is F15-04(2022). \u00b7 DIN 17745.<br \/><span style=\"font-size:12.5px;color:#7b8f9b;line-height:1.6;display:inline-block;margin-top:6px;\">SPECIFICATION GAP: with the withdrawal of ASTM F15 in 2024, the only specification family left in force is AMS 7726\/7727\/7728. Those three numbers cover WIRE, BAR AND FORGINGS, and SHEET, STRIP AND PLATE; TUBING appears in none of them.<\/span><\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Advantage<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">The expansion CURVE is flat between 20 and 450 \u00b0C and follows the curve of borosilicate glass across that band. For NILO alloy K, Special Metals gives mean coefficients referenced to 20 \u00b0C of 20-100 \u00b0C: 6.0 \u00b7 20-200 \u00b0C: 5.5 \u00b7 20-250 \u00b0C: 5.3 \u00b7 20-300 \u00b0C: 5.1 \u00b7 20-400 \u00b0C: 4.9 \u00b7 20-500 \u00b0C: 6.2 x\u2026<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#F7FAFB;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;line-height:1.5;\">Welding<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;\">In glass-to-metal seal parts Kovar is joined by brazing and resistance welding rather than by fusion welding; where fusion welding is used, GTAW is chosen and the heat input is limited.<\/div>\n<\/div>\n<div style=\"display:flex;flex-wrap:wrap;border-top:1px solid #eceff1;\">\n<div style=\"flex:0 0 118px;padding:11px 14px;background:#fdeceb;font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#c0392b;font-weight:600;line-height:1.5;\">Limits<\/div>\n<div style=\"flex:1 1 230px;min-width:0;padding:11px 14px;font-size:14.5px;line-height:1.7;color:#3d5260;word-wrap:break-word;overflow-wrap:break-word;background:#fdeceb;\">ABOVE 450 \u00b0C THE EXPANSION CURVE BREAKS DOWN. The inflection point is 450 \u00b0C; above it the coefficient rises sharply (the 20-500 \u00b0C mean is 6.2, the 600-700 \u00b0C value 7.8 and the 800-900 \u00b0C value 10.3 x 10-6\/\u00b0C). The match with the glass ends and the seal is left under stress. The Curie temperature is 435 \u00b0C;<\/div>\n<\/div>\n<div style=\"padding:14px;border-top:1px solid #eceff1;\"><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/contact\/\" style=\"display:inline-block;padding:11px 20px;font-size:14px;font-weight:700;text-decoration:none;margin:0 8px 6px 0;background:#dd3333;color:#ffffff;\">REQUEST A QUOTE<\/a><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nickel-alloys\/\" style=\"display:inline-block;padding:11px 20px;font-size:14px;font-weight:700;text-decoration:none;margin:0 8px 6px 0;font-weight:600;border:1px solid #12303f;color:#12303f;\">All nickel alloys &rarr;<\/a><span data-dm=\"dm-teknik\" style=\"cursor:pointer;display:inline-block;padding:11px 20px;font-size:14px;font-weight:700;text-decoration:none;margin:0 8px 6px 0;border:1px solid #dd3333;color:#dd3333;\">TECHNICAL DETAILS &darr;<\/span><\/div>\n<div style=\"padding:9px 14px;border-top:1px solid #eceff1;font-size:11.5px;color:#8a9aa4;line-height:1.5;\">Compiled from manufacturer data sheets \u00b7 confirm against the current specification before ordering<\/div>\n<\/div>\n<\/div>\n<p><!-- \/dm-hap --><!-- dm-nav --><\/p>\n<style>h4[id^=\"dm-b\"]{scroll-margin-top:120px}#dm-teknik{scroll-margin-top:120px}<\/style>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:0 0 22px;padding:12px 14px;\">\n<div style=\"font-size:10.5px;letter-spacing:.09em;text-transform:uppercase;color:#6b8091;font-weight:600;margin-bottom:9px;\">On this page &middot; click to jump<\/div>\n<div><span data-dm=\"dm-b0\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">What Kovar Is<\/span><span data-dm=\"dm-b1\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Standards by Product Form<\/span><span data-dm=\"dm-b2\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Temperature Limits<\/span><span data-dm=\"dm-b3\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Product Forms With NO Standard<\/span><span data-dm=\"dm-b4\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Chemical Composition<\/span><span data-dm=\"dm-b5\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Mechanical Properties<\/span><span data-dm=\"dm-b6\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Physical Properties<\/span><span data-dm=\"dm-b7\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Heat Treatment<\/span><span data-dm=\"dm-b8\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Welding, Soldering and Plating<\/span><span data-dm=\"dm-b9\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Machining<\/span><span data-dm=\"dm-b10\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Corrosion<\/span><span data-dm=\"dm-b11\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Frequently Asked Questions<\/span><span data-dm=\"dm-b12\" style=\"cursor:pointer;display:inline-block;padding:5px 11px;border:1px solid #dfe6ea;background:#F7FAFB;margin:0 6px 7px 0;font-size:13px;color:#12303f;\">Common Datasheet Errors<\/span><\/div>\n<\/div>\n<p><script>(function(){function go(id){var e=document.getElementById(id);if(e){var s=document.scrollingElement||document.documentElement;var y=e.getBoundingClientRect().top+s.scrollTop-118;if(y-0-0-0-0!==y){y=0;}window.scrollTo(0,y);}}function bind(el){el.addEventListener(\"click\",function(ev){ev.preventDefault();go(el.getAttribute(\"data-dm\"));});}function init(){var l=document.querySelectorAll(\"[data-dm]\");Array.prototype.forEach.call(l,bind);if(location.hash){if(location.hash.indexOf(\"#dm-\")===0){try{history.replaceState(null,\"\",location.pathname+location.search);}catch(e){}window.scrollTo(0,0);setTimeout(function(){window.scrollTo(0,0);},80);}}}if(document.readyState===\"loading\"){document.addEventListener(\"DOMContentLoaded\",init);}else{init();}})();<\/script><!-- \/dm-nav --><br \/>\n<span id=\"dm-teknik\" style=\"display:block;height:0;overflow:hidden;\"><\/span><br \/>\nKovar is a nickel-iron-cobalt based alloy with a specifically controlled coefficient of thermal expansion. Within the nickel alloy group it forms, together with Invar 36, the controlled expansion sub-class. Its UNS designation is K94610.<\/p>\n<p>The alloy is formulated to give an expansion coefficient very close to that of borosilicate glass over the 20-400 \u00b0C range. That match makes it possible to form a hermetic, gas-tight joint between glass or ceramic and metal that does not crack under thermal cycling. Invar 36 aims at the lowest possible expansion, whereas Kovar aims to match a particular glass \u2014 that is the difference between them.<\/p>\n<p>This property makes the material indispensable in electronic packaging and vacuum technology. Although the name Kovar is used commercially for most Fe-Ni-Co low expansion alloys, technically only material conforming to ASTM F15 is regarded as true Kovar.<\/p>\n<p>It is used in electronics for transistor, diode and integrated circuit packages, TO-3 \/ TO-5 metal housings and microwave sealing components; in aerospace for hermetic sub-system enclosures and for the glass-to-metal seals of vacuum and laser tubes; in medical devices for pacemaker and implant bodies; and in optoelectronics for fibre optic connector housings.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Chemical Composition \u00b7 Kovar (K94610)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Fe \u2014 Iron<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Bakiye<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Ni \u2014 Nickel<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">~29%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Co \u2014 Cobalt<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">~17%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Mn \u2014 Manganese<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">0.30% max<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Si \u2014 Silicon<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">0.20% max<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">C \u2014 Carbon<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">0.04% max<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Key Properties \u00b7 Kovar<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Primary function<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Hermetic sealing to glass and ceramic<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Expansion match<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">20 \u2013 400 \u00b0C controlled range, matched to borosilicate glass<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Typical product forms<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Plate, strip, bar, machined parts<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div class=\"dm-std\" style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Standards and Equivalents \u00b7 Kovar<\/div>\n<div data-dmtw=\"1\" style=\"position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;overflow-x:auto;\">\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Trade name<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Kovar<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">UNS<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">K94610<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">W.Nr (DIN\/EN)<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">1.3981<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">ASTM<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">F15<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Available forms<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Round bar \u00b7 Flat bar \u00b7 Plate \u00b7 Sheet \u00b7 Tube \u00b7 Forgings<br \/><span style=\"font-size:13px;color:#6b7a84;\">All forms are supplied to order.<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"margin:28px 0 0;padding:14px 16px;border:1px solid #e0e0e0;background:#FBFCFD;font-size:15px;line-height:1.7;\">\n<p style=\"margin:0 0 10px;\"><span style=\"color:#DD3333;font-weight:700;\">\u2192<\/span> Contact us for Kovar stock availability, sizes and ASTM F15 certified supply.<\/p>\n<p style=\"margin:0;\"><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/contact\/\" style=\"display:inline-block;background:#DD3333;color:#ffffff;font-weight:700;font-size:14px;padding:9px 16px;text-decoration:none;\">Request a quote<\/a><\/p>\n<\/div>\n<div style=\"margin:22px 0 0;padding:14px 16px;border:1px solid #e0e0e0;background:#FBFCFD;\">\n<p style=\"font-size:11px;font-weight:700;letter-spacing:.08em;text-transform:uppercase;color:#9aa3a8;margin:0 0 8px;line-height:1.4;\">Related grades<\/p>\n<p style=\"margin:0;font-size:15px;line-height:2;color:#333;\"><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/invar-36\/\" style=\"color:#24BEE5;font-weight:600;text-decoration:none;\">Invar 36<\/a> &nbsp;\u00b7&nbsp; <a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nikel-200\/\" style=\"color:#24BEE5;font-weight:600;text-decoration:none;\">Nickel 200<\/a> &nbsp;\u00b7&nbsp; <a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nikel-201\/\" style=\"color:#24BEE5;font-weight:600;text-decoration:none;\">Nickel 201<\/a> &nbsp;\u00b7&nbsp; <a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/monel-400\/\" style=\"color:#24BEE5;font-weight:600;text-decoration:none;\">Monel 400<\/a> &nbsp;\u00b7&nbsp; <a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/nickel-alloys\/\" style=\"color:#666;font-weight:600;text-decoration:none;\">All nickel alloys \u2192<\/a><\/p>\n<\/div>\n<p><!-- dm-zengin --><\/p>\n<h4 id=\"dm-b0\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">What Kovar Is \u2014 and Why It Is a MATCHED-Expansion Alloy, Not a Low-Expansion One<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\">Kovar (UNS <b>K94610<\/b> \u00b7 W.Nr. <b>1.3981<\/b> \u00b7 DIN designation <b>FeNi29Co17<\/b> \u2014 some publishers write <b>FeNi29Co18<\/b> \u00b7 ASTM <b>F15<\/b> \u00b7 Chinese <b>4J29<\/b>) is a ternary iron-nickel-cobalt alloy, nominally <b>29 % nickel \u2013 17 % cobalt \u2013 balance iron<\/b>. This cobalt-bearing Fe-Ni-Co family was historically developed under the name <b>Fernico<\/b>. Kovar contains no chromium and no molybdenum, is never bought for strength, and <b>is not a corrosion alloy<\/b>.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>The one distinguishing sentence is this:<\/b> Kovar exists not because its thermal expansion is <i>low<\/i>, but because <b>the SHAPE of its expansion curve is tailored to that of borosilicate glass<\/b>. Alloys that expand less than Kovar exist \u2014 <b>Invar 36<\/b> heads the list and expands less than a quarter as much over 20\u2013100 \u00b0C. <b>But Invar does not match glass; Kovar does.<\/b> What a hermetic glass-to-metal transition needs is not low expansion but a metal curve that <b>FOLLOWS the glass curve<\/b> throughout cooldown.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>The second distinguishing fact is cobalt.<\/b> Cobalt is there not only to shape the expansion curve but to <b>make the oxide interface between glass and metal work<\/b>: the bond forms through a deliberately grown <b>nickel(II) oxide \u2013 cobalt(II) oxide<\/b> film on the metal surface, and <b>cobalt makes that oxide easier to melt and to dissolve in the molten glass<\/b>. The proportion of iron oxide in such a seal is low, because cobalt reduces it. <b>In a cobalt-free Fe-Ni alloy this mechanism does not work<\/b> \u2014 the second reason you cannot substitute Invar for Kovar.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Honest Comparison \u00b7 Invar 36 \u00b7 \u201cInvar 42\u201d (Alloy 42) \u00b7 Kovar<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Invar 36<\/b><br \/>K93600\/K93603 \u00b7 1.3912<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Fe\u201336 Ni.<\/b> <b>1.5 \u00d7 10\u207b\u2076\/K<\/b> over 20\u2013100 \u00b0C \u00b7 inflection <b>220 \u00b0C<\/b> \u00b7 Curie <b>279 \u00b0C<\/b>. <b>A dimensional-stability alloy.<\/b> It does <b>NOT match<\/b> glass or ceramic \u2014 <b>it expands far too little<\/b>. No cobalt, therefore no oxide-interface mechanism. Uses: precision optics, metrology, composite tooling, LNG membranes<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>\u201cInvar 42\u201d = Alloy 42<\/b><br \/>K94100 \u00b7 1.3917 \u00b7 NILO 42<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Fe\u201342 Ni.<\/b> <b>4.0\u20134.7 \u00d7 10\u207b\u2076\/K<\/b> over 30\u2013300 \u00b0C \u00b7 inflection <b>370 \u00b0C<\/b> \u00b7 Curie <b>330 \u00b0C<\/b>. <b>This is a glass\/ceramic matching alloy<\/b> and it <b>matches silicon and alumina<\/b>. IC lead frames, semiconductor packages. <b>Sold as \u201cInvar 42\u201d but it is NOT the same alloy as Invar 36<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Alloy 48<\/b><br \/>K94800<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Fe\u201348 Ni.<\/b> Inflection <b>460 \u00b0C<\/b>. For <b>soft (soda-lime) glasses<\/b>, not for borosilicate<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>KOVAR<\/b><br \/>K94610 \u00b7 1.3981<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Fe\u201329 Ni\u201317 Co.<\/b> <b>~5.1 \u00d7 10\u207b\u2076\/K<\/b> over 20\u2013300 \u00b0C \u00b7 inflection <b>450 \u00b0C<\/b> \u00b7 Curie <b>435 \u00b0C<\/b>. <b>The shape of the curve is tailored to borosilicate glass (the 7052 family)<\/b> and <b>cobalt makes the oxide interface work<\/b>. The <b>only true hermetic glass-to-metal sealing alloy<\/b> in this family. Uses: hermetic packages, vacuum tubes, microwave tubes, X-ray tubes, optoelectronic packages<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>The selection rule \u2014 one sentence<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>If dimension is critical, Invar 36. If you need a hermetic seal to borosilicate glass, Kovar. If you need a match to silicon or alumina, alloy 42. These are NOT interchangeable.<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Trade names \u2014 not all produced to the same specification<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Kovar\u00ae<\/b> is a registered trademark (CRS Holdings \/ Carpenter Technology). Other trade names for the same alloy: <b>Nilo\u00ae K<\/b> (Special Metals), <b>Pernifer\u00ae 2918<\/b> (VDM Metals), <b>Dilver\u00ae P<\/b>, <b>Rodar\u00ae<\/b>, <b>Nicoseal\u00ae<\/b>, <b>Telcoseal\u00ae<\/b>, <b>Fenicoloy\u00ae<\/b>, <b>Ulbravar\u00ae<\/b>, <b>Nicosel\u00ae<\/b>. The Chinese equivalent is <b>4J29<\/b>. <b>All belong to the K94610 family, but carbon and impurity ceilings \u2014 and, more importantly, the as-delivered decarburisation condition \u2014 vary from mill to mill.<\/b> If you are going to seal to glass, write <b>\u201cdecarburised in wet hydrogen\u201d separately into the order<\/b>; the trade name does not guarantee it.<\/p>\n<h4 id=\"dm-b1\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Standards by Product Form \u2014 and What Happened in 2024<\/h4>\n<p><!-- dm-diy-std --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">STANDARDS BY PRODUCT FORM<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:12px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"overflow-x:auto;position:relative;z-index:2;\">\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;min-width:430px;background:transparent;\">\n<tr>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Product form<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Standards<\/th>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Sheet, strip, plate<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\"><b style=\"font-size:16.5px;font-weight:800;color:#12303f;\">AMS 7728<\/b> (&#8216;Iron-Nickel-Cobalt Alloy, Sheet, Strip, and Plate, 53Fe &#8211; 29Ni &#8211; 17Co, Low Expansion Glass Sealing, Annealed&#8217;) \u00b7 AMS-I-23011 \/ MIL-I-23011 Class 1 \u00b7 ASTM F15 \u2014 WITHDRAWN in 2024, last edition F15-04(2022) \u00b7 DIN 17745<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Round bar, flat bar, forging<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\"><b style=\"font-size:16.5px;font-weight:800;color:#12303f;\">AMS 7727<\/b> (&#8216;Iron-Nickel-Cobalt Alloy, Bars and Forgings 53Fe &#8211; 29Ni &#8211; 17Co Low Expansion, Glass Sealing&#8217;) \u00b7 AMS-I-23011 \/ MIL-I-23011 Class 1 \u00b7 ASTM F15 (withdrawn) \u00b7 DIN 17745<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Wire<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\"><b style=\"font-size:16.5px;font-weight:800;color:#12303f;\">AMS 7726<\/b> (&#8216;Iron-Nickel-Cobalt Alloy, Wire 53Fe &#8211; 29Ni &#8211; 17Co Low Expansion, Glass Sealing, Annealed&#8217;) \u00b7 AMS-I-23011 \/ MIL-I-23011 Class 1 \u00b7 ASTM F15 (withdrawn) \u00b7 DIN 17745<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Tube<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">NO AMS number \u2014 <b style=\"font-size:16.5px;font-weight:800;color:#12303f;\">AMS 7726<\/b>, 7727 and 7728 do not cover tubing \u00b7 ASTM F15 did cover tubing but was withdrawn in 2024 \u00b7 There is no product specification in force; the acceptance criteria must be written into the purchase order<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Expansion coefficient acceptance criterion<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">ASTM F15 (withdrawn edition) acceptance band: 4.60-5.20 \u00b5m\/m\u00b7\u00b0C over 30-400 \u00b0C and 5.10-5.50 \u00b5m\/m\u00b7\u00b0C over 30-450 \u00b0C. Because the specification is not in force, this band must be written into the purchase order.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Chemical composition and numbering<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">UNS K94610 \u00b7 W.Nr. 1.3981 \u00b7 DIN 17745 \u00b7 FeNi29Co17<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\">AMS numbers are given first, ASTM afterwards. The titles of all three AMS numbers were verified one by one from SAE records. The most important gap is TUBING: neither an AMS number nor an ASTM specification in force covers Kovar tube. Because ASTM F15 has been withdrawn, the expansion coefficient acceptance band must be written into the purchase order.<\/div>\n<\/div>\n<p><!-- \/dm-diy-std --><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Kovar&#8217;s ASTM basis disappeared in 2024 and most distributor pages still do not publish this. Read this section before you quote.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Standards by Product Form \u00b7 Kovar (K94610 \/ 1.3981)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Principal specification<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>ASTM F15 \u2014 \u201cStandard Specification for Iron-Nickel-Cobalt Sealing Alloy\u201d. WITHDRAWN 2024, NO REPLACEMENT.<\/b> The last valid edition is F15-04(2022). Scope: <b>UNS K94610<\/b>, nominally 29 % Ni \u2013 17 % Co \u2013 53 % Fe, for glass sealing in electronic applications. Forms covered: <b>wire, rod, bar, strip, sheet and tubing<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Wire<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>SAE AMS 7726<\/b> \u2014 wire<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Rod \u00b7 bar \u00b7 forgings<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>SAE AMS 7727<\/b> \u2014 bars and forgings<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Sheet \u00b7 strip \u00b7 plate<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>SAE AMS 7728<\/b> \u2014 sheet, strip and plate<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Tube<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Was covered by the withdrawn <b>F15<\/b>. Today: mill specification. Capillary tube is commercially available but <b>has no product specification<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Seamless or welded PIPE<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>No specification, and there never was one.<\/b> F15 covered <i>tubing<\/i>, not pressure pipe<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Wrought fittings \u00b7 flanges<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No specification<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Bolts \u00b7 nuts<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>No specification<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Castings<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Kovar has no cast equivalent and no casting specification.<\/b> Hermetic package bodies are made from wrought material by <b>deep drawing, stamping or machining<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Welding wire<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>No AWS classification.<\/b> Matched Kovar filler wire is commercially available but sold to <b>proprietary specification<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Covered electrode<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No specification.<\/b> Kovar is not welded with covered electrodes<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Military<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>MIL-I-23011<\/b> is cited by one distributor \u2014 <b>single source, could not be independently verified<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Europe<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Material number <b>1.3981<\/b>. Two publishers cite <b>DIN 17745<\/b> and <b>AFNOR NF A54-301<\/b>. <b>No current, in-force EN product specification could be verified<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>ASTM F29<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">One manufacturer&#8217;s bulletin also lists <b>ASTM F29<\/b> on the NILO K line. <b>Single source, and the scope of F29 could not be independently verified<\/b> \u2014 confirm before writing it on a certificate<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>ASME IX P \/ F number<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>\u2014 could not be verified. Do NOT publish a P or F number<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>ASME code acceptance<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>No published ASME pressure-vessel allowable stress table for Kovar could be verified.<\/b> Kovar is not marketed as a pressure-boundary material; <b>do not look for a maximum code temperature<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Inspection document<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>EN 10204 3.1<\/b>; <b>3.2<\/b> for critical hermetic work<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">What the withdrawal of F15 means in practice<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>The alloy is not banned; the document the certificate rested on is gone.<\/b> In the same 2024 round <b>ASTM F1684<\/b> (low-expansion alloys including Invar) and <b>ASTM F30<\/b> (Fe-Ni sealing alloys) were also withdrawn \u2014 the entire controlled-expansion family lost its ASTM basis at once. <b>For Kovar this carries particular weight<\/b>, because F15 was not only a chemistry table: <b>it also carried the expansion acceptance requirements and the hardness\/temper requirements<\/b>.<br \/><b>Three practical consequences.<\/b> (1) Cite the standard <b>with its edition year<\/b> in the purchase text: \u201c<b>ASTM F15-04(2022), withdrawn edition<\/b>\u201d. (2) <b>AMS 7726 \/ 7727 \/ 7728 remain in force<\/b> and are the strongest published specification route left for Kovar \u2014 cite the one that matches the form (wire \/ bar-forging \/ sheet-strip-plate). (3) Move the work the standard used to do <b>into the order text<\/b>: chemical ranges, <b>expansion measurement range and acceptance criterion<\/b>, temper and hardness, and <b>the as-delivered heat treatment condition (decarburised in wet hydrogen or not?)<\/b>.<\/p>\n<h4 id=\"dm-b2\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Temperature Limits \u2014 Kovar&#8217;s Real Ceiling Is 450 \u00b0C, for Two Reasons<\/h4>\n<p><!-- dm-diy-isil --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">HEAT TREATMENT \u2014 SCHEMATIC<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">1 \u00b7 ANNEALING \u2014 the usual delivery condition<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">1 \u00b7 ANNEALING \u2014 the usual delivery condition<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Standard anneal for parts that will not enter a glass-to-metal seal and for general use. It recrystallises the material and relieves internal stress. It gives no strength increase.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">850-1000 \u00b0C (1560-1830 \u00b0F), preferably in hydrogen or cracked ammonia \u2014 Special Metals NILO K. Alternative for sheet and strip: 999 \u00b0C for 30 minutes \u2014 EFINEA \/ Ed Fagan.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">According to section; 30 minutes for sheet and strip (EFINEA).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Furnace cool (EFINEA).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Typical annealed hardness 68 HRB (EFINEA, High Temp Metals, Ed Fagan, Aircraft Materials).<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">2 \u00b7 DECARBURIZING ANNEAL \u2014 WET HYDROGEN (mandatory for glass sealing)<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">2 \u00b7 DECARBURIZING ANNEAL \u2014 WET HYDROGEN (mandatory for glass sealing)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">This is the stage that determines the quality of the hermetic glass-to-metal seal. The wet hydrogen atmosphere removes carbon and dissolved gases. If glass sealing is attempted without this anneal, gas bubbles and leaks form in the seal.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">900-1050 \u00b0C (1650-1920 \u00b0F) \u2014 Special Metals NILO K. \u00b7 Two stages of 900 \u00b1 20 \u00b0C and 1100 \u00b1 20 \u00b0C \u2014 NiWire and High Temp Metals. \u00b7 A band of 840-1100 \u00b0C (1540-2010 \u00b0F) \u2014 Carpenter Technology.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">1 hour (Special Metals). \u00b7 1 hour at 900 \u00b0C plus 15 minutes at 1099-1100 \u00b0C (High Temp Metals, NiWire). \u00b7 20 minutes to 2 hours depending on temperature (Carpenter).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">To room temperature within one hour (High Temp Metals). \u00b7 At most 5 \u00b0C\/min down to 200 \u00b0C (NiWire).<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">3 \u00b7 CONTROLLED OXIDATION (before glass sealing)<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">3 \u00b7 CONTROLLED OXIDATION (before glass sealing)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">A thin, controlled oxide layer is formed on the surface so that the glass can wet the metal. This stage could not be verified numerically in four independent sources; no temperature or time is given and the existence of the stage is stated together with its source count.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">No figure given \u2014 it appears qualitatively in two independent sources; no numerical band could be verified in four.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">4 \u00b7 COLD WORKING \u2014 the only strengthening route<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">4 \u00b7 COLD WORKING \u2014 the only strengthening route<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">THERE IS NO PRECIPITATION HARDENING. Strength rises only with cold deformation. When intermediate annealing is needed, stage 1 is repeated; on parts that will enter a glass-to-metal seal the final operation is stage 2.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Room temperature<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">In cold-drawn wire and strip the tensile strength rises above 850 N\/mm2 (NiWire).<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">5 \u00b7 REGION TO AVOID \u2014 service above 450 \u00b0C<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Step<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">5 \u00b7 REGION TO AVOID \u2014 service above 450 \u00b0C<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Summary<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Not a heat treatment stage but a usage limit. The inflection point is 450 \u00b0C; above it the expansion coefficient rises sharply and the match with the glass ends. The Curie temperature is 435 \u00b0C and the magnetic transition is the cause of this behaviour.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Temperature<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Inflection point 450 \u00b0C \u2014 Special Metals, EFINEA. Curie temperature 435 \u00b0C \u2014 Carpenter, High Temp Metals, EFINEA, Hempel.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Time<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Cooling<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Resulting hardness<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">The mean expansion coefficient is 6.15 over 450-500 \u00b0C, 7.80 over 600-700 \u00b0C and 10.31 over 800-900 \u00b0C, in 10-6\/\u00b0C (High Temp Metals).<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\">The diagram is schematic; the time axis is NOT to scale. No published TTT\/CCT curve was used, so no curve is drawn. Kovar is NOT PRECIPITATION HARDENABLE and cannot be hardened by heat treatment. The purpose of these cycles is not hardness but PREPARING A SOFT AND CLEAN STRUCTURE FOR THE GLASS-TO-METAL SEAL: removing carbon and oxygen, ordering the grain structure and relieving internal stress. The word &#8216;ageing&#8217; is not used for this alloy. Schematic; the time axis is not to scale. NOT PRECIPITATION HARDENABLE \u2014 there is no solution treatment plus ageing cycle. Stage 3 (controlled oxidation) could not be verified numerically in four independent sources; no temperature or time is given. The decarburizing anneal is mandatory for a glass-to-metal seal; for general use stage 1 is sufficient.<\/div>\n<\/div>\n<p><!-- \/dm-diy-isil --><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Kovar&#8217;s service limit is not a code limit but the coincidence of two separate physical events.<\/b> Both occur at roughly the same temperature, and that coincidence defines the whole application window of the alloy.<\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">The Real Limits<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Glass matching window<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Approximately \u221280 \u00b0C to +450 \u00b0C.<\/b> Within this range Kovar&#8217;s expansion curve closely follows that of borosilicate glass and alumina ceramic. <b>This is a design window, not a strength limit<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Inflection point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>450 \u00b0C (840 \u00b0F)<\/b> \u2014 where the expansion curve bends. Above it expansion <b>climbs rapidly<\/b>: the 20\u2013450 \u00b0C mean is <b>5.3<\/b> while the 20\u2013500 \u00b0C mean is <b>6.2 \u00d7 10\u207b\u2076\/K<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Curie temperature<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>435 \u00b0C (815 \u00b0F)<\/b> \u2014 three independent publishers. <b>[Conflict]<\/b> One publisher writes <b>425 \u00b0C<\/b>. <b>435 \u00b0C and 450 \u00b0C are not the same thing<\/b>: one is where magnetic order is lost, the other is where the expansion curve bends<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>The glass strain point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>The strain point of 7052 borosilicate glass is 435\u2013440 \u00b0C.<\/b> That is the temperature above which the glass can no longer sustain stress and begins to flow. <b>Kovar&#8217;s Curie temperature and the glass strain point are practically the SAME temperature<\/b> \u2014 which is why 450 \u00b0C is a real ceiling for a glass-to-metal transition <b>for two separate reasons<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>What happens above 450 \u00b0C<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>The metal starts to expand faster than the glass and the match breaks down.<\/b> On cooldown the joint is left with a residual stress distribution different from the designed one. The result: cracked glass, interface separation, <b>loss of hermeticity<\/b>. <b>If you are designing a package with high-temperature cycling, treat 450 \u00b0C as a red line<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>The sealing temperature is ABOVE that ceiling<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">The softening point of 7052 glass is <b>710\u2013712 \u00b0C<\/b> and sealing is performed near there. <b>This is not a contradiction:<\/b> sealing is done while the glass is fluid and carries no stress; the service window must stay below the glass strain point<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Oxidation \u00b7 high temperature<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Kovar is not a high-temperature alloy.<\/b> No chromium, no protective oxide. An oxide that thickens above 600 \u00b0C in air <b>ruins the seal<\/b> \u2014 this property is used deliberately only in the controlled oxidising step<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>The cryogenic side<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">The lower end of the matching window is published as <b>\u221280 \u00b0C<\/b>. The alloy itself remains ductile far colder, but <b>no glass-matching guarantee is published below \u221280 \u00b0C<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b3\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Product Forms With NO Standard \u2014 the Commercially Valuable Section<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>After the withdrawal of F15 this list grew. These are the sentences a sales engineer should have memorised.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Specification Gaps for Kovar<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>General position (post-2024)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No in-force ASTM product specification remains for any form.<\/b> The published route that remains is the trio <b>AMS 7726 (wire) \/ 7727 (bar and forgings) \/ 7728 (sheet, strip, plate)<\/b>. <b>When a customer asks for an AMS number, give the one that matches the form<\/b>; listing all three is an error<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Pipe<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Never existed.<\/b> Kovar pipe is not a process pipe; do not confuse it with the <b>tube<\/b> used in vacuum feedthroughs<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Flanges \u00b7 fittings<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No standard.<\/b> A Kovar vacuum flange (for example in a CF\/ConFlat-type feedthrough) is machined <b>to drawing<\/b>; Kovar is not in the ASME B16.5 material list<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Castings<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>There is no standardised cast Kovar grade, and that is just as well.<\/b> Segregation and coarse grain in a casting <b>shift the expansion curve locally<\/b>; in a glass-to-metal seal that means a leak. Hermetic parts are made from <b>wrought material<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Welding consumables<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No AWS class.<\/b> Matched Kovar wire is sold to proprietary specification. <b>A weld bead expands differently in its own zone<\/b>; if a weld will run near a glass feedthrough, account for that distance in the design<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Plating specification<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Kovar has no plating specification of its own.<\/b> Established field practice is <b>1.3\u20133.8 \u00b5m (50\u2013150 microinches) nickel underplate + 1.3\u20132.5 \u00b5m (50\u2013100 microinches) gold<\/b>, but that is <b>a manufacturer&#8217;s recommendation<\/b>, not a standard. <b>You must write the thickness and the acceptance criterion yourself<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Decarburisation condition<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>This is the most critical gap.<\/b> No in-force product standard mandates whether the as-delivered condition is decarburised. <b>If it is not written into the order, material unsuitable for glass sealing will arrive and the certificate will not show it<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Expansion acceptance criterion<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">F15 carried the expansion requirements; it is withdrawn. <b>Write into the order text which expansion band you accept over which temperature range<\/b> \u2014 otherwise the only property that matters in this alloy is never measured on the certificate<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b4\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Chemical Composition \u2014 and How C, Mn, Si and S Limits Affect Glass Sealing<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Chemistry in Kovar does two separate jobs: it fixes the expansion curve, and it keeps the glass interface clean. The major elements do the first, the impurity ceilings the second.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Chemical Composition \u00b7 weight %<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Nickel<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>28.0\u201330.0<\/b> (two independent sources). Some publishers give a nominal <b>29.0<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Cobalt<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>17.0\u201318.0<\/b> (two independent sources). Nominal <b>17.0<\/b>. <b>This is the source of the DIN naming confusion:<\/b> some publishers write <b>FeNi29Co17<\/b>, others <b>FeNi29Co18<\/b> \u2014 the two ends of the same band<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Iron<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Balance (nominal ~53 %). One publisher gives a band of <b>50.5\u201356<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>CRITICAL NOTE on Ni, Co and Fe<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">The specification&#8217;s own wording: \u201c<b>The iron, nickel and cobalt percentages listed are nominal. They shall be adjusted by the MANUFACTURER so that the alloy meets the requirements for coefficient of thermal expansion.<\/b>\u201d <b>In other words, the governing acceptance criterion in Kovar is not chemistry but EXPANSION.<\/b> A heat that meets the chemistry table but fails the expansion band <b>is not Kovar<\/b>. That single sentence changes where you look when reading a certificate<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Carbon<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>[Conflict \u2014 the most important conflict on this page]<\/b> Published ceilings: <b>\u22640.04<\/b> (two sources reproducing the ASTM F15 route) \u00b7 <b>\u22640.05<\/b> (one European mill) \u00b7 <b>\u22640.03<\/b> (one supplier) \u00b7 <b>\u22640.02<\/b> (one US mill&#8217;s own typical ceiling) \u00b7 one encyclopaedic source says <b>&lt;0.01<\/b>. <b>If you are sealing to glass, demand the lowest ceiling and write it into the order<\/b> (see below)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Manganese<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>\u22640.50<\/b> \u00b7 one mill nominal <b>0.30<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Silicon<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>\u22640.20<\/b> (two sources) \u00b7 one European mill <b>\u22640.30<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Phosphorus \u00b7 Sulphur<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>P \u22640.03 \u00b7 S \u22640.03<\/b> (one European mill) \u00b7 <b>P \u22640.02 \u00b7 S \u22640.02<\/b> (one supplier)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Chromium \u00b7 Copper \u00b7 Molybdenum<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Cr \u22640.20 \u00b7 Cu \u22640.20 \u00b7 Mo \u22640.20<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Aluminium \u00b7 Magnesium \u00b7 Zirconium \u00b7 Titanium<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Each \u22640.10<\/b> (one source) \u00b7 another source states <b>the four combined \u22640.20<\/b>. <b>These are deoxidiser residues and are unwanted at the glass interface<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">C, Mn, Si and S \u2014 why glass sealing hangs on these<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Carbon: enemy number one.<\/b> Carbon dissolved in Kovar reacts in the glass-sealing furnace with the surface oxide and with the glass to produce <b>carbon monoxide and carbon dioxide<\/b>. That gas becomes trapped in the molten glass and at the glass-metal interface as <b>bubbles and blisters<\/b>. The consequences are: the bonded area shrinks and the joint weakens mechanically; and when blisters coalesce they <b>open a leak path<\/b>. Leaks seen in hermeticity testing usually originate here. <b>This is why Kovar is DECARBURISED in wet hydrogen before glass sealing<\/b> \u2014 it is not merely cleaned, carbon is physically removed from the alloy. <b>The decarburising anneal is not a cleaning step but a metallurgical operation, and it is MANDATORY for glass-to-metal sealing.<\/b><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Silicon and aluminium: they corrupt the quality of the oxide film.<\/b> What the seal bonds to is a deliberately grown <b>NiO\u2013CoO<\/b> film on the metal surface; the glass wets that film and dissolves it. Silicon and aluminium form <b>stable, stubborn oxides that do not dissolve in glass<\/b>; those oxides leave locally non-wetting islands within the film and weaken the bond. <b>That is why the Si and Al ceilings are held so low<\/b> \u2014 not for strength.<br \/><b>Manganese:<\/b> the ceiling is 0.50 %; more than that changes the composition and colour of the oxide film and makes the process harder to control.<br \/><b>Sulphur and phosphorus:<\/b> they segregate to grain boundaries. Sulphur governs both <b>hot cracking in welds<\/b> and <b>tearing in deep drawing and stamping<\/b>; since hermetic package bodies are usually deep drawn, this is directly a yield issue.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>The one sentence that reaches purchasing:<\/b> on a Kovar order, write the <b>carbon ceiling and the decarburisation condition separately<\/b>. \u201cKovar to ASTM F15\u201d \u2014 even if the standard were still in force \u2014 <b>does not guarantee that material arrives ready for glass sealing<\/b>.<\/p>\n<h4 id=\"dm-b5\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Mechanical Properties<\/h4>\n<p><!-- dm-diy-sert --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">STRENGTH VALUES<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:12px 10px 0;\"><svg viewBox=\"0 0 740 364\" style=\"width:100%;height:auto;display:block;\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\" role=\"img\"><rect x=\"16\" y=\"6\" width=\"12\" height=\"12\" fill=\"#12303f\"\/><text x=\"34\" y=\"16\" font-size=\"11.5\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Yield (MPa)<\/text><rect x=\"146\" y=\"6\" width=\"12\" height=\"12\" fill=\"#7fa8bd\"\/><text x=\"164\" y=\"16\" font-size=\"11.5\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Tensile (MPa)<\/text><text x=\"16\" y=\"44\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed \u2014 strip and sheet<\/text><rect x=\"16\" y=\"50\" width=\"396.6\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"419.6\" y=\"62\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">517<\/text><rect x=\"16\" y=\"68\" width=\"264.6\" height=\"15\" fill=\"#12303f\"\/><text x=\"287.6\" y=\"80\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">345<\/text><text x=\"16\" y=\"108\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed \u2014 Special Metals NILO K<\/text><rect x=\"16\" y=\"114\" width=\"398.9\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"421.9\" y=\"126\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">520<\/text><rect x=\"16\" y=\"132\" width=\"260.8\" height=\"15\" fill=\"#12303f\"\/><text x=\"283.8\" y=\"144\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">340<\/text><text x=\"16\" y=\"172\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed \u2014 Aircraft Materials<\/text><rect x=\"16\" y=\"178\" width=\"398.9\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"421.9\" y=\"190\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">520<\/text><rect x=\"16\" y=\"196\" width=\"260.8\" height=\"15\" fill=\"#12303f\"\/><text x=\"283.8\" y=\"208\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">340<\/text><text x=\"16\" y=\"236\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed \u2014 upper bound (sheet and strip)<\/text><rect x=\"16\" y=\"242\" width=\"433.4\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"456.4\" y=\"254\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">565<\/text><text x=\"16\" y=\"282\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Annealed \u2014 upper bound (rod and wire)<\/text><rect x=\"16\" y=\"288\" width=\"449.5\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"472.5\" y=\"300\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">586<\/text><text x=\"16\" y=\"328\" font-size=\"12.5\" font-weight=\"bold\" fill=\"#12303f\" font-family=\"Arial,Helvetica,sans-serif\">Cold drawn (hard) \u2014 wire and strip<\/text><rect x=\"16\" y=\"334\" width=\"652.0\" height=\"15\" fill=\"#7fa8bd\"\/><text x=\"675.0\" y=\"346\" font-size=\"11.5\" fill=\"#5b7180\" font-family=\"Arial,Helvetica,sans-serif\">850<\/text><\/svg><\/div>\n<div style=\"padding:12px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"overflow-x:auto;position:relative;z-index:2;\">\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;min-width:430px;background:transparent;\">\n<tr>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Condition<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Hardness<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Yield MPa<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Tensile MPa<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Elongation<\/th>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Annealed \u2014 strip and sheet<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">68 HRB<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">345<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">517<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">30%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Annealed \u2014 Special Metals NILO K<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">340<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">520<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">42%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Annealed \u2014 Aircraft Materials<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">340<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">520<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">42%<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Annealed \u2014 upper bound (sheet and strip)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">565 max<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Annealed \u2014 upper bound (rod and wire)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">586 max<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Cold drawn (hard) \u2014 wire and strip<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">above 850<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">\u2014<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\"><b style=\"color:#12303f;\">Because ASTM F15 was withdrawn in 2024 there is NO ASTM specification minimum in force for this alloy; the specifications in force are AMS 7726\/7727\/7728, of which only the titles could be verified in this work \u2014 their mechanical tables were not read. Every row below is a PRODUCER TYPICAL VALUE and cannot be used as a specification minimum. Because Kovar is not precipitation hardenable, the rows are split by TEMPER, not by ageing condition. This alloy is bought for its expansion curve and not for its strength; the table is supplementary.<\/b> There is NO ASTM SPECIFICATION MINIMUM in force; ASTM F15 was withdrawn in 2024. All rows are producer typical values. There are two clusters of elongation values: 30% (EFINEA\/Ed Fagan\/High Temp Metals) and 42% (Special Metals\/Aircraft Materials). No average has been taken; the two clusters are given on separate rows. There is no precipitation hardening; the last row shows cold work. This alloy is bought for its expansion curve and not for its strength.<\/div>\n<\/div>\n<p><!-- \/dm-diy-sert --><\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Kovar is a soft, ductile, deep-drawable alloy and is never bought for strength. Do not mix the two source groups below.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Annealed \u00b7 Typical Values<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Source A (US route)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm <b>517 MPa (75 ksi)<\/b> \u00b7 Rp0.2 <b>345 MPa (50 ksi)<\/b> \u00b7 Elongation <b>30 %<\/b> (in 2 in) \u00b7 <b>68 HRB<\/b> \u00b7 E <b>138 GPa (20 \u00d7 10\u00b3 ksi)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Source B (European manufacturer&#8217;s bulletin)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">20 \u00b0C: Rm <b>520 MPa<\/b> \u00b7 Rp0.2 <b>340 MPa<\/b> \u00b7 A <b>42 %<\/b> \u00b7 Reduction of area 72 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">100 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm 430 \u00b7 Rp0.2 260 \u00b7 A 42 % \u00b7 72 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">200 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Rm 400 \u00b7 Rp0.2 210 \u00b7 A 42 % \u00b7 72 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">300 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm 400 \u00b7 Rp0.2 140 \u00b7 A 45 % \u00b7 73 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">400 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Rm 400 \u00b7 Rp0.2 110 \u00b7 A 49 % \u00b7 76 %<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Source C (European mill sheet)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Rm <b>450\u2013585 MPa<\/b> \u00b7 Rp0.2 <b>\u2265200 MPa<\/b> \u00b7 A <b>\u226525 %<\/b> \u00b7 <b>110\u2013170 HV<\/b>. <b>Rm here is a BAND<\/b>, not a single value<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Elongation conflict<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>[Conflict]<\/b> Three sources give <b>30 %<\/b>, <b>42 %<\/b> and <b>\u226525 %<\/b>. Most of the difference comes from <b>gauge length and product form<\/b>. <b>Do not impose an elongation requirement without stating the gauge length<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Upper limits by product form<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">One source gives Rm <b>max 570 MPa (82 ksi)<\/b> for sheet\/strip and <b>max 585 MPa (85 ksi)<\/b> for rod\/wire. <b>In Kovar the upper limit matters too<\/b>: material that is too hard tears in deep drawing and its expansion curve may shift after annealing<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Hardness bands<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Annealed <b>\u2264160 HV (\u226483 HRB)<\/b> \u00b7 full hard <b>\u2265230 HV (\u226597 HRB)<\/b>. One US source gives <b>68 HRB<\/b> annealed, another <b>120 HB<\/b>. <b>Always state the scale<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Modulus conflict<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>138\u2013139 GPa<\/b> (three sources) \u00b7 <b>130 GPa<\/b> (one manufacturer&#8217;s bulletin, as-rolled). <b>Use 138 GPa for calculation<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b6\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Physical Properties<\/h4>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Physical Properties \u00b7 Kovar (K94610)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Density<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>8.36 g\/cm\u00b3<\/b> (0.302 lb\/in\u00b3) \u2014 three independent sources. <b>[Conflict]<\/b> One manufacturer&#8217;s bulletin gives <b>8.16<\/b>, one distributor <b>8.25<\/b>. <b>8.36 is the majority and mill position; use it and footnote the difference<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Melting point<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>1450 \u00b0C<\/b> (2640 \u00b0F) \u2014 three sources agree. One publisher gives a band of <b>1440\u20131460 \u00b0C<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Thermal conductivity (20 \u00b0C)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>17 W\/m\u00b7K<\/b> (three sources in the 16.7\u201317.6 range; 0.17 W\/cm\u00b7\u00b0C is the same number). <b>Clearly above Invar 36&#8217;s ~10 W\/m\u00b7K<\/b> \u2014 a real difference for heat removal in a hermetic package, but still less than half that of carbon steel<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Electrical resistivity<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>49 \u00b5\u03a9\u00b7cm<\/b> at 20 \u00b0C \u2014 two independent sources (294 ohm-cir-mil\/ft is the same number). <b>[Conflict]<\/b> One manufacturer&#8217;s bulletin gives <b>43 \u00b5\u03a9\u00b7cm<\/b> at 20 \u00b0C, rising to <b>114 \u00b5\u03a9\u00b7cm<\/b> at 600 \u00b0C. <b>49 \u00b5\u03a9\u00b7cm is the majority value<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">Specific heat<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>~0.46 kJ\/kg\u00b7K<\/b> (0.11 Btu\/lb\u00b7\u00b0F) \u00b7 one distributor gives <b>0.50 J\/g\u00b7\u00b0C<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">Modulus of elasticity<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>138 GPa<\/b> (20 \u00d7 10\u00b3 ksi) \u00b7 one bulletin 130 GPa<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Curie temperature<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>435 \u00b0C (815 \u00b0F)<\/b> \u2014 three sources. <b>[Conflict]<\/b> one distributor writes 425 \u00b0C<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Inflection point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>450 \u00b0C (840 \u00b0F)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Magnetic behaviour<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>FERROMAGNETIC below the Curie temperature.<\/b> This is a real constraint that is missed in electronic package design: a Kovar-bodied package <b>distorts the local magnetic field<\/b> and causes trouble for magnetically sensitive circuits (Hall sensors, magnetometers, some MEMS gyroscopes, RF ferrite components). <b>No numerical relative permeability value could be found \u2014 do not publish a \u00b5r figure<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>The commercially meaningful point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Kovar is magnetic, rust-prone, soft and expensive.<\/b> All of that is accepted for one thing: <b>an expansion curve that matches borosilicate glass and alumina ceramic between \u221280 and +450 \u00b0C<\/b>. Outside that window Kovar has no advantage at all<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">MEAN COEFFICIENT OF THERMAL EXPANSION \u00b7 10\u207b\u2076\/K \u00b7 THE MOST IMPORTANT TABLE ON THIS PAGE<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">25 \u2192 100 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>5.85<\/b> \u00b7 second manufacturer <b>5.86<\/b> \u00b7 third manufacturer (20\u2013100 \u00b0C) <b>6.0<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">25 \u2192 200 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>5.20<\/b> \u00b7 third manufacturer (20\u2013200 \u00b0C) <b>5.5<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">25 \u2192 300 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>5.13<\/b> \u00b7 second manufacturer <b>5.13<\/b> \u00b7 third manufacturer <b>5.1<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">25 \u2192 350 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>4.90<\/b> \u00b7 third manufacturer <b>4.9<\/b> \u2014 <b>the MINIMUM of the curve is here<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">25 \u2192 400 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>5.06<\/b> \u00b7 third manufacturer <b>4.9<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">25 \u2192 450 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>5.26<\/b> \u00b7 second manufacturer <b>5.25<\/b> \u00b7 third manufacturer <b>5.3<\/b> \u2014 <b>the upper edge of the matching window<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">25 \u2192 500 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>6.14<\/b> \u00b7 third manufacturer <b>6.2<\/b> \u2014 <b>past the inflection point<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">25 \u2192 600 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>7.81<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">25 \u2192 700 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>9.11<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\">25 \u2192 800 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>10.31<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\">25 \u2192 900 \u00b0C<\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>11.25<\/b> \u2014 <b>now it behaves like ordinary steel<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Verification<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">This table is a unit conversion of a US manufacturer&#8217;s \u00b0F table and it matches a European mill&#8217;s \u00b0C table <b>exactly at three points<\/b> (5.86 \/ 5.13 \/ 5.25). A third manufacturer&#8217;s 20 \u00b0C-based table gives the same curve <b>within \u00b10.3<\/b>. <b>Three independent publishers show the same curve<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>The SHAPE of the curve \u2014 the real point<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Note that the value is <b>5.85<\/b> over 25\u2013100 \u00b0C, then <b>FALLS<\/b> to <b>4.90<\/b> over 25\u2013350 \u00b0C, then rises again. <b>That dip is not an accident; it is engineered to match the glass curve.<\/b> What separates Kovar from Invar is not a low number but <b>this S shape<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Compared with the glass<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>7052 borosilicate glass: 4.6\u20134.7 \u00d7 10\u207b\u2076\/K over 0\u2013300 \u00b0C<\/b>, and <b>5.3 \u00d7 10\u207b\u2076\/K<\/b> from 25 \u00b0C to the setting point. Kovar over the same ranges is <b>5.13<\/b> and <b>5.26<\/b>. <b>The difference is a few percent and it is deliberate<\/b> \u2014 because the metal contracts slightly more, the glass is left in <b>compression<\/b>. <b>Glass is strong in compression and weak in tension; a good glass-to-metal seal keeps the glass in slight compression<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b7\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Heat Treatment \u2014 the Wet Hydrogen Decarburising Anneal and Controlled Oxidation<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Heat treatment in Kovar is done for the GLASS INTERFACE, not for strength. This is the section anyone making glass-to-metal seals must read.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Four Distinct Operations \u2014 Their ORDER and PURPOSE Must Not Be Confused<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>1 \u00b7 Standard anneal (softening)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>850\u20131000 \u00b0C (1560\u20131830 \u00b0F)<\/b>, preferably in <b>hydrogen or cracked ammonia<\/b> (one manufacturer&#8217;s bulletin). A European mill specifies <b>850 \u00b0C for 30 minutes<\/b> in a protective atmosphere (wet or dry hydrogen, dissociated ammonia or a similar neutral atmosphere) and requires <b>furnace cooling to about 175 \u00b0C to prevent oxidation and thermal shock<\/b>. <b>This step restores ductility; it does not prepare the part for glass sealing<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>2 \u00b7 WET HYDROGEN DECARBURISING ANNEAL \u2014 MANDATORY for glass sealing<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>900\u20131050 \u00b0C (1650\u20131920 \u00b0F) for 1 hour in a wet hydrogen atmosphere<\/b> (one manufacturer&#8217;s bulletin). A US mill describes the same operation as: <b>\u201call degreased, fabricated Kovar alloy parts should be degassed and annealed in a wet hydrogen atmosphere\u201d<\/b>; temperature <b>838\u20131099 \u00b0C (1540\u20132010 \u00b0F)<\/b>, time <b>about 2 hours<\/b> at the low end and <b>20 minutes<\/b> at the high end, then <b>cool below 300 \u00b0C (570 \u00b0F)<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Why WET hydrogen?<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Dry hydrogen degasses but does NOT remove carbon.<\/b> The water vapour in wet hydrogen <b>oxidises the dissolved carbon to CO and CO\u2082, which escape<\/b>. At the end of the operation the alloy is both <b>decarburised<\/b> and has a <b>controlled surface condition<\/b>. <b>Skip this step and the carbon produces CO\/CO\u2082 in the sealing furnace, leaves bubbles and blisters at the interface, and HERMETICITY IS LOST<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>The ORDER of operations is critical<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Fabricate first, then degrease, then decarburise.<\/b> Machining and drawing oils leave carbon on the surface; <b>a decarburising anneal performed BEFORE those operations is wasted<\/b>. One mill&#8217;s own wording makes this explicit: the treatment is applied to <b>\u201cdegreased, fabricated\u201d<\/b> parts<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>3 \u00b7 Controlled oxidation (immediately before glass sealing)<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>600\u20131000 \u00b0C (1110\u20131830 \u00b0F) in air<\/b>, depending on the film thickness required (one manufacturer&#8217;s bulletin). A US mill gives a narrower window: <b>650\u2013700 \u00b0C (1200\u20131290 \u00b0F)<\/b> until a <b>dark grey to slightly brown<\/b> oxide forms. That film is <b>NiO\u2013CoO<\/b> based and it is what the glass wets and dissolves<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Oxide COLOUR is a quality indicator<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>Grey, grey-blue or grey-brown = a good seal.<\/b> <b>A metallic colour = insufficient oxide<\/b> (the glass does not wet, the bond is weak). <b>Black = over-oxidised<\/b> (the film is thick and brittle, the bond is again weak). <b>Both extremes mean a weak joint.<\/b> This is a shop-floor visual check that no distributor page publishes<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>4 \u00b7 Stress relief<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>No separate stress relief temperature or time for Kovar could be independently verified.<\/b> In practice the annealing and decarburising treatments also relieve stress. <b>Do not invent a number<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Cooling rule<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">One European mill requires furnace cooling to <b>~175 \u00b0C<\/b> after annealing; a US mill requires cooling <b>below 300 \u00b0C<\/b> after decarburisation. The purpose is the same: <b>prevent a hot part from meeting air and oxidising uncontrollably, and prevent thermal shock<\/b><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b8\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Welding, Soldering and Plating<\/h4>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Joining Methods<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Suitable welding processes<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>TIG (GTAW), electron beam, laser and resistance (seam) welding<\/b> \u2014 all four are published and established in the field. Hermetic package lids are typically closed by <b>parallel seam resistance welding or laser<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Filler metal<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>No AWS classification.<\/b> Matched Kovar wire is sold to proprietary specification. <b>Using a foreign filler creates a band in the weld that expands differently<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Welding near a glass feedthrough \u2014 the most common mistake<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Weld heat damages the glass-to-metal joint.<\/b> The weld must be <b>far enough<\/b> from the feedthrough and the heat sink path must be considered; otherwise the glass cracks or the interface separates. <b>A part decarburised before welding can locally pick up carbon again in the HEAT AFFECTED ZONE<\/b> \u2014 if glass sealing follows welding, review the operation sequence<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Soldering and brazing<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Kovar is routinely <b>soldered and brazed<\/b>, but <b>not directly<\/b>: with no chromium the surface oxidises rapidly and solder will not wet it. <b>That is why it is nickel plated first<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>NICKEL PLATING \u2014 why it is mandatory<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Three separate reasons.<\/b> (1) <b>Corrosion:<\/b> Kovar has no chromium and rusts in humid air; the nickel underplate is the barrier. (2) <b>Solderability:<\/b> a nickel surface is wetted by solder and braze alloys, bare Kovar is not. (3) <b>Conductivity and interconnect:<\/b> Kovar&#8217;s electrical conductivity is poor (<b>49 \u00b5\u03a9\u00b7cm<\/b>); the gold top layer provides wire bonding and a low-resistance contact. <b>Established practice: 1.3\u20133.8 \u00b5m (50\u2013150 microinches) nickel + 1.3\u20132.5 \u00b5m (50\u2013100 microinches) gold<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>A caution on gold plating<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Gold thickness <b>must be controlled<\/b>: excess gold forms brittle gold-tin intermetallics in a solder joint. <b>There is no published plating specification for Kovar<\/b>; you must write the thickness and acceptance criterion yourself<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>The sequence of sealing and plating<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Glass sealing FIRST, plating AFTERWARDS.<\/b> Glass is not sealed to a plated surface \u2014 what the glass bonds to is the nickel-cobalt oxide film, not the nickel plate. <b>A production flow that reverses this order will not pass a hermeticity test<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Hydrogen embrittlement<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Hydrogen from an electrolytic nickel plating bath can cause trouble in stressed thin sections. <b>No published bake-out schedule for Kovar could be found<\/b> \u2014 do not invent a temperature and time; use your plater&#8217;s own qualified schedule<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b9\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Machining<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Kovar is not as difficult as Invar 36, but it is not easy either.<\/b> It comes from the same family and behaves the same way: it <b>work-hardens like austenitic stainless<\/b>, produces <b>stringy, gummy chips<\/b> and wraps them around the tool. The one thing in its favour is a thermal conductivity about <b>1.7 times<\/b> that of Invar (<b>17 W\/m\u00b7K<\/b> versus <b>10 W\/m\u00b7K<\/b>), so heat leaves the tool tip a little better. <b>Do not raise speeds on the strength of that.<\/b><\/p>\n<div style=\"border:1px solid #d7dfe4;background:#ffffff;margin:24px 0 18px;position:relative;overflow:hidden;\">\n<div style=\"background:#DD3333;color:#ffffff;font-size:13px;font-weight:700;letter-spacing:.04em;text-transform:uppercase;padding:10px 12px;line-height:1.35;\">Machining \u00b7 Kovar (parameters published for the NILO family)<\/div>\n<p><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<table style=\"border-collapse:collapse;width:100%;font-size:15px;line-height:1.5;\">\n<tbody>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>General rule<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Machine in the annealed condition<\/b>, with <b>high speed steel or tungsten carbide tipped tools<\/b> (manufacturer&#8217;s bulletin). Machining in the hard temper increases work hardening and distortion<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Rough turning<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\"><b>30\u201345 m\/min (98\u2013148 ft\/min)<\/b> \u00b7 feed <b>0.25\u20130.40 mm\/rev<\/b> (typical values published by the manufacturer for the NILO family)<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Tool geometry<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Large, sharp, rigidly supported<\/b> tools; <b>positive top rake<\/b>. Interrupted cuts, dwelling and successive thin cuts create a <b>glazed, work-hardened surface<\/b> \u2014 restarting a cut in it is very difficult<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Coolant<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Sulphurised\/chlorinated cutting oils break chips well. <b>BUT a Kovar-specific warning:<\/b> cutting oil and cutting fluid leave <b>carbon<\/b> on the surface. On parts destined for glass sealing this demands <b>complete degreasing before the decarburising anneal<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>MANDATORY post-fabrication step<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\"><b>Every finished Kovar part must be degreased and decarburised in wet hydrogen before glass sealing.<\/b> Machining adds both cold work and surface carbon; both are removed in that anneal. <b>This is not an optional step<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;\"><b>Deep drawing and stamping<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;\">Hermetic package bodies are typically produced by <b>deep drawing<\/b>. Kovar takes it well but <b>intermediate anneals are required<\/b>; material forced in the hard temper tears. <b>The sulphur ceiling is directly a yield question here<\/b><\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;font-weight:700;color:#12303f;width:42%;background:#F7FAFB;\"><b>Magnetic workholding<\/b><\/td>\n<td style=\"padding:7px 12px;border-top:1px solid #eceff1;background:#F7FAFB;\">Kovar is ferromagnetic, so a magnetic chuck <b>works<\/b>. But <b>demagnetise afterwards<\/b>: residual magnetism makes fine chips cling to the part and contaminates the plating and sealing steps<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<h4 id=\"dm-b10\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Corrosion \u2014 Kovar Is NOT Stainless<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Kovar is not a corrosion alloy. It rusts. The fact that it is used in hermetic packages does not change that \u2014 those packages are plated.<\/b><\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Why it rusts<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\">In Kovar <b>chromium exists only as an impurity ceiling (\u22640.20 %)<\/b>, which is <b>nowhere near<\/b> enough to form a passive oxide film. The bulk of the alloy is <b>iron<\/b> (~53 %). Nickel and cobalt add some resistance but <b>do not passivate<\/b>. <b>For corrosion purposes, think of Kovar as a low-alloy steel.<\/b> That is not what the alloy was designed for anyway: its chemistry is chosen entirely for <b>the expansion curve and the glass interface<\/b>.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Where it is GOOD<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>It is good when plated and enclosed.<\/b> The field reality is that almost all Kovar components are used <b>nickel + gold plated<\/b>, and corrosion resistance comes <b>from the plating, not from the alloy<\/b>. <b>In vacuum and inside a dry hermetic cavity<\/b> there is no corrosion problem \u2014 keeping the inside dry and inert is the whole point of a hermetic package. <b>Bare Kovar stored in a dry, climate-controlled environment<\/b> is fine for reasonable periods.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">WHERE IT FAILS \u2014 the list that must be published<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>1. Bare Kovar plus humid air.<\/b> Unplated Kovar <b>rusts<\/b> in a humid environment. Condensation in storage, moisture in transit, sweating in the shop all produce surface rust \u2014 and <b>you cannot seal glass to a rusted surface<\/b>.<br \/><b>2. Seawater, chlorides and salt spray.<\/b> <b>No resistance whatsoever.<\/b> Electronic packages in marine environments are protected <b>by plating and enclosure<\/b>, not by the alloy.<br \/><b>3. Acids.<\/b> With no chromium and no molybdenum it is unprotected in both reducing and oxidising acids. <b>Kovar is not a process equipment material.<\/b><br \/><b>4. Plating pinholes.<\/b> This is the most insidious failure mode. Micro-pores in the nickel plate create <b>galvanically accelerated local corrosion<\/b> beneath the gold: <b>gold is the cathode and Kovar the anode<\/b>, and that couple <b>accelerates<\/b> corrosion at the bottom of the pore. This is why nickel underplate thickness and freedom from porosity are critical \u2014 gold alone is not enough.<br \/><b>5. Fingerprints.<\/b> Kovar parts destined for glass sealing <b>must not be handled with bare hands<\/b>. Hand perspiration contains chloride and organic acids; it both pits the surface and prevents the oxide film from forming evenly.<br \/><b>6. Furnace atmosphere upsets.<\/b> If atmosphere control is lost in the decarburising or oxidising furnace, the surface ends up with an oxide of the <b>wrong thickness or wrong composition<\/b>; <b>a black (over-oxidised) surface gives a weak bond to glass<\/b>. That is not corrosion, but it leads to the same outcome \u2014 a leak.<br \/><b>7. Long open storage.<\/b> For unplated Kovar strip and bar, <b>VCI packaging, dry storage and a protective film are mandatory<\/b>.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Be honest about numerical corrosion data:<\/b> no published corrosion rate table, PREN value or critical pitting temperature for Kovar could be found \u2014 and none of those would be meaningful for this alloy anyway. <b>Do not publish a corrosion rate figure.<\/b><\/p>\n<h4 id=\"dm-b11\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Frequently Asked Questions<\/h4>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Can we skip the decarburising anneal and go straight to glass sealing? Furnace time is expensive.<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>No. This is the most expensive shortcut in glass-to-metal sealing, and its failures often show up not in the hermeticity test but in the field.<\/b><br \/>Here is why. Carbon dissolved in Kovar reacts in the sealing furnace with the surface oxide and with the glass to produce <b>carbon monoxide and carbon dioxide<\/b>. That gas becomes trapped inside the molten glass and precisely at the <b>glass-metal interface<\/b>: bubbles and blisters form. They have two consequences \u2014 <b>the bonded area shrinks<\/b> and the joint weakens mechanically; and when blisters coalesce they open a <b>leak path along the interface<\/b>. A part that barely passes a helium leak test drifts outside the limit after a few thermal cycles.<br \/><b>The correct sequence is:<\/b> finish fabrication \u2192 <b>complete degreasing<\/b> (cutting and drawing oils leave carbon on the surface) \u2192 <b>wet hydrogen decarburising anneal<\/b> (900\u20131050 \u00b0C for 1 hour; another mill says 838\u20131099 \u00b0C, about 2 hours at the low end and 20 minutes at the high end, then cool below 300 \u00b0C) \u2192 <b>controlled oxidation<\/b> (650\u2013700 \u00b0C until a dark grey to slightly brown film forms) \u2192 <b>glass sealing<\/b> \u2192 <b>plating<\/b>.<br \/><b>The difference between wet and dry hydrogen lies exactly here:<\/b> dry hydrogen degasses but does not remove carbon. What removes carbon is the <b>water vapour in wet hydrogen oxidising it to CO and CO\u2082<\/b>.<br \/><b>Commercial advice:<\/b> if you want to save furnace time, this is not the step to save it on. <b>Write \u201cdelivered decarburised in wet hydrogen\u201d into the order<\/b> and buy the material in that condition \u2014 but remember it must be repeated after fabrication.<\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Our package goes through a furnace that reaches 500 \u00b0C. Will Kovar be a problem?<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Yes. 450 \u00b0C is a genuine red line in this alloy, and for two reasons \u2014 both of which occur at about the same temperature.<\/b><br \/><b>The first is in the metal:<\/b> the inflection point of Kovar&#8217;s expansion curve is <b>450 \u00b0C<\/b> and the Curie temperature is <b>435 \u00b0C<\/b>. Above these points expansion <b>climbs rapidly<\/b>: the 25\u2013450 \u00b0C mean is <b>5.26<\/b>, but at 25\u2013500 \u00b0C it is <b>6.14<\/b>, at 25\u2013600 \u00b0C <b>7.81<\/b> and at 25\u2013700 \u00b0C <b>9.11 \u00d7 10\u207b\u2076\/K<\/b>. In a cycle reaching 500 \u00b0C the metal expands <b>more<\/b> than the glass expects.<br \/><b>The second is in the glass:<\/b> the <b>strain point of 7052 borosilicate glass is 435\u2013440 \u00b0C<\/b>. Above that the glass is no longer elastic and <b>relieves stress permanently<\/b>. When the part cools, the joint is left with a residual stress distribution <b>different from the one that was designed<\/b>. The design holds the glass in slight <b>compression<\/b>; when that balance is disturbed, the glass can be driven into <b>tension<\/b> \u2014 and glass is weak in tension.<br \/><b>Practical outcome:<\/b> a 500 \u00b0C process cycle <b>may not break a hermetic Kovar\u2013borosilicate transition in one pass, but it raises the probability of a leak with cycle count<\/b>. <b>What to do:<\/b> bring the process temperature below 450 \u00b0C; or replace the transition with a <b>ceramic-to-metal<\/b> solution (alumina with an active metal braze); or <b>change the assembly sequence<\/b> so the glass feedthrough stays out of the furnace cycle. <b>What not to do is reason that \u201cKovar melts at 1450 \u00b0C\u201d and treat 500 \u00b0C as safe. The melting point is completely irrelevant here.<\/b><\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Our datasheet says Corning 7052. Our supplier says they cannot get 7052. Now what?<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>Your supplier is right. Corning 7052 has been discontinued since 1991.<\/b> The published succession is: <b>7052 \u2192 Corning 7056 \u2192 Corning 7720 \u2192 today Schott 8250<\/b>. When you ask for \u201cKovar sealing glass\u201d today, what you actually get is <b>Schott 8250<\/b> or an equivalent.<br \/><b>This does not make old specifications worthless<\/b> \u2014 but you must rewrite the specification <b>against the glass PROPERTY, not the glass brand<\/b>. The numbers to hold on to, for 7052: <b>46\u201347 \u00d7 10\u207b\u2077\/\u00b0C over 0\u2013300 \u00b0C<\/b> (i.e. 4.6\u20134.7 \u00d7 10\u207b\u2076\/K), <b>53 \u00d7 10\u207b\u2077\/\u00b0C<\/b> from 25 \u00b0C to the setting point, <b>strain point 435\u2013440 \u00b0C<\/b>, <b>annealing point 480\u2013484 \u00b0C<\/b>, <b>softening point 710\u2013712 \u00b0C<\/b>, <b>density 2.27 g\/cm\u00b3<\/b>. Ask how close the new glass is to those values.<br \/><b>Why it matters:<\/b> Kovar over the same ranges gives <b>5.13<\/b> and <b>5.26 \u00d7 10\u207b\u2076\/K<\/b>. The metal contracts <b>a few percent more<\/b> than the glass, and that difference keeps the glass in <b>compression<\/b> \u2014 which is the design principle of a good glass-to-metal seal. If the new glass expands appreciably differently, <b>that balance is disturbed<\/b> and the transition must be requalified.<br \/><b>What to do:<\/b> write the specification as \u201c<b>borosilicate sealing glass matched to Kovar (K94610), expansion 4.6\u20134.7 \u00d7 10\u207b\u2076\/K over 0\u2013300 \u00b0C, strain point \u2265435 \u00b0C<\/b>\u201d and give the brand name as an <b>example<\/b>. <b>Any document that makes a brand name the specification eventually goes out of supply.<\/b><\/p>\n<p style=\"margin:18px 0 6px;font-size:15px;font-weight:700;color:#12303f;line-height:1.5;\">Invar 36 expands less and costs less. Can we use it instead of Kovar?<\/p>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>No \u2014 and \u201cexpands less\u201d is precisely the wrong part of that sentence.<\/b><br \/>What a hermetic glass-to-metal transition needs is <b>not low expansion but MATCHED expansion<\/b>. Invar 36 gives <b>1.5 \u00d7 10\u207b\u2076\/K<\/b> over 20\u2013100 \u00b0C; borosilicate glass over the same region gives <b>4.6\u20134.7<\/b>. The difference is <b>more than threefold<\/b>. In a glass-to-metal seal that means a mismatch accumulating through cooldown that puts the glass <b>into tension<\/b> \u2014 and glass is weak in tension and cracks.<br \/>The second and less known difference is <b>the SHAPE of the curve<\/b>. Kovar&#8217;s coefficient is <b>5.85<\/b> over 25\u2013100 \u00b0C, <b>falls<\/b> to <b>4.90<\/b> over 25\u2013350 \u00b0C, then rises again to <b>5.26<\/b> over 25\u2013450 \u00b0C. That dip is not an accident; <b>it is engineered to follow the glass&#8217;s own curve<\/b>. Invar&#8217;s curve, by contrast, <b>climbs continuously<\/b> above 220 \u00b0C (5.5 over 20\u2013300 \u00b0C, 10.1 over 20\u2013500 \u00b0C). <b>The two curves are nowhere parallel.<\/b><br \/>The third difference is <b>cobalt<\/b>. The seal bonds through a <b>nickel-cobalt oxide<\/b> film grown on the metal surface, and <b>cobalt makes that oxide easier to melt and to dissolve in the glass<\/b>. Invar has no cobalt; its oxide is largely iron oxide and does not behave the same way in glass.<br \/><b>In short:<\/b> buy Invar 36 for dimensional stability \u2014 optical benches, metrology frames, composite tooling, LNG membranes. <b>Buy Kovar for a hermetic glass-to-metal transition.<\/b> The price difference is trivial next to the cost of a single leaking package.<\/p>\n<h4 id=\"dm-b12\" style=\"font-size:19px;font-weight:700;color:#12303f;margin:30px 0 10px;line-height:1.35;\">Common Datasheet Errors \u2014 Check Before You Order<\/h4>\n<p style=\"margin:0 0 12px;font-size:15px;line-height:1.75;\"><b>1. Missing the withdrawal of ASTM F15.<\/b> <b>F15 was withdrawn in 2024 with no replacement<\/b> \u2014 and <b>F1684<\/b> and <b>F30<\/b> went with it. Most pages that still say \u201cconforms to ASTM F15\u201d do not know this. <b>Cite the edition year<\/b>, and know that <b>AMS 7726\/7727\/7728<\/b> are still in force.<br \/><b>2. Not separating the AMS numbers by form.<\/b> <b>7726 = WIRE<\/b>, <b>7727 = BAR and FORGINGS<\/b>, <b>7728 = SHEET, STRIP and PLATE<\/b>. Listing all three as \u201cthe Kovar specification\u201d leads to a wire specification being written onto a plate order.<br \/><b>3. Skipping the decarburising anneal, or mistaking it for a cleaning step.<\/b> <b>Wet hydrogen decarburisation is a MANDATORY metallurgical operation for glass-to-metal sealing<\/b>, not degreasing. Skip it and carbon produces CO\/CO\u2082, leaves blisters at the interface and <b>hermeticity is lost<\/b>. Most distributor pages never mention it at all.<br \/><b>4. Confusing dry hydrogen with wet hydrogen.<\/b> <b>Dry hydrogen degasses; it does NOT remove carbon.<\/b> What decarburises is the <b>water vapour<\/b> in wet hydrogen.<br \/><b>5. Writing the operation sequence backwards.<\/b> The correct order is <b>fabricate \u2192 degrease \u2192 decarburise \u2192 controlled oxidation \u2192 glass seal \u2192 plate<\/b>. <b>Glass is not sealed to a plated surface<\/b>; what the glass bonds to is the <b>nickel-cobalt oxide film<\/b>, not the nickel plate.<br \/><b>6. Confusing the Curie temperature with the inflection point.<\/b> <b>Curie 435 \u00b0C<\/b>, <b>inflection 450 \u00b0C<\/b>. One distributor writes <b>425 \u00b0C<\/b> for Curie. <b>The design ceiling is 450 \u00b0C<\/b>, and that temperature also sits just above the <b>strain point of 7052 glass (435\u2013440 \u00b0C)<\/b> \u2014 two separate reasons, one line.<br \/><b>7. Publishing a single expansion number.<\/b> In Kovar expansion is a curve that <b>falls, then rises<\/b>: 25\u2013100 \u00b0C <b>5.85<\/b> \u00b7 25\u2013350 \u00b0C <b>4.90<\/b> (minimum) \u00b7 25\u2013450 \u00b0C <b>5.26<\/b> \u00b7 25\u2013500 \u00b0C <b>6.14<\/b> \u00b7 25\u2013900 \u00b0C <b>11.25<\/b>. <b>The entire value of the alloy is in the SHAPE of that curve; a single number destroys it.<\/b><br \/><b>8. Assuming Corning 7052 is still made.<\/b> <b>7052 has been discontinued since 1991.<\/b> The succession is <b>7056 \u2192 7720 \u2192 Schott 8250<\/b>. Tie the specification to <b>expansion and strain point values<\/b>, not to a brand name.<br \/><b>9. Density conflict.<\/b> <b>8.36 g\/cm\u00b3<\/b> is the majority and mill value. One manufacturer&#8217;s bulletin gives <b>8.16<\/b>, one distributor <b>8.25<\/b>. If you price by weight, <b>state which density you used<\/b>.<br \/><b>10. Resistivity conflict.<\/b> <b>49 \u00b5\u03a9\u00b7cm<\/b> is confirmed by two independent sources (294 ohm-cir-mil\/ft is the same number). One manufacturer&#8217;s bulletin gives <b>43 \u00b5\u03a9\u00b7cm<\/b>. State which you used in RF and power calculations.<br \/><b>11. DIN name confusion.<\/b> <b>FeNi29Co17<\/b> and <b>FeNi29Co18<\/b> are the same alloy; the difference is which end of the cobalt band (<b>17.0\u201318.0 %<\/b>) went into the name. <b>The material number is 1.3981 in both cases.<\/b><br \/><b>12. Material number confusion.<\/b> <b>1.3981 = Kovar<\/b>, <b>1.3912 = Invar 36<\/b>, <b>1.3917 = alloy 42<\/b>. All three are called \u201clow-expansion Fe-Ni\u201d and all three do entirely different jobs.<br \/><b>13. Confusion with \u201cInvar 42\u201d.<\/b> <b>Alloy 42<\/b> (K94100) is sometimes sold as \u201cInvar 42\u201d. <b>It is neither Invar 36 nor Kovar:<\/b> Fe\u201342 Ni, inflection 370 \u00b0C, matched to silicon and alumina. <b>Read the UNS number on the certificate, not the trade name.<\/b><br \/><b>14. Treating the chemistry table as the only acceptance criterion.<\/b> The specification&#8217;s own note reads: <b>the iron, nickel and cobalt percentages are NOMINAL and are adjusted by the manufacturer so that the alloy meets the expansion requirements.<\/b> <b>So the governing acceptance criterion is EXPANSION.<\/b> With F15 withdrawn, <b>you must write the expansion acceptance band into the order yourself<\/b>; otherwise the only property that matters is never measured.<br \/><b>15. Omitting the carbon ceiling, or hiding the conflict in it.<\/b> Published ceilings range over <b>\u22640.02 \u00b7 \u22640.03 \u00b7 \u22640.04 \u00b7 \u22640.05<\/b>. <b>If you are sealing to glass this difference matters; demand the lowest ceiling and write it into the order.<\/b><br \/><b>16. Assuming Kovar is \u201cstainless\u201d.<\/b> <b>Chromium is only a \u22640.20 % impurity ceiling; no passive film forms and bare Kovar rusts in a humid environment.<\/b> Field corrosion resistance comes <b>from nickel + gold plating, not from the alloy<\/b>.<br \/><b>17. Treating nickel plating as cosmetic.<\/b> The nickel underplate does <b>three jobs at once<\/b>: corrosion barrier, solderability, and a pore-free base for the gold top layer. <b>Gold alone is not enough<\/b>: micro-pores in the nickel <b>accelerate local corrosion<\/b> under the gold\u2013Kovar galvanic couple.<br \/><b>18. Omitting the magnetic behaviour.<\/b> Kovar is <b>ferromagnetic below 435 \u00b0C<\/b> and is a constraint for magnetically sensitive circuits. <b>Do not publish a relative permeability (\u00b5r) figure \u2014 no verifiable value could be found.<\/b><br \/><b>19. Mistaking the melting point for a safety margin.<\/b> <b>1450 \u00b0C<\/b> is correct and <b>completely irrelevant<\/b>. Kovar&#8217;s service ceiling is <b>450 \u00b0C<\/b>, set by the glass match, not by melting.<br \/><b>20. Specifying elongation without a gauge length.<\/b> Published elongation values range over <b>25 %, 30 % and 42 %<\/b>; most of the spread comes from <b>gauge length and product form<\/b>. <b>Do not impose an elongation requirement without stating the gauge length.<\/b><\/p>\n<p><!-- dm-diy-kars --><\/p>\n<div style=\"border:1px solid #e3e9ec;margin:22px 0 26px;background:#fff;position:relative;overflow:hidden;\">\n<div style=\"background:#12303f;color:#fff;padding:9px 14px;font-size:14px;font-weight:700;letter-spacing:.3px;position:relative;z-index:2;\">COMPARISON<\/div>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"padding:10px 14px 0;font-size:12.5px;color:#5b7180;line-height:1.7;\">MEAN LINEAR COEFFICIENT OF THERMAL EXPANSION (10-6\/\u00b0C) over the same temperature ranges referenced to 20 \u00b0C. The values for the two alloys come from the SAME measurement basis in the SAME source (the Special Metals NILO alloys bulletin), and each row has additionally been cross-checked against independent sources. These two alloys are distinguished by their expansion behaviour rather than by their mechanical strength, so the comparison is built on that criterion.<\/div>\n<div style=\"padding:12px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"overflow-x:auto;position:relative;z-index:2;\">\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;min-width:430px;background:transparent;\">\n<tr>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Grade<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">UNS<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">W.-Nr.<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 100<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 200<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 250<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 300<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 400<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Cte 20 500<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Donum noktasi<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Curie<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Davranis<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Ne icin secilir<\/th>\n<th style=\"padding:7px 9px;text-align:left;font-size:12px;color:#12303f;background:#F2F6F8;border:1px solid #eceff1;\">Capraz kontrol<\/th>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;\">Kovar<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">K94610<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">1.3981<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">6.0<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">5.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">5.3<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">5.1<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">4.9<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">6.2<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">450 \u00b0C (Special Metals, EFINEA)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">435 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">The coefficient FALLS from room temperature to the inflection point and stays flat across the 20-450 \u00b0C band, then rises sharply. The value is higher than Invar&#8217;s, but THE CURVE IS FLAT.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Hermetic glass-to-metal seals. What is wanted is not a low coefficient but a curve that MATCHES the borosilicate glass curve all the way to 450 \u00b0C.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">EFINEA \/ Carpenter 5.86 for 25-100 \u00b0C; 5.06 for 25-400 \u00b0C; 5.25 for 25-450 \u00b0C \u00b7 NiWire 6.4 for 20-100 \u00b0C; 5.3 for 20-450 \u00b0C \u00b7 Wikipedia 5.5 for 25-200 \u00b0C; 5.3 for 25-450 \u00b0C \u00b7 ASTM F15 acceptance band 4.60-5.20 for 30-400 \u00b0C and 5.10-5.50 for 30-450 \u00b0C<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;\">Invar 36<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">K93600 (also K93601, K93603)<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">1.3912<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">1.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">2.6<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">3.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">5.5<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">8.4<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">10.1<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">220 \u00b0C (Special Metals); ESPI gives 190 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">277-279 \u00b0C<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">The coefficient is at its lowest around room temperature and RISES RAPIDLY with temperature. Above the Curie temperature the Invar effect disappears entirely.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Work below 200 \u00b0C in which the dimension must not change with temperature. It is NOT SUITABLE for glass-to-metal seals; its curve matches no technical glass.<\/td>\n<td style=\"padding:7px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">Carpenter 1.30 at 93 \u00b0C \u00b7 Rolled Alloys 1.44 for 21-100 \u00b0C \u00b7 Nickel Institute 1.26 for -18\/93 \u00b0C \u00b7 NeoNickel 1.2-1.5 for -100\/+100 \u00b0C<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<div style=\"padding:10px 12px 2px;position:relative;overflow:hidden;\"><span aria-hidden=\"true\" data-dmwm=\"1\" style=\"position:absolute;top:50%;left:50%;transform:translate(-50%,-50%) rotate(-18deg);font-size:72px;font-weight:800;letter-spacing:.12em;color:#12303f;opacity:.05;white-space:nowrap;pointer-events:none;user-select:none;z-index:3;\">DEFENCE METAL<\/span><\/p>\n<div style=\"position:relative;z-index:2;\">\n<div style=\"font-size:13.5px;font-weight:700;color:#12303f;margin:6px 0 6px;\">Additional information<\/div>\n<table style=\"width:100%;border-collapse:collapse;font-size:13.5px;background:transparent;\">\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Kritik fark<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">Kovar&#8217;s coefficient is about four times that of Invar 36 over the 20-100 \u00b0C band. Even so it is Kovar that is used in glass-to-metal seals, because the criterion is not the SMALLNESS of the coefficient but the SHAPE OF THE CURVE. The seal is formed as the glass cools from its setting temperature to room temperature; if glass and metal contract at different rates through that cooling, the joint cracks. Because Kovar&#8217;s curve follows the borosilicate glass curve up to 450 \u00b0C, the seal stays free of stress throughout that cooling. Invar 36&#8217;s curve, by contrast, diverges rapidly above 220 \u00b0C and matches no technical glass. The two alloys are not interchangeable. NEITHER alloy is precipitation hardenable.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Glass note<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(247,250,251,.78);color:#3d5260;\">The glass family Kovar is matched to is BOROSILICATE; the matching glass most often named is Corning 7052. Special Metals states that the expansion characteristics of NILO alloy K &#8216;match those of borosilicate glasses and alumina type ceramics&#8217;; NiWire writes that the match holds between -80 and 450 \u00b0C; EFINEA states that 450 \u00b0C is &#8216;the working range for sealing to borosilicate glasses&#8217; and names Corning 7052 as the matching glass. The borosilicate glass family has a coefficient of about 5 ppm\/K over 30-200 \u00b0C. THE NAME CORNING 7052 APPEARS EXPLICITLY IN ONLY ONE INDEPENDENT SOURCE, so it is written on the card as the &#8216;typical matching glass&#8217;, while the glass family (borosilicate) rests on four sources.<\/td>\n<\/tr>\n<tr>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);font-weight:700;color:#12303f;width:34%;vertical-align:top;\">Siparis notu<\/td>\n<td style=\"padding:6px 9px;border:1px solid #eceff1;background:rgba(255,255,255,.72);color:#3d5260;\">An expansion coefficient is NEVER ordered without stating its temperature range. The statement &#8216;Kovar, 5 ppm\/K&#8217; is incomplete; it must be written as &#8216;mean linear coefficient of expansion over 30-450 \u00b0C, 5.10-5.50 \u00b5m\/m\u00b7\u00b0C&#8217;. Because ASTM F15 (Kovar) and ASTM F1684 (Invar) were both withdrawn in 2024, the acceptance range must be written into the purchase order.<\/td>\n<\/tr>\n<\/table>\n<\/div>\n<\/div>\n<\/div>\n<div style=\"padding:6px 14px 12px;font-size:12px;color:#5b7180;line-height:1.7;border-top:1px solid #f0f3f5;position:relative;z-index:2;\">Same criterion, same reference temperature (20 \u00b0C), same measurement basis: Tables 7 and 10 of the Special Metals NILO bulletin. The coefficients are given TOGETHER WITH THEIR TEMPERATURE RANGES; a coefficient given without a range cannot be used. The values in the cross-check rows use different reference temperatures (20, 25, 30 \u00b0C), so they are not expected to agree exactly and have not been averaged. The name Corning 7052 appears explicitly in one independent source; the glass FAMILY (borosilicate) is verified by four. NEITHER alloy is precipitation hardenable.<\/div>\n<\/div>\n<p><!-- \/dm-diy-kars --><\/p>\n<p><!-- \/dm-zengin --><\/p>\n<p><!-- dm-ld --><script type=\"application\/ld+json\">{\"@context\":\"https:\/\/schema.org\",\"@type\":\"WebPage\",\"name\":\"Kovar\",\"url\":\"https:\/\/www.defencemetal.com\/index.php\/en\/kovar\/\",\"inLanguage\":\"en\",\"description\":\"Kovar (UNS K94610 \u00b7 W.Nr. 1.3981 \u00b7 DIN designation FeNi29Co17 \u2014 some publishers write FeNi29Co18 \u00b7 ASTM F15 \u00b7 Chinese 4J29) is a ternary iron-nickel-cobalt alloy, nominally 29 % nickel \u2013 17 % cobalt \u2013 balance iron.\",\"isPartOf\":{\"@type\":\"WebSite\",\"name\":\"Defence Metal\",\"url\":\"https:\/\/www.defencemetal.com\/\"},\"publisher\":{\"@type\":\"Organization\",\"name\":\"Defence Metal\",\"url\":\"https:\/\/www.defencemetal.com\/\"},\"mainEntity\":{\"@type\":\"DefinedTerm\",\"name\":\"Kovar\",\"description\":\"Kovar (UNS K94610 \u00b7 W.Nr. 1.3981 \u00b7 DIN designation FeNi29Co17 \u2014 some publishers write FeNi29Co18 \u00b7 ASTM F15 \u00b7 Chinese 4J29) is a ternary iron-nickel-cobalt alloy, nominally 29 % nickel \u2013 17 % cobalt \u2013 balance iron.\",\"inDefinedTermSet\":{\"@type\":\"DefinedTermSet\",\"name\":\"Defence Metal - metals and alloys\",\"url\":\"https:\/\/www.defencemetal.com\/\"},\"alternateName\":[\"UNS K94610\",\"W.Nr. 1.3981\",\"FeNi29Co17\"],\"identifier\":[{\"@type\":\"PropertyValue\",\"propertyID\":\"UNS\",\"value\":\"K94610\"},{\"@type\":\"PropertyValue\",\"propertyID\":\"Werkstoffnummer\",\"value\":\"1.3981\"}],\"additionalProperty\":[{\"@type\":\"PropertyValue\",\"name\":\"DIN \/ EN designation\",\"value\":\"FeNi29Co17\"}]}}<\/script><!-- \/dm-ld --><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Kovar \/ (1.3981) \/ UNS K94610 \/ ASTM F15 DEFENCE METAL Kovar UNS K94610 \u00b7 W.Nr. 1.3981 \u00b7 DIN 17745 \u00b7 FeNi29Co17 \u00b7 ~53% Fe \u2013 29% Ni \u2013 17% Co. Minor elements: C 0.02-0.04% max \u00b7 Mn 0.30-0.50% max \u00b7 Si 0.20% max \u00b7 Cr 0.20% max \u00b7 Cu 0.20% max \u00b7 Mo 0.20% &hellip; <\/p>\n<p class=\"link-more\"><a href=\"https:\/\/www.defencemetal.com\/index.php\/en\/kovar\/\" class=\"more-link\"><span class=\"screen-reader-text\"> &#8220;Kovar \/ (1.3981) \/ ASTM F15&#8221;<\/span>devam\u0131n\u0131 oku<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":3526,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_yoast_wpseo_title":"KOVAR \/ (1.3981) \/ UNS K94610 | Defence Metal","_yoast_wpseo_metadesc":"Kovar (UNS K94610, 1.3981) \u2014 controlled expansion Fe-Ni-Co alloy matched to borosilicate glass for hermetic glass-to-metal seals. ASTM F15.","inspiro_hide_title":false,"inspiro_hide_featured_image":false,"footnotes":""},"dm_sektor":[18,14,11],"class_list":["post-3537","page","type-page","status-publish","hentry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.5 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>KOVAR \/ (1.3981) \/ UNS K94610 | Defence Metal<\/title>\n<meta name=\"description\" content=\"Kovar (UNS K94610, 1.3981) \u2014 controlled expansion Fe-Ni-Co alloy matched to borosilicate glass for hermetic glass-to-metal seals. 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